High-temperature molten salt thermal energy storage systems for solar applications

Alkali and alkaline earth carbonate latent-heat storage salts, metallic containment materials, and thermal conductivity enhancement materials were investigated to satisfy the high temperature (704 to 871 C) thermal energy storage requirements of advanced solar-thermal power generation concepts are described. Properties of the following six salts selected for compatibility studies are given: three pure carbonates, K2CO3, Li2CO3 and Na2CO3; two eutectic mixtures, BaCO3/Na2CO3 and K2CO3/NaCO3, and one off-eutectic mixture of Na2CO3/K2CO3

High-temperature molten salt thermal energy storage systems

The results of comparative screening studies of candidate molten carbonate salts as phase change materials (PCM) for advanced solar thermal energy storage applications at 540 to 870 C (1004 to 1600 F) and steam Rankine electric generation at 400 to 540 C (752 to 1004 F) are presented. Alkali carbonates are attractive as latent heat storage materials because of their relatively high storage capacity and thermal conductivity, low corrosivity, moderate cost, and safe and simple handling requirements. Salts were tested in 0.1 kWhr lab scale modules and evaluated on the basis of discharge heat flux, solidification temperature range, thermal cycling stability, and compatibility with containment materials. The feasibility of using a distributed network of high conductivity material to increase the heat flux through the layer of solidified salt was evaluated. The thermal performance of an 8 kWhr thermal energy storage (TES) module containing LiKCO3 remained very stable throughout 5650 hours and 130 charge/discharge cycles at 480 to 535 C (896 to 995 F). A TES utilization concept of an electrical generation peaking subsystem composed of a multistage condensing steam turbine and a TES subsystem with a separate power conversion loop was defined. Conceptual designs for a 100 MW sub e TES peaking system providing steam at 316 C, 427 C, and 454 C (600 F, 800 F, and 850 F) at 3.79 million Pa (550 psia) were developed and evaluated. Areas requiring further investigation have also been identified

Glassy behaviour in short range lattice models without quenched disorder

We investigate the quenching process in lattice systems with short range interaction and several crystalline states as ground states. We consider in particular the following systems on square lattice: - hard particle (exclusion) model; - q states planar Potts model. The system is initially in a homogeneous disordered phase and relaxes toward a new equilibrium state as soon as the temperature is rapidly lowered. The time evolution can be described numerically by a stochastic process such as the Metropolis algorithm. The number of pure, equivalent, ground states is q for the Potts model and r for the hard particle model, and it is known that for r or q larger or equal to d+1, the final equilibrium state may be polycrystalline, i.e. not made of a uniform phase. We find that in addition n_g and q_g exist such that for r > r_g, or q > q_g the system evolves toward a glassy state, i.e. a state in which the ratio of the interaction energy among the different crystalline phases to the total energy of the system never vanishes; moreover we find indications that r_g=q_g. We infer that q=q_g (and r=r_g) corresponds to the crossing from second order to discontinuous transition in the phase diagram of the system.Comment: 10 pages, 3 figure

A thermodynamical fiber bundle model for the fracture of disordered materials

We investigate a disordered version of a thermodynamic fiber bundle model proposed by Selinger, Wang, Gelbart, and Ben-Shaul a few years ago. For simple forms of disorder, the model is analytically tractable and displays some new features. At either constant stress or constant strain, there is a non monotonic increase of the fraction of broken fibers as a function of temperature. Moreover, the same values of some macroscopic quantities as stress and strain may correspond to different microscopic cofigurations, which can be essential for determining the thermal activation time of the fracture. We argue that different microscopic states may be characterized by an experimentally accessible analog of the Edwards-Anderson parameter. At zero temperature, we recover the behavior of the irreversible fiber bundle model.Comment: 18 pages, 10 figure

Urine peptidomic biomarkers for diagnosis of patients with systematic lupus erythematosus

Background: Systematic lupus erythematosus (SLE) is characterized with various complications which can cause serious organ damage in the human body. Despite the significant improvements in disease management of SLE patients, the non-invasive diagnosis is entirely missing. In this study, we used urinary peptidomic biomarkers for early diagnosis of disease onset to improve patient risk stratification, vital for effective drug treatment. Methods: Urine samples from patients with SLE, lupus nephritis (LN) and healthy controls (HCs) were analyzed using capillary electrophoresis coupled to mass spectrometry (CE-MS) for state-of-the-art biomarker discovery. Results: A biomarker panel made up of 65 urinary peptides was developed that accurately discriminated SLE without renal involvement from HC patients. The performance of the SLE-specific panel was validated in a multicentric independent cohort consisting of patients without SLE but with different renal disease and LN. This resulted in an area under the receiver operating characteristic (ROC) curve (AUC) of 0.80 (p < 0.0001, 95% confidence interval (CI) 0.65–0.90) corresponding to a sensitivity and a specificity of 83% and 73%, respectively. Based on the end terminal amino acid sequences of the biomarker peptides, an in silico methodology was used to identify the proteases that were up or down-regulated. This identified matrix metalloproteinases (MMPs) as being mainly responsible for the peptides fragmentation. Conclusions: A laboratory-based urine test was successfully established for early diagnosis of SLE patients. Our approach determined the activity of several proteases and provided novel molecular information that could potentially influence treatment efficacy

Dynamical trapping and chaotic scattering of the harmonically driven barrier

A detailed analysis of the classical nonlinear dynamics of a single driven square potential barrier with harmonically oscillating position is performed. The system exhibits dynamical trapping which is associated with the existence of a stable island in phase space. Due to the unstable periodic orbits of the KAM-structure, the driven barrier is a chaotic scatterer and shows stickiness of scattering trajectories in the vicinity of the stable island. The transmission function of a suitably prepared ensemble yields results which are very similar to tunneling resonances in the quantum mechanical regime. However, the origin of these resonances is different in the classical regime.Comment: 14 page

Two Algebraic Process Semantics for Contextual Nets

We show that the so-called 'Petri nets are monoids' approach initiated by Meseguer and Montanari can be extended from ordinary place/transition Petri nets to contextual nets by considering suitable non-free monoids of places. The algebraic characterizations of net concurrent computations we provide cover both the collective and the individual token philosophy, uniformly along the two interpretations, and coincide with the classical proposals for place/transition Petri nets in the absence of read-arcs

Statistical properties of acoustic emission signals from metal cutting processes

Acoustic Emission (AE) data from single point turning machining are analysed in this paper in order to gain a greater insight of the signal statistical properties for Tool Condition Monitoring (TCM) applications. A statistical analysis of the time series data amplitude and root mean square (RMS) value at various tool wear levels are performed, �nding that ageing features can be revealed in all cases from the observed experimental histograms. In particular, AE data amplitudes are shown to be distributed with a power-law behaviour above a cross-over value. An analytic model for the RMS values probability density function (pdf) is obtained resorting to the Jaynes' maximum entropy principle (MEp); novel technique of constraining the modelling function under few fractional moments, instead of a greater amount of ordinary moments, leads to well-tailored functions for experimental histograms.Comment: 16 pages, 7 figure

Thermodynamical fingerprints of fractal spectra

We investigate the thermodynamics of model systems exhibiting two-scale fractal spectra. In particular, we present both analytical and numerical studies on the temperature dependence of the vibrational and electronic specific heats. For phonons, and for bosons in general, we show that the average specific heat can be associated to the average (power law) density of states. The corrections to this average behavior are log-periodic oscillations which can be traced back to the self-similarity of the spectral staircase. In the electronic case, even if the thermodynamical quantities exhibit a strong dependence on the particle number, regularities arise when special cases are considered. Applications to substitutional and hierarchical structures are discussed.Comment: 8 latex pages, 9 embedded PS figure

Effects of the centrifugal force on stellar dynamo simulations

The centrifugal force is often omitted in simulations of stellar convection. This force might be important in rapidly rotating stars such as solar analogues due to its $\Omega^2$ scaling, where $\Omega$ is the rotation rate of the star. We study the effects of the centrifugal force in a set of 21 semi-global stellar dynamo simulations with varying rotation rates. Among these, we include three control runs aimed at distinguishing the effects of the centrifugal force from the nonlinear evolution of the solutions. We solve the 3D MHD equations with the Pencil Code in a solar-like convective zone in a spherical wedge setup with a $2\pi$ azimuthal extent. We decompose the magnetic field in spherical harmonics and study the migration of azimuthal dynamo waves (ADWs), energy of different large-scale magnetic modes, and differential rotation. In the regime with the lowest rotation rates, $\Omega = 5-10\Omega_\odot$, where $\Omega_\odot$ is the rotation rate of the Sun, we see no marked changes in neither the differential rotation nor the magnetic field properties. For intermediate rotation with $\Omega = 20-25\Omega_\odot$ we identify an increase of the differential rotation as a function of centrifugal force. The axisymmetric magnetic energy tends to decrease with centrifugal force while the non-axisymmetric one increases. The ADWs are also affected, especially the propagation direction. In the most rapidly rotating set with $\Omega=30\Omega_\odot$, these changes are more pronounced and in one case the propagation direction of the ADW changes from prograde to retrograde. Control runs suggest that the results are a consequence of the centrifugal force and not due to the details of the initial conditions or the history of the run. We find that the differential rotation and properties of the ADWs change as a function of the centrifugal force only when rotation is rapid enough.Comment: 8 pages, 7 figures, submitted to A&