Solution and bulk properties of branched polyvinyl acetates IV--Melt viscosity

The melt viscosities of some randomly branched and some comb shaped branched polyvinyl acetate fractions were compared to the viscosities of linear polymer over a range of molecular weights. The melt viscosity of the branched polymer was usually higher than that of linear polymer of the same weight average molecular weight. The extent of this increase was related to the molecular weight of the branches but no correlation could be found which included the number of branches per molecule. This unusual behaviour is believed to be due to the fact that the length of the branches in the polymers of this study was above the critical chain length for polyvinyl acetate which made it possible for the branches to be engaged in intermolecular chain entanglements.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/32168/1/0000223.pd

High resolution measurements and modeling of auroral hydrogen emission line profiles

Measurements in the visible wavelength range at high spectral resolution (1.3 A° ) have been made at Longyearbyen, Svalbard (15.8 E,78.2 N) during an interval of intense proton precipitation. The shape and Doppler shift of hydrogen Balmer beta line profiles have been compared with model line profiles, using as input ion energy spectra from almost coincident passes of the FAST and DMSP spacecraft. The comparison shows that the simulation contains the important physical processes that produce the profiles, and confirms that measured changes in the shape and peak wavelength of the hydrogen profiles are the result of changing energy input. This combination of high resolution measurements with modeling provides a method of estimating the incoming energy and changes in flux of precipitating protons over Svalbard, for given energy and pitch-angle distributions. Whereas for electron precipitation, information on the incident particles is derived from brightness and brightness ratios which require at least two spectral windows, for proton precipitation the Doppler profile of resulting hydrogen emission is directly related to the energy and energy flux of the incident energetic protons and can be used to gather information about the source region. As well as the expected Doppler shift to shorter wavelengths, the measured profiles have a significant red-shifted component, the result of upward flowing emitting hydrogen atoms