1,535 research outputs found

    Possible high temperature superconductivity in Ti-doped A-Sc-Fe-As-O (A= Ca, Sr) system

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    We report a systematic study on the effect of partial substitution of Sc3+^{3+} by Ti4+^{4+} in Sr2_{2}ScFeAsO3_{3}, Ca2_{2}ScFeAsO3_{3} and Sr3_{3}Sc2_{2}Fe2_{2}As2_{2}O5_{5} on their electrical properties. High level of doping results in an increased carrier concentration and leads to the appearance of superconductivity with the onset of Tc_{c} up to 45 K.Comment: 8 pages, 4 figures, 2 new figure

    Superconductivity induced by Ni doping in BaFe2_2As2_2

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    A series of 122 phase BaFe2−x_{2-x}Nix_xAs2_2 (xx = 0, 0.055, 0.096, 0.18, 0.23) single crystals were grown by self flux method and a dome-like Ni doping dependence of superconducting transition temperature is discovered. The transition temperature TconT_c^{on} reaches a maximum of 20.5 K at xx = 0.096, and it drops to below 4 K as xx ≥\geq 0.23. The negative thermopower in the normal state indicates that electron-like charge carrier indeed dominates in this system. This Ni-doped system provides another example of superconductivity induced by electron doping in the 122 phase.Comment: 7 pages, 5 figures, revised version, added EDX result, accepted for special issue of NJ

    Distorted magnetic orders and electronic structures of tetragonal FeSe from first-principles

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    We use the state-of-the-arts density-functional-theory method to study various magnetic orders and their effects on the electronic structures of the FeSe. Our calculated results show that, for the spins of the single Fe layer, the striped antiferromagnetic orders with distortion are more favorable in total energy than the checkerboard antiferromagnetic orders with tetragonal symmetry, which is consistent with known experimental data, and the inter-layer magnetic interaction is very weak. We investigate the electronic structures and magnetic property of the distorted phases. We also present our calculated spin coupling constants and discuss the reduction of the Fe magnetic moment by quantum many-body effects. These results are useful to understand the structural, magnetic, and electronic properties of FeSe, and may have some helpful implications to other FeAs-based materials

    Pair-Hopping Mechanism for Layered Superconductors

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    We propose a possible charge fluctuation effect expected in layered superconducting materials. In the multireference density functional theory, relevant fluctuation channels for the Josephson coupling between superconducting layers include the interlayer pair hopping derived from the Coulomb repulsion. When interlayer single-electron tunneling processes are irrelevant in the Kohn-Sham electronic band structure calculation, the two-body effective interactions stabilize a superconducting phase. This state is also regarded as a valence-bond solid in a bulk electronic state. The hidden order parameters coexist with the superconducting order parameter when the charging effect of a layer is comparable to the pair hopping. Relevant materials structures favorable for the pair-hopping mechanism are discussed.Comment: 24 pages, 2 figures, to be published in J. Phys. Soc. Jpn. (2009
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