185 research outputs found
Robust and Biocompatible Functionalization of ZnS Nanoparticles by Catechol-Bearing Poly(2-Methyl-2-Oxazoline)s.
Zinc sulfide (ZnS) nanoparticles (NPs) are particularly interesting materials for their electronic and luminescent properties. Unfortunately, their robust and stable functionalization and stabilization, especially in aqueous media, has represented a challenging and not yet completely accomplished task. In this work, we report the synthesis of colloidally stable, photoluminescent and biocompatible core\u2013polymer shell ZnS and ZnS:Tb NPs by employing a water-in-oil miniemulsion (ME) process combined with surface functionalization via catechol-bearing poly-2-methyl-2-oxazoline (PMOXA) of various molar masses. The strong binding of catechol anchors to the metal cations of the ZnS surface, coupled with the high stability of PMOXA against chemical degradation, enable the formation of suspensions presenting excellent colloidal stability. This feature, combined with the assessed photoluminescence and biocompatibility, make these hybrid NPs suitable for optical bioimaging
Proposta de um modelo de maturidade para Gestão do Conhecimento: KM3
A implementação da Gestão do Conhecimento (GC) ocorre em estágios, ou seja, é um processo que demanda mudanças na organização. O objetivo principal desta pesquisa é desenvolver um modelo de maturidade de gestão do conhecimento. Esta pesquisa adotou os princípios da Teoria do Ciclo de Vida. A pesquisa é qualitativa de caráter exploratório. Inicialmente, a partir da análise dos modelos de GC existentes foi desenvolvida uma proposta de Modelo de Maturidade para Gestão do Conhecimento, denominado KM3. Na sequência, esta proposta foi analisada por profissionais. Estes confirmaram os estágios do modelo de maturidade de GC e contribuíram para o refinamento dos fatores alocados em cada estágio. O KM3 é formado por cinco estágios: Falta de Consciência (2 fatores), Planejamento (15 fatores), Iniciação (20 fatores), Desenvolvimento (24 fatores) e Integração (24 fatores)
Theory of the optical conductivity of (TMTSF)PF in the mid-infrared range
We propose an explanation of the mid-infrared peak observed in the optical
conductivity of the Bechgaard salt (TMTSF)PF in terms of electronic
excitations. It is based on a numerical calculation of the conductivity of the
quarter-filled, dimerized Hubbard model. The main result is that, even for
intermediate values of for which the charge gap is known to be very
small, the first peak, and at the same time the main structure, of the optical
conductivity is at an energy of the order of the dimerization gap, like in the
infinite case. This surprising effect is a consequence of the optical
selection rules.Comment: 10 pages, 9 uuencoded figure
Thermal Conductivity of superconducting (TMTSF)_2ClO_4: evidence for a nodeless gap
We report on the first measurements of thermal conductivity in the
superconducting state of (TMTSF)_2ClO_4. The electronic contribution to heat
transport is found to decrease rapidly below T_c, indicating the absence of
low-energy electronic excitations. We argue that this result provides strong
evidence for a nodeless superconducting gap function but does not exclude a
possible unconventional order parameter.Comment: 4 pages including 4 figures, submitted to Phys. Rev. Let
On the Relationship Between the Critical Temperature and the London Penetration Depth in Layered Organic Superconductors
We present an analysis of previously published measurements of the London
penetration depth of layered organic superconductors. The predictions of the
BCS theory of superconductivity are shown to disagree with the measured zero
temperature, in plane, London penetration depth by up to two orders of
magnitude. We find that fluctuations in the phase of the superconducting order
parameter do not determine the superconducting critical temperature as the
critical temperature predicted for a Kosterlitz--Thouless transition is more
than an order of magnitude greater than is found experimentally for some
materials. This places constraints on theories of superconductivity in these
materials.Comment: 5 pages, 1 figur
Heat Conduction in -(BEDT-TTF)Cu(NCS)
The first study of thermal conductivity, , in a quasi-two-dimensional
organic superconductor of the -(BEDT-TTF)X family reveals features
analogous to those already observed in the cuprates. The onset of
superconductivity is associated with a sudden increase in which can be
suppressed by the application of a moderate magnetic field. At low
temperatures, a finite linear term - due to a residual electronic contribution-
was resolved. The magnitude of this term is close to what is predicted by the
theory of transport in unconventional superconductors.Comment: 5 pages, 4 figures include
Nonlinear anomalous diffusion equation and fractal dimension: Exact generalized gaussian solution
In this work we incorporate, in a unified way, two anomalous behaviors, the
power law and stretched exponential ones, by considering the radial dependence
of the -dimensional nonlinear diffusion equation where , ,
, and are real parameters and is a time-dependent
source. This equation unifies the O'Shaugnessy-Procaccia anomalous diffusion
equation on fractals () and the spherical anomalous diffusion for
porous media (). An exact spherical symmetric solution of this
nonlinear Fokker-Planck equation is obtained, leading to a large class of
anomalous behaviors. Stationary solutions for this Fokker-Planck-like equation
are also discussed by introducing an effective potential.Comment: Latex, 6 pages. To appear in Phys. Rev.
On-chain electrodynamics of metallic (TMTSF)_2 X salts: Observation of Tomonaga-Luttinger liquid response
We have measured the electrodynamic response in the metallic state of three
highly anisotropic conductors, (TMTSF)_2 X, where X=PF_6, AsF_6, or ClO_4, and
TMTSF is the organic molecule tetramethyltetraselenofulvalene. In all three
cases we find dramatic deviations from a simple Drude response. The optical
conductivity has two features: a narrow mode at zero frequency, with a small
spectral weight, and a mode centered around 200 cm^{-1}, with nearly all of the
spectral weight expected for the relevant number of carriers and single
particle bandmass. We argue that these features are characteristic of a nearly
one-dimensional half- or quarter-filled band with Coulomb correlations, and
evaluate the finite energy mode in terms of a one-dimensional Mott insulator.
At high frequencies (\hbar\omega > t_\perp, the transfer integral perpendicular
to the chains), the frequency dependence of the optical conductivity
\sigma_1(\omega) is in agreement with calculations based on an interacting
Tomonaga-Luttinger liquid, and is different from what is expected for an
uncorrelated one-dimensional semiconductor. The zero frequency mode shows
deviations from a simple Drude response, and can be adequately described with a
frequency dependent mass and relaxation rate.Comment: 12 pages, 7 figures, RevTeX; minor corrections to text and
references; To be published in Phys. Rev. B, 15 July 199
Finite-Temperature Transport in Finite-Size Hubbard Rings in the Strong-Coupling Limit
We study the current, the curvature of levels, and the finite temperature
charge stiffness, D(T,L), in the strongly correlated limit, U>>t, for Hubbard
rings of L sites, with U the on-site Coulomb repulsion and t the hopping
integral. Our study is done for finite-size systems and any band filling. Up to
order t we derive our results following two independent approaches, namely,
using the solution provided by the Bethe ansatz and the solution provided by an
algebraic method, where the electronic operators are represented in a
slave-fermion picture. We find that, in the U=\infty case, the
finite-temperature charge stiffness is finite for electronic densities, n,
smaller than one. These results are essencially those of spinless fermions in a
lattice of size L, apart from small corrections coming from a statistical flux,
due to the spin degrees of freedom. Up to order t, the Mott-Hubbard gap is
\Delta_{MH}=U-4t, and we find that D(T) is finite for n<1, but is zero at
half-filling. This result comes from the effective flux felt by the holon
excitations, which, due to the presence of doubly occupied sites, is
renormalized to
\Phi^{eff}=\phi(N_h-N_d)/(N_d+N_h), and which is zero at half-filling, with
N_d and N_h being the number of doubly occupied and empty lattice sites,
respectively. Further, for half-filling, the current transported by any
eigenstate of the system is zero and, therefore, D(T) is also zero.Comment: 15 pages and 6 figures; accepted for PR
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