12 research outputs found

    NUCLEATION AND GROWTH DURING FACETING OF THE PLATINUM-COVERED W(111) SURFACE

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    Low energy electron microscopy (LEEM) and scanning tunneling microscopy (STM) have been used to investigate the faceting of W(111) as induced by Pt. The atomically rough W(111) surface, when fully covered with a monolayer film of Pt and annealed to temperatures higher than {approximately}750 K, experiences a significant morphological restructuring: the initially planar surface undergoes a faceting transition and forms three-sided pyramids with {l_brace}211{r_brace} faces. When Pt is dosed onto the heated surface, the transition from planar to faceted structure proceeds through the nucleation and growth of spatially separated faceted regions, as shown by LEEM. STM reveals the atomic structure of the partially faceted surface, with large planar regions, dotted by clusters of pyramids of various sizes

    LEEM investigation of the faceting of the Pt covered W(111) surface

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    A low energy electron microscope (LEEM) has been used to investigate the faceting of W(111) as induced by Pt. The atomically rough W(111) surface, when fully covered with a monolayer film of Pt and annealed to temperatures higher than {approximately} 750 K, experiences a significant morphological restructuring: the initially planar surface undergoes a faceting transition and forms three-sided pyramids with {211} faces. The experiments demonstrate the capability of LEEM for imaging both the fully and partially faceted surface. In addition, we have observed the formation of the facets in real time, when Pt is dosed onto the heated surface. We find that the transition from planar surface, to partially faceted surface, and to fully faceted surface proceeds through the nucleation and growth of spatially separated faceted regions

    Nanoscale surface chemistry

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