Large prebiotic molecules in space: photo-physics of acetic acid and its isomers

An increasing number of large molecules have been positively identified in space. Many of these molecules are of biological interest and thus provide insight into prebiotic organic chemistry in the protoplanetary nebula. Among these molecules, acetic acid is of particular importance due to its structural proximity to glycine, the simplest amino acid. We compute electronic and vibrational properties of acetic acid and its isomers, methyl formate and glycolaldehyde, using density functional theory. From computed photo-absorption cross-sections, we obtain the corresponding photo-absorption rates for solar radiation at 1 AU and find them in good agreement with previous estimates. We also discuss glycolaldehyde diffuse emission in Sgr B2(N), as opposite to emissions from methyl formate and acetic acid that appear to be concentrate in the compact region Sgr B2(N-LMH).Comment: 8 pages, 5 figure

Photo-evaporation of close-in gas giants orbiting around G and M stars

X-rays and extreme ultraviolet radiation impacting on a gas produce a variety of effects that, depending on the electron content, may provide a significant heating of the illuminated region. In a planetary atmosphere of solar composition, stellar high energy radiation may heat the gas to very high temperatures, that may have consequences on the stability of planetary atmospheres, in particular for close-in planets. We investigate the variations with stellar age in the occurring frequency of gas giant planets orbiting G and M stars, taking into account that the high energy luminosity of a low mass star evolves in time, both in intensity and hardness. Using the energy-limited escape approach we investigate the effects induced by the atmospheric mass loss on giant exoplanet distribution that is initially flat, at several distances from the parent star. We follow the dynamical evolution of the planet atmosphere, tracking the departures from the initial profile due to the atmospheric escape, until it reaches the final mass-radius configuration. We find that a significant fraction of low mass Jupiter-like planets orbiting with periods lower than ~3.5 days either vaporize during the first billion years, or lose a relevant part of their atmospheres. The planetary initial mass profile is significantly distorted; in particular, the frequency of occurrence of gas giants, less massive than 2 MJ, around young star can be considerably greater than the one around older stellar counterparts

Modelling dust extinction in the Magellanic Clouds

We model the extinction profiles observed in the Small and Large Magellanic clouds with a synthetic population of dust grains consisting by core-mantle particles and a collection of free-flying polycyclic aromatic hydrocarbons. All different flavors of the extinction curves observed in the Magellanic Clouds can be described by the present model, that has been previously (successfully) applied to a large sample of diffuse and translucent lines of sight in the Milky Way. We find that in the Magellanic Clouds the extinction produced by classic grains is generally larger than absorption by polycyclic aromatic hydrocarbons. Within this model, the non-linear far-UV rise is accounted for by polycyclic aromatic hydrocarbons, whose presence in turn is always associated to a gap in the size distribution of classical particles. This hints either a physical connection between (e.g., a common cause for) polycyclic aromatic hydrocarbons and the absence of middle-sized dust particles, or the need for an additional component in the model, that can account for the non-linear far-UV rise without contributing to the UV bump at $\sim$217 nm, e.g., nanodiamonds

Modelling extragalactic extinction through gamma-ray burst afterglows

We analyze extragalactic extinction profiles derived through gamma-ray burst afterglows, using a dust model specifically constructed on the assumption that dust grains are not immutable but respond time-dependently to the local physics. Such a model includes core-mantle spherical particles of mixed chemical composition (silicate core, sp2 and sp3 carbonaceous layers), and an additional molecular component, in the form of free-flying polycyclic aromatic hydrocarbons. We fit most of the observed extinction profiles. Failures occur for lines of sight presenting remarkable rises blueward the bump. We find a tendency in the carbon chemical structure to become more aliphatic with the galactic activity, and to some extent with increasing redshifts. Moreover, the contribution of the moleclar component to the total extinction is more important in younger objects. The results of the fitting procedure (either successes and failures) may be naturally interpreted through an evolutionary prescription based on the carbon cycle in the interstellar medium of galaxies

C2absorption-line diagnostics of diffuse interstellar clouds

The excitation of the diatomic carbon molecule in diffuse interstellar clouds is discussed for a cloud with large density fluctuations of small linear filling factor along the line of sight. Possible implications for the chemistry of the diffuse cloud in front of Cygnus OB2 No. 12 are discussed.Physic

EXCITATION OF C2 IN DIFFUSE INTERSTELLAR CLOUDS

We investigate the effects and the implications of incorporating new collision and radiative rates in modeling the excitation of diatomic carbon molecule. The present results suggest that diffuse and translucent interstellar clouds may present a structure in which regions with different densities and kinetic temperatures overlap along the line of sight, such as core-halo clouds, the nested structure of the molecular gas, and clumpiness. Such conclusion reflects the response of the C{sub 2} rotational ladder to the interplay of thermal and radiative conditions, with low and high rotational levels tracing different regions of the parameter space. To relieve constraints to the formation and excitation of C{sub 2} molecules, we propose a scenario in which the chemistry in diffuse clouds is supplemented by chemistry in many transient and tiny perturbations

EXTRAGALACTIC INTERSTELLAR EXTINCTION CURVES: INDICATORS OF LOCAL PHYSICAL CONDITIONS

Normalized interstellar extinction curves (ISECs) in the Milky Way and other galaxies show a variety of shapes. This variety is attributed to differences along different sight lines in the abundances of the several dust and gas components contributing to extinction. In this paper we propose that these abundance differences are not arbitrary but are a specific consequence of the physical conditions on those sight lines. If this proposal is correct, then it implies that ISECs contain information about physical conditions in the regions generating extinction. This may be particularly important for high redshift galaxies where information on the conditions may be difficult to obtain. We adopt a model of extinction carriers in which the solid and gaseous components are not immutable but respond time-dependently to the local physics. We validate this model by fitting extinction curves measured on sight lines in the Magellanic Clouds and obtained for the gamma-ray burst afterglow GRB 080605. We present results for this model as follows: (1) we show that computed ISECs are controlled by a small number of physical parameters, (2) we demonstrate the sensitivity of computed ISECs to these parameters, (3) we compute as examples ISECs for particular galaxy types, and (4) we note that different galaxy types have different shapes of ISEC

Observational Evidence of Dust Evolution in Galactic Extinction Curves

Although structural and optical properties of hydrogenated amorphous carbons are known to respond to varying physical conditions, most conventional extinction models are basically curve fits with modest predictive power. We compare an evolutionary model of the physical properties of carbonaceous grain mantles with their determination by homogeneously fitting observationally derived Galactic extinction curves with the same physically well-defined dust model. We find that a large sample of observed Galactic extinction curves are compatible with the evolutionary scenario underlying such a model, requiring physical conditions fully consistent with standard density, temperature, radiation field intensity, and average age of diffuse interstellar clouds. Hence, through the study of interstellar extinction we may, in principle, understand the evolutionary history of the diffuse interstellar clouds

Modeling Galactic Extinction with Dust and "Real" Polycyclic Aromatic Hydrocarbons

We investigate the remarkable apparent variety of galactic extinction curves by modeling extinction profiles with core-mantle grains and a collection of single polycyclic aromatic hydrocarbons. Our aim is to translate a synthetic description of dust into physically well-grounded building blocks through the analysis of a statistically relevant sample of different extinction curves. All different flavors of observed extinction curves, ranging from the average galactic extinction curve to virtually 'bumpless' profiles, can be described by the present model. We prove that a mixture of a relatively small number (54 species in 4 charge states each) of polycyclic aromatic hydrocarbons can reproduce the features of the extinction curve in the ultraviolet, dismissing an old objection to the contribution of polycyclic aromatic hydrocarbons to the interstellar extinction curve. Despite the large number of free parameters (at most the 54 Multiplication-Sign 4 column densities of each species in each ionization state included in the molecular ensemble plus the 9 parameters defining the physical properties of classical particles), we can strongly constrain some physically relevant properties such as the total number of C atoms in all species and the mean charge of the mixture. Such properties are found to be largely independent of the adoptedmore » dust model whose variation provides effects that are orthogonal to those brought about by the molecular component. Finally, the fitting procedure, together with some physical sense, suggests (but does not require) the presence of an additional component of chemically different very small carbonaceous grains.« les

Signatures of X-ray dominated chemistry in the spectra of exoplanetary atmospheres

High-energy radiation from stars impacts planetary atmospheres deeply affecting their chemistry, providing departures from chemical equilibrium. While the upper atmospheric layers are dominated by ionizations induced by extreme ultraviolet radiation, deeper into the atmosphere molecular abundances are controlled by a characteristic X-ray dominated chemistry, mainly driven by an energetic secondary electron cascade. In this work, we aim at identifying molecular photochemically induced fingerprints in the transmission spectra of a giant planet atmosphere. We have developed a numerical code capable of synthesizing transmission spectra with arbitrary spectral resolution, exploiting updated infrared photoabsorption cross sections. Chemical mixing ratios are computed using a photochemical model, tailored to investigate high energy ionization processes. We find that in case of high levels of stellar activity, synthetic spectra in both low and high resolutions show significant, potentially observable out-of-equilibrium signatures arising mainly from CO, CH$_4$, C$_2$H$_2$, and HCN.Comment: The paper has been accepted for publication in The Planetary Science Journal (PSJ