Critical revision of the ZEPLIN-I sensitivity to WIMP interactions

The ZEPLIN collaboration has recently published its first result presenting a maximum sensitivity of $1.1 \times 10^{-6}$ picobarn for a WIMP mass of $\approx$ 60 GeV. The analysis is based on a discrimination method using the different time distribution of scintillation light generated in electron recoil and nuclear recoil interactions. We show that the methodology followed both for the calibration of the ZEPLIN-I detector response and for the estimation of the discrimination power is not reliable enough to claim any background discrimination at the present stage. The ZEPLIN-I sensitivity appears then to be in the order of 10$^{-3}$ picobarn, three orders of magnitude above the claimed 1.1 10$^{-6}$ picobarn.Comment: 8 pages, 4 figures, minor corrections, two references updated, final version accepted in Physics Letters

Ultrafast intersystem crossing of 4-Thiothymidine inaqueous solution

Ultrafast intersystem crossing of UVA-sensitive 4-thiothymidine in aqueous solution was investigated by pump?probe transient absorption. 4-Thiothymidine in the excited singlet state exhibited a distinctively different photophysical pathway from that of thymidine, with intersystem crossing to the triplet manifold being dominant and the triplet formation being completed within approximately 10 ps. This was further supported by quantum chemical calculations. We propose that the unique behavior of photoexcited 4-thiothymidine results from its distinctive molecular and electronic structures and that the triplet form is the initial toxic source to DNA and other biomolecules