25 research outputs found

    Electrode Polarization Effects in Broadband Dielectric Spectroscopy

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    In the present work, we provide broadband dielectric spectra showing strong electrode polarization effects for various materials, belonging to very different material classes. This includes both ionic and electronic conductors as, e.g., salt solutions, ionic liquids, human blood, and colossal-dielectric-constant materials. These data are intended to provide a broad data base enabling a critical test of the validity of phenomenological and microscopic models for electrode polarization. In the present work, the results are analyzed using a simple phenomenological equivalent-circuit description, involving a distributed parallel RC circuit element for the modeling of the weakly conducting regions close to the electrodes. Excellent fits of the experimental data are achieved in this way, demonstrating the universal applicability of this approach. In the investigated ionically conducting materials, we find the universal appearance of a second dispersion region due to electrode polarization, which is only revealed if measuring down to sufficiently low frequencies. This indicates the presence of a second charge-transport process in ionic conductors with blocking electrodes.Comment: 9 pages, 6 figures, experimental data are provided in electronic form (see "Data Conservancy"

    Colossal dielectric constants in transition-metal oxides

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    Many transition-metal oxides show very large ("colossal") magnitudes of the dielectric constant and thus have immense potential for applications in modern microelectronics and for the development of new capacitance-based energy-storage devices. In the present work, we thoroughly discuss the mechanisms that can lead to colossal values of the dielectric constant, especially emphasising effects generated by external and internal interfaces, including electronic phase separation. In addition, we provide a detailed overview and discussion of the dielectric properties of CaCu3Ti4O12 and related systems, which is today's most investigated material with colossal dielectric constant. Also a variety of further transition-metal oxides with large dielectric constants are treated in detail, among them the system La2-xSrxNiO4 where electronic phase separation may play a role in the generation of a colossal dielectric constant.Comment: 31 pages, 18 figures, submitted to Eur. Phys. J. for publication in the Special Topics volume "Cooperative Phenomena in Solids: Metal-Insulator Transitions and Ordering of Microscopic Degrees of Freedom

    The influence of underdense polymer target with/without high-Z nanoparticles on laser radiation absorption and energy transport

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    Fabrication methods for low-density fine-structure (cell size <<1 μ\mu m) 3-D networks of cellulose triacetate (TAC) are developed. Target densities ranged 4-20 mg/cc, similar polymer structures were produced both with no load and with high-Z cluster dopant with concentration up to 30%. Foams of varying density down to 0.25 plasma critical density at the third harmonic of iodine laser wavelength are supplied for laser shots. Experiments with underdense foam targets with and without clusters irradiated on the PALS laser facility are analyzed preliminary, showing strong influence of target structure on process of laser light absorption. Heat and radiation transport in such targets are considered
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