Triple correlation for detection of damage-related nonlinearities in composite structures

Nonlinear effects in vibration responses are investigated for the undamaged composite plate and the composite plate with a delamination. The analysis is focused on higher harmonic generation in vibration responses for various excitation amplitude levels. This effect is investigated using the triple correlation technique. The dynamics of composite plate was modelled using two-dimensional finite elements and the classical lamination theory. The doubled-node approach was used to model delamination area. Mode shapes and natural frequencies were estimated based on numerical models. Next, the delamination divergence analysis was used to obtain relative displacements for delaminated plies. Experimental modal analysis test was carried out to verify the numerical models. The two strongest vibration modes as well as two vibration modes with the smallest and largest motion level of delaminated plies were selected for nonlinear vibration test. The Fisher criterion was employed to verify the effectiveness and confidence level of the proposed technique. The results show that the method can be used not only to reveal nonlinearities, but also to reliably detect impact damage in composites. These results are confirmed using the statistical analysis

Analysis of elastic nonlinearity for impact damage detection in composite laminates

This paper concerns the experimental analysis of nonlinear response features of a composite laminate plate for impact damage detection. The measurement procedure is based on the Scaling Subtraction Method (SSM) and consists in exciting the damaged specimen with two sinusoidal signals at different amplitude. The linearly rescaled response signal at low amplitude excitation is subtracted from the response at large amplitude excitation to extract the nonlinear signatures. The latter are analysed in the time domain to infer the presence of damage. Results are compared with frequency domain analyses using the nonlinear vibro-acoustic modulation technique (NWMS). Changes in amplitude and phase as well as modulation effects of the acquired responses are also monitored. Surface-bonded, low profile piezoceramic transducers are used for excitation and sensing. Both measurements techniques are applied to detect barely visible impact damage in laminate composite plate. Non-destructive penetrant-enhanced X-ray inspections are carried out to characterize the extent of internal damage. The behavior of the nonlinear features and the sensitivity of each technique are also investigated in the paper

Damage imaging in composites using nonlinear vibro‐acoustic wave modulations

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Generation of higher harmonics in longitudinal vibration of beams with breathing cracks

Classical nonlinear vibration methods used for structural damage detection are often based on higher- and sub-harmonic generation. However, nonlinearities arising from sources other than damage – e.g. boundary conditions or a measurement chain – are a primary concern in these methods. This paper focuses on localisation of damage-related nonlinearities based on higher harmonic generation. Numerical and experimental investigations in longitudinal vibration of beams with breathing cracks are presented. Numerical modelling is performed using a two-dimensional finite element approach. Different crack depths, locations and boundary conditions are investigated. The results demonstrate that nonlinearities in cracked beams are particularly strong in the vicinity of damage, allowing not only for damage localisation but also for separation of crack induced nonlinearity from other sources of nonlinearities

Outcome of children relapsing after first allogeneic haematopoietic stem cell transplantation for acute myeloid leukaemia: a retrospective I-BFM analysis of 333 children

Outcome of 333 children with acute myeloid leukaemia relapsing after a first allogeneic haematopoietic stem cell transplantation was analyzed. Four-year probability of overall survival (4y-pOS) was 14%. 4y-pOS for 122 children receiving a second haematopoietic stem cell transplantation was 31% and 3% for those that did not (P = <0·0001). Achievement of a subsequent remission impacted survival (P = <0·0001). For patients receiving a second transplant survival with or without achieving a subsequent remission was comparable. Graft source (bone marrow vs. peripheral blood stem cells, P = 0·046) and donor choice (matched family vs. matched unrelated donor, P = 0·029) positively impacted survival after relapse. Disease recurrence and non-relapse mortality at four years reached 45% and 22%

Single molecule detection from a large-scale SERS-active Au79Ag21 substrate

Detecting and identifying single molecules are the ultimate goal of analytic sensitivity. Single molecule detection by surface-enhanced Raman scattering (SM-SERS) depends predominantly on SERS-active metal substrates that are usually colloidal silver fractal clusters. However, the high chemical reactivity of silver and the low reproducibility of its complicated synthesis with fractal clusters have been serious obstacles to practical applications of SERS, particularly for probing single biomolecules in extensive physiological environments. Here we report a large-scale, free standing and chemically stable SERS substrate for both resonant and nonresonant single molecule detection. Our robust substrate is made from wrinkled nanoporous Au79Ag21 films that contain a high number of electromagnetic “hot spots” with a local SERS enhancement larger than 109. This biocompatible gold-based SERS substrate with superior reproducibility, excellent chemical stability and facile synthesis promises to be an ideal candidate for a wide range of applications in life science and environment protection

Distortion in a 7xxx aluminum alloy during liquid phase sintering

The distortion in a sintered 7xxx aluminum alloy, Al-7Zn-2.5Mg-1Cu (wt. pct), has been investigated by sintering three rectangular bars in each batch at 893 K (620 °C) for 0 to 40 minutes in nitrogen, followed by air or furnace cooling. They were placed parallel to each other, equally spaced apart at 2 mm, with their long axes being perpendicular to the incoming nitrogen flow. Pore evolution in each sample during isothermal sintering was examined metallographically. The compositional changes across sample mid-cross section and surface layers were analyzed using energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy depth profiling, respectively. The two outer samples bent toward the middle one, while the middle sample was essentially distortion free after sintering. The distortion in the outer samples was a result of differential shrinkage between their outer and inner surfaces during isothermal sintering. The porous outer surface showed an enrichment of oxygen around the large pores as well as lower magnesium and zinc contents than the interior and inner surface of the same sample, while the inner surface was distinguished by the presence of AlN. The differential shrinkage was caused by different oxygen contents in local sintering atmosphere and unbalanced loss of magnesium and zinc between the outer and inner surfaces

Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries

Undesired electrode-electrolyte interactions prevent the use of many high-energy-density cathode materials in practical lithium-ion batteries. Efforts to address their limited service life have predominantly focused on the active electrode materials and electrolytes. Here an advanced three-dimensional chemical and imaging analysis on a model material, the nickel-rich layered lithium transition-metal oxide, reveals the dynamic behaviour of cathode interphases driven by conductive carbon additives (carbon black) in a common nonaqueous electrolyte. Region-of-interest sensitive secondary-ion mass spectrometry shows that a cathode-electrolyte interphase, initially formed on carbon black with no electrochemical bias applied, readily passivates the cathode particles through mutual exchange of surface species. By tuning the interphase thickness, we demonstrate its robustness in suppressing the deterioration of the electrode/electrolyte interface during high-voltage cell operation. Our results provide insights on the formation and evolution of cathode interphases, facilitating development of in situ surface protection on high-energy-density cathode materials in lithium-based batteries.ope