Crystal structure, Fermi surface calculations and Shubnikov-de Haas oscillations spectrum of the organic metal θ\theta-(BETS)4_4HgBr4_4(C6_6H5_5Cl) at low temperature

The organic metal \theta$-(BETS)$_4$HgBr$_4$(C$_6$H$_5$Cl) is known to undergo a phase transition as the temperature is lowered down to about 240 K. X-ray data obtained at 200 K indicate a corresponding modification of the crystal structure, the symmetry of which is lowered from quadratic to monoclinic. In addition, two different types of cation layers are observed in the unit cell. The Fermi surface (FS), which can be regarded as a network of compensated electron and hole orbits according to band structure calculations at room temperature, turns to a set of two alternating linear chains of orbits at low temperature. The field and temperature dependence of the Shubnikov-de Haas oscillations spectrum have been studied up to 54 T. Eight frequencies are observed which, in any case, points to a FS much more complex than predicted by band structure calculations at room temperature, even though some of the observed Fourier components might be ascribed to magnetic breakdown or frequency mixing. The obtained spectrum could result from either an interaction between the FS's linked to each of the two cation layers or to an eventual additional phase transition in the temperature range below 200 K.Comment: accepted for publication in Solid State Science

Effect of External Pressure on the Metal–Insulator Transition of the Organic Quasi-Two-Dimensional Metal K-(BEDT-TTF)2Hg(SCN)2Br

The metal–insulator transition in the organic quasi-two-dimensional metal κ-(BEDT-TTF)2Hg(SCN)2Br at TMI ≈ 90 K has been investigated. The crystal structure changes during this transition from monoclinic above TMI to triclinic below TMI. A theoretical study suggested that this phase transition should be of the metal-to-metal type and brings about a substantial change of the Fermi surface. Apparently, the electronic system in the triclinic phase is unstable toward a Mott insulating state, leading to the growth of the resistance when the temperature drops below TMI ≈ 90 K. The application of external pressure suppresses the Mott transition and restores the metallic electronic structure of the triclinic phase. The observed quantum oscillations of the magnetoresistance are in good agreement with the calculated Fermi surface for the triclinic phase, providing a plausible explanation for the puzzling behavior of κ-(BEDT-TTF)2Hg(SCN)2Br as a function of temperature and pressure around 100 K. The present study points out interesting differences in the structural and physical behaviors of the two room temperature isostructural salts of κ-(BEDT-TTF)2Hg(SCN)2X with X = Br, Cl.The work at the Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry was carried out within the project of state assignment number AAAA-A19-119092390079-8. V.N.Z. acknowledges the support of the Russian Foundation for Basic Research No. 21-52-12027. The work in Spain was supported by the MICIU (Grant PGC2018-096955-B-C44) and Generalitat de Catalunya (2017SGR1506). E.C. acknowledges the support of the Spanish MICIU through the Severo Ochoa FUNFUTURE (CEX2019-000917-S) Excellence Center distinction.With funding from the Spanish government through the ‘Severo Ochoa Centre of Excellence’ accreditation (CEX2019-000917-S).Peer reviewe

Effect of External Pressure on the Metal–Insulator Transition of the Organic Quasi-Two-Dimensional Metal κ-(BEDT-TTF)2Hg(SCN)2Br

The metal–insulator transition in the organic quasi-two-dimensional metal κ-(BEDT-TTF)2Hg(SCN)2Br at TMI ≈ 90 K has been investigated. The crystal structure changes during this transition from monoclinic above TMI to triclinic below TMI. A theoretical study suggested that this phase transition should be of the metal-to-metal type and brings about a substantial change of the Fermi surface. Apparently, the electronic system in the triclinic phase is unstable toward a Mott insulating state, leading to the growth of the resistance when the temperature drops below TMI ≈ 90 K. The application of external pressure suppresses the Mott transition and restores the metallic electronic structure of the triclinic phase. The observed quantum oscillations of the magnetoresistance are in good agreement with the calculated Fermi surface for the triclinic phase, providing a plausible explanation for the puzzling behavior of κ-(BEDT-TTF)2Hg(SCN)2Br as a function of temperature and pressure around 100 K. The present study points out interesting differences in the structural and physical behaviors of the two room temperature isostructural salts of κ-(BEDT-TTF)2Hg(SCN)2X with X = Br, Cl

Effect of External Pressure on the Metal–Insulator Transition of the Organic Quasi-Two-Dimensional Metal κ-(BEDT-TTF)₂Hg(SCN)₂Br

The metal–insulator transition in the organic quasi-two-dimensional metal κ-(BEDT-TTF)2Hg(SCN)2Br at TMI ≈ 90 K has been investigated. The crystal structure changes during this transition from monoclinic above TMI to triclinic below TMI. A theoretical study suggested that this phase transition should be of the metal-to-metal type and brings about a substantial change of the Fermi surface. Apparently, the electronic system in the triclinic phase is unstable toward a Mott insulating state, leading to the growth of the resistance when the temperature drops below TMI ≈ 90 K. The application of external pressure suppresses the Mott transition and restores the metallic electronic structure of the triclinic phase. The observed quantum oscillations of the magnetoresistance are in good agreement with the calculated Fermi surface for the triclinic phase, providing a plausible explanation for the puzzling behavior of κ-(BEDT-TTF)2Hg(SCN)2Br as a function of temperature and pressure around 100 K. The present study points out interesting differences in the structural and physical behaviors of the two room temperature isostructural salts of κ-(BEDT-TTF)2Hg(SCN)2X with X = Br, Cl