Strain controlled oxygen vacancy formation and ordering in CaMnO3_3

We use first-principles calculations to investigate the stability of bi-axially strained \textit{Pnma} perovskite CaMnO$_3$ towards the formation of oxygen vacancies. Our motivation is provided by promising indications that novel material properties can be engineered by application of strain through coherent heteroepitaxy in thin films. While it is usually assumed that such epitaxial strain is accommodated primarily by changes in intrinsic lattice constants, point defect formation is also a likely strain relaxation mechanism. This is particularly true at the large strain magnitudes ($>$4%) which first-principles calculations often suggest are required to induce new functionalities. We find a strong dependence of oxygen vacancy defect formation energy on strain, with tensile strain lowering the formation energy consistent with the increasing molar volume with increasing oxygen deficiency. In addition, we find that strain differentiates the formation energy for different lattice sites, suggesting its use as a route to engineering vacancy ordering in epitaxial thin films.Comment: 7 pages, 7 figure

Sub-national variability of wind power generation in complex terrain and its correlation with large-scale meteorology

The future European electricity system will depend heavily on variable renewable generation, including wind power. To plan and operate reliable electricity supply systems, an understanding of wind power variability over a range of spatio-temporal scales is critical. In complex terrain, such as that found in mountainous Switzerland, wind speeds are influenced by a multitude of meteorological phenomena, many of which occur on scales too fine to capture with commonly used meteorological reanalysis datasets. Past work has shown that anticorrelation at a continental scale is an important way to help balance variable generation. Here, we investigate systematically for the first time the possibility of balancing wind variability by exploiting anticorrelation between weather patterns in complex terrain. We assess the capability for the Consortium for Small-scale Modeling (COSMO)-REA2 and COSMO-REA6 reanalyses (with a 2 and 6 km horizontal resolution, respectively) to reproduce historical measured data from weather stations, hub height anemometers, and wind turbine electricity generation across Switzerland. Both reanalyses are insufficient to reproduce site-specific wind speeds in Switzerland's complex terrain. We find however that mountain-valley breezes, orographic channelling, and variability imposed by European-scale weather regimes are represented by COSMO-REA2. We discover multi-day periods of wind electricity generation in regions of Switzerland which are anticorrelated with neighbouring European countries. Our results suggest that significantly more work is needed to understand the impact of fine scale wind power variability on national and continental electricity systems, and that higher-resolution reanalyses are necessary to accurately understand the local variability of renewable generation in complex terrain.ISSN:1748-9326ISSN:1748-931

Respiratory distress syndrome in near-term babies after caesarean section.

Severe respiratory distress syndrome (RDS) caused by surfactant deficiency is described not only in preterm infants but also in (near-) term babies after caesarean section (CS), especially when carried out before the onset of labour. The aim of the present study was to document the severity of this theoretically avoidable entity in order to improve obstetric and perinatal care. All neonates admitted to the paediatric intensive care unit of the University Hospital of Bern between 1988 and 2000 with RDS on the basis of hyaline membrane disease (HMD) needing mechanical ventilation (MV) after CS and with a birthweight > or = 2500 g were analysed. HMD was diagnosed when respiratory distress and the typical radiological signs were present. Patients were grouped into elective CS before onset of labour and before rupture of membranes (group 1, n = 34) and patients delivered by emergency CS or CS after onset of labour or rupture of membranes (group 2, n = 22). Analysed indices for severity of illness were duration of stay in intensive care unit and MV, ventilation mode, worst oxygenation index (OI), presence of pulmonary air leak, and systemic hypotension. Mean gestational age (GA) was 37 2/7 weeks in group 1 and 36 2/7 weeks in group 2; no patient had a GA of > or = 39 0/7 weeks. Duration of MV was 4.4 days in group 1 and 3.9 days in group 2. Thirteen patients (38%) of group 1 and 7 (32%) of group 2 had to be managed by rescue high-frequency ventilation. A total of 7 patients had an OI>40. Eight patients (24%) in group 1 and 4 (18%) in group 2 developed a pulmonary air leak. Fourteen neonates (41%) in group 1 had to be supported by catecholamines versus 5 (22%) in group 2. There was one death in group 1. Severe RDS on the basis of HMD can also occur in near-term babies after CS; even a fatal outcome can not be excluded. The severity of illness in elective CS without labour may be quite high and is comparable to newborns delivered by CS (after onset of labour and/or rupture of the membranes) who were 1 week younger. No case of HMD was found in our population when CS was carried out after completion of 39 post-menstrual weeks of gestation

Phylogenetic and phylogeographic analyses of African and Arabian Dorcas gazelles (Gazella dorcas)

Once common throughout the entire Sahelo-Saharan region, population sizes of Dorcas gazelles (Gazella dorcas) are nowadays decreasing dramatically. The uncertain taxonomy of this species—with a variety of described subspecies without validated status—hampers conservation efforts. In this situation, phylogenetic and phylogeographic investigations using molecular techniques are highly warranted conservation tools. Here, we investigate sequence variation of the mitochondrial cytochrome b gene and control region of 73 dorcas (G. dorcas) and Saudi gazelles (G. saudiya) throughout the entire distribution range

Color van der Waals forces between heavy quarkonia in effective QCD

The perturbative renormalization group for light-front QCD Hamiltonian produces a logarithmically rising interquark potential already in second order, when all gluons are neglected. There is a question if this approach produces also color van der Waals forces between heavy quarkonia and of what kind. This article shows that such forces do exist and estimates their strength, with the result that they are on the border of exclusion in naive approach, while more advanced calculation is possible in QCD.Comment: 7 pages, elsart, bibliography in .bbl file, to be submitted to Physics Letters

An Atlas of Monte Carlo Models of Dust Extinction in Galaxies for Cosmological Applications

We present an extensive study of the radiative transfer in dusty galaxies based on Monte Carlo simulations. The main output of these simulations are the attenuation curves ${\cal A}_\lambda$ (i.e. the ratio between the observed, dust extinguished, total intensity to the intrinsic unextinguished one of the galaxy as a function of wavelength). We have explored the dependence of ${\cal A}_\lambda$ on a conspicuous set of quantities (Hubble type, inclination, dust optical thickness, dust distribution and extinction properties) for a large wavelength interval, ranging from 1250\AA to the K band, thus finally providing a comprehensive atlas of dust extinction in galaxies, which is electronically available. This study is particularly suitable for inclusion into galaxy formation evolution models and to directly interpret observational data on high redshift galaxies.Comment: 29 pages, aasms4.sty, LaTeX, 5 figures. ApJSS, accepte

Second-Order Formalism for 3D Spin-3 Gravity

A second-order formalism for the theory of 3D spin-3 gravity is considered. Such a formalism is obtained by solving the torsion-free condition for the spin connection \omega^a_{\mu}, and substituting the result into the action integral. In the first-order formalism of the spin-3 gravity defined in terms of SL(3,R) X SL(3,R) Chern-Simons (CS) theory, however, the generalized torsion-free condition cannot be easily solved for the spin connection, because the vielbein e^a_{\mu} itself is not invertible. To circumvent this problem, extra vielbein-like fields e^a_{\mu\nu} are introduced as a functional of e^a_{\mu}. New set of affine-like connections \Gamma_{\mu M}^N are defined in terms of the metric-like fields, and a generalization of the Riemann curvature tensor is also presented. In terms of this generalized Riemann tensor the action integral in the second-order formalism is expressed. The transformation rules of the metric and the spin-3 gauge field under the generalized diffeomorphims are obtained explicitly. As in Einstein gravity, the new affine-like connections are related to the spin connection by a certain gauge transformation, and a gravitational CS term expressed in terms of the new connections is also presented.Comment: 40 pages, no figures. v2:references added, coefficients of eqs in apppendix D corrected, minor typos also corrected, v3:Version accepted for publication in Classical and Quantum Gravit

Report on perceived policy needs and decision contexts

Adaptation to climate change is a new challenge for existing institutions and decision-making processes. In order to assess what form this challenge takes for decision-makers, we conducted interviews and a policy review to determine the perceived policy needs in Austria, Finland, France, Italy, Poland, Romania, Spain and the United Kingdom. In each country, interviews are conducted at the national level and the sub-national (state) level if the national level is not sufficiently active in adaptation planning yet. We focus on general adaptation policy as well as specific sectors for each country, in line with the distribution of MEDIATION case studies. Different countries are at different stages of developing adaptation policy, but the underlying needs are similar across them. We group the needs into nine categories: inter-agency coordination, multi-level governance, mainstreaming, awareness-raising, coping with uncertainty, research needs, tools and information access, financial and human resources, and political commitment. We also look at suggestions for the EU's role in coordinating adaptation policy