A terminal molybdenum carbide prepared by methylidyne deprotonation

The carbide anion [CMo{N(R)Ar}_3]– [R = C(CD_3)_2CH_3, Ar = C_6H_3Me_2-3,5], is obtained by deprotonation of the corresponding methylidyne compound, [HCMo{N(R)Ar}_3], and is characterized by X-ray diffraction as its {K(benzo-15-crown-5)_2}+ salt, thereby providing precedent for the carbon atom as a terminal substituent in transition-metal chemistry

Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs

The modular synthesis of a series of nitrogen-rich polydentate ligands that feature a common pincer-type framework is reported. These ligands allow for site-selective installation of palladium and platinum to give rise to bi- and trimetallic complexes that have d^(8)–d^(8) interactions

Horn antenna with v-shaped corrugated surface

Corrugated shape is easily machined for millimeter wave application and is better suited for folding antenna designs. Measured performance showed ""V'' corrugations and rectangular corrugations have nearly the same pattern beamwidth, gain, and impedance. Also, ""V'' corrugations have higher relative power loss

A Random Utility Analysis of Southern Alberta Sportfishing

Resource /Energy Economics and Policy,

Estimating normal mixture parameters from the distribution of a reduced feature vector

A FORTRAN computer program was written and tested. The measurements consisted of 1000 randomly chosen vectors representing 1, 2, 3, 7, and 10 subclasses in equal portions. In the first experiment, the vectors are computed from the input means and covariances. In the second experiment, the vectors are 16 channel measurements. The starting covariances were constructed as if there were no correlation between separate passes. The biases obtained from each run are listed

Smoking, dementia and cognitive decline in the elderly, a systematic review.

Background. Nicotine may aid reaction time, learning and memory, but smoking increases cardiovascular risk. Cardiovascular risk factors have been linked to increased risk of dementia. A previous meta-analysis found that current smokers were at higher risk of subsequent dementia, Alzheimers disease, vascular dementia and cognitive decline. Methods. In order to update and examine this further a systematic review and meta-analysis was carried out using different search and inclusion criteria, database selection and more recent publications. Both reviews were restricted to those aged 65 and over. Results. The review reported here found a significantly increased risk of Alzheimers disease with current smoking and a likely but not significantly increased risk of vascular dementia, dementia unspecified and cognitive decline. Neither review found clear relationships with former smoking. Conclusion. Current smoking increases risk of Alzheimers disease and may increase risk of other dementias. This reinforces need for smoking cessation, particularly aged 65 and over. Nicotine alone needs further investigation. © 2008 Peters et al; licensee BioMed Central Ltd

BBO and the Neutron-Star-Binary Subtraction Problem

The Big Bang Observer (BBO) is a proposed space-based gravitational-wave (GW) mission designed primarily to search for an inflation-generated GW background in the frequency range 0.1-1 Hz. The major astrophysical foreground in this range is gravitational radiation from inspiraling compact binaries. This foreground is expected to be much larger than the inflation-generated background, so to accomplish its main goal, BBO must be sensitive enough to identify and subtract out practically all such binaries in the observable universe. It is somewhat subtle to decide whether BBO's current baseline design is sufficiently sensitive for this task, since, at least initially, the dominant noise source impeding identification of any one binary is confusion noise from all the others. Here we present a self-consistent scheme for deciding whether BBO's baseline design is indeed adequate for subtracting out the binary foreground. We conclude that the current baseline should be sufficient. However if BBO's instrumental sensitivity were degraded by a factor 2-4, it could no longer perform its main mission. It is impossible to perfectly subtract out each of the binary inspiral waveforms, so an important question is how to deal with the "residual" errors in the post-subtraction data stream. We sketch a strategy of "projecting out" these residual errors, at the cost of some effective bandwidth. We also provide estimates of the sizes of various post-Newtonian effects in the inspiral waveforms that must be accounted for in the BBO analysis.Comment: corrects some errors in figure captions that are present in the published versio

The Arizona Radio Observatory CO Mapping Survey of Galactic Molecular Clouds: III. The Serpens Cloud in CO J=2-1 and 13CO J=2-1 Emission

We mapped 12CO and 13CO J = 2-1 emission over 1.04 square deg of the Serpens molecular cloud with 38 arcsec spatial and 0.3 km/s spectral resolution using the Arizona Radio Observatory Heinrich Hertz Submillimeter telescope. Our maps resolve kinematic properties for the entire Serpens cloud. We also compare our velocity moment maps with known positions of Young Stellar Objects (YSOs) and 1.1 mm continuum emission. We find that 12CO is self-absorbed and 13CO is optically thick in the Serpens core. Outside of the Serpens core, gas appears in filamentary structures having LSR velocities which are blue-shifted by up to 2 km/s relative to the 8 km/s systemic velocity of the Serpens cloud. We show that the known Class I, Flat, and Class II YSOs in the Serpens core most likely formed at the same spatial location and have since drifted apart. The spatial and velocity structure of the 12CO line ratios implies that a detailed 3-dimensional radiative transfer model of the cloud will be necessary for full interpretation of our spectral data. The starless cores region of the cloud is likely to be the next site of star formation in Serpens.Comment: 41 pages, 15 figure