141 research outputs found
Monitoring the orientation of rare-earth-doped nanorods for flow shear tomography
Rare-earth phosphors exhibit unique luminescence polarization features
originating from the anisotropic symmetry of the emitter ion's chemical
environment. However, to take advantage of this peculiar property, it is
necessary to control and measure the ensemble orientation of the host particles
with a high degree of precision. Here, we show a methodology to obtain the
photoluminescence polarization of Eu-doped LaPO4 nano rods assembled in an
electrically modulated liquid-crystalline phase. We measure Eu3+ emission
spectra for the three main optimal configurations ({\sigma}, {\pi} and
{\alpha}, depending on the direction of observation and the polarization axes)
and use them as a reference for the nano rod orientation analysis. Based on the
fact that flowing nano rods tend to orient along the shear strain profile, we
use this orientation analysis to measure the local shear rate in a flowing
liquid. The potential of this approach is then demonstrated through tomographic
imaging of the shear rate distribution in a microfluidic system.Comment: 8 pages, 3 figures + supplementary files for experimental and
numerical method
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