322 research outputs found
Lead acid battery recycling for the twenty-first century
There is a growing need to develop novel processes to recover lead from end-of-life lead-acid batteries, due to increasing energy costs of pyrometallurgical lead recovery, the resulting CO2 emissions and the catastrophic health implications of lead exposure from lead-to-air emissions. To address these issues, we are developing an iono-metallurgical process, aiming to displace the pyrometallurgical process that has dominated lead production for millennia. The proposed process involves the dissolution of Pb salts into the deep eutectic solvent (DES) Ethaline 200, a liquid formed when a 1 : 2 molar ratio of choline chloride and ethylene glycol are mixed together. Once dissolved, the Pb can be recovered through electrodeposition and the liquid can then be recycled for further Pb recycling. Firstly, DESs are being used to dissolve the lead compounds (PbCO3, PbO, PbO2 and PbSO4) involved and their solubilities measured by inductively coupled plasma optical emission spectrometry (ICP-OES). The resulting Pb2+ species are then reduced and electrodeposited as elemental lead at the cathode of an electrochemical cell; cyclic voltammetry and chronoamperometry are being used to determine the electrodeposition behaviour and mechanism. The electrodeposited films were characterized by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). We discuss the implications and opportunities of such processes
Technologies bringing young Zebrafish from a niche field to the limelight
Fundamental life science and pharmaceutical research are continually striving to provide physiologically relevant context for their biological studies. Zebrafish present an opportunity for high-content screening (HCS) to bring a true in vivo model system to screening studies. Zebrafish embryos and young larvae are an economical, human-relevant model organism that are amenable to both genetic engineering and modification, and direct inspection via microscopy. The use of these organisms entails unique challenges that new technologies are overcoming, including artificial intelligence (AI). In this perspective article, we describe the state-of-the-art in terms of automated sample handling, imaging, and data analysis with zebrafish during early developmental stages. We highlight advances in orienting the embryos, including the use of robots, microfluidics, and creative multi-well plate solutions. Analyzing the micrographs in a fast, reliable fashion that maintains the anatomical context of the fluorescently labeled cells is a crucial step. Existing software solutions range from AI-driven commercial solutions to bespoke analysis algorithms. Deep learning appears to be a critical tool that researchers are only beginning to apply, but already facilitates many automated steps in the experimental workflow. Currently, such work has permitted the cellular quantification of multiple cell types in vivo, including stem cell responses to stress and drugs, neuronal myelination and macrophage behavior during inflammation and infection. We evaluate pro and cons of proprietary versus open-source methodologies for combining technologies into fully automated workflows of zebrafish studies. Zebrafish are poised to charge into HCS with ever-greater presence, bringing a new level of physiological context
An Empirically Derived Three-Dimensional Laplace Resonance in the Gliese 876 Planetary System
We report constraints on the three-dimensional orbital architecture for all
four planets known to orbit the nearby M dwarf Gliese 876 based solely on
Doppler measurements and demanding long-term orbital stability. Our dataset
incorporates publicly available radial velocities taken with the ELODIE and
CORALIE spectrographs, HARPS, and Keck HIRES as well as previously unpublished
HIRES velocities. We first quantitatively assess the validity of the planets
thought to orbit GJ 876 by computing the Bayes factors for a variety of
different coplanar models using an importance sampling algorithm. We find that
a four-planet model is preferred over a three-planet model. Next, we apply a
Newtonian MCMC algorithm to perform a Bayesian analysis of the planet masses
and orbits using an n-body model in three-dimensional space. Based on the
radial velocities alone, we find that a 99% credible interval provides upper
limits on the mutual inclinations for the three resonant planets
( for the "c" and "b" pair and for
the "b" and "e" pair). Subsequent dynamical integrations of our posterior
sample find that the GJ 876 planets must be roughly coplanar
( and ), suggesting the amount of
planet-planet scattering in the system has been low. We investigate the
distribution of the respective resonant arguments of each planet pair and find
that at least one argument for each planet pair and the Laplace argument
librate. The libration amplitudes in our three-dimensional orbital model
supports the idea of the outer-three planets having undergone significant past
disk migration.Comment: 19 pages, 11 figures, 8 tables. Accepted to MNRAS. Posterior samples
available at https://github.com/benelson/GJ87
The 55 Cancri Planetary System: Fully Self-Consistent N-body Constraints and a Dynamical Analysis
We present an updated study of the planets known to orbit 55 Cancri A using
1,418 high-precision radial velocity observations from four observatories
(Lick, Keck, Hobby-Eberly Telescope, Harlan J. Smith Telescope) and transit
time/durations for the inner-most planet, 55 Cancri "e" (Winn et al. 2011). We
provide the first posterior sample for the masses and orbital parameters based
on self-consistent n-body orbital solutions for the 55 Cancri planets, all of
which are dynamically stable (for at least years). We apply a GPU
version of Radial velocity Using N-body Differential evolution Markov Chain
Monte Carlo (RUN DMC; B. Nelson et al. 2014) to perform a Bayesian analysis of
the radial velocity and transit observations. Each of the planets in this
remarkable system has unique characteristics. Our investigation of high-cadence
radial velocities and priors based on space-based photometry yields an updated
mass estimate for planet "e" ( M), which affects its
density ( g cm) and inferred bulk composition.
Dynamical stability dictates that the orbital plane of planet "e" must be
aligned to within of the orbital plane of the outer planets (which we
assume to be coplanar). The mutual interactions between the planets "b" and "c"
may develop an apsidal lock about . We find 36-45% of all our model
systems librate about the anti-aligned configuration with an amplitude of
. Other cases showed short-term perturbations in the
libration of , circulation, and nodding, but we find the
planets are not in a 3:1 mean-motion resonance. A revised orbital period and
eccentricity for planet "d" pushes it further toward the closest known Jupiter
analog in the exoplanet population.Comment: 12 pages, 5 figures, 4 tables, accepted to MNRAS. Figure 2 (left) is
updated from published version. Posterior samples available at
http://www.personal.psu.edu/ben125/Downloads.htm
Timescales of variation in diversity and production of bacterioplankton assemblages in the Lower Mississippi River
Copyright: © 2020 Payne et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Rivers are characterized by rapid and continuous one-way directional fluxes of flowing, aqueous habitat, chemicals, suspended particles, and resident plankton. Therefore, at any particular location in such systems there is the potential for continuous, and possibly abrupt, changes in diversity and metabolic activities of suspended biota. As microorganisms are the principal catalysts of organic matter degradation and nutrient cycling in rivers, examination of their assemblage dynamics is fundamental to understanding system-level biogeochemical patterns and processes. However, there is little known of the dynamics of microbial assemblage composition or production of large rivers along a time interval gradient. We quantified variation in alpha and beta diversity and production of particle-associated and free-living bacterioplankton assemblages collected at a single site on the Lower Mississippi River (LMR), the final segment of the largest river system in North America. Samples were collected at timescales ranging from days to weeks to months up to a year. For both alpha and beta diversity, there were similar patterns of temporal variation in particle-associated and free-living assemblages. Alpha diversity, while always higher on particles, varied as much at a daily as at a monthly timescale. Beta diversity, in contrast, gradually increased with time interval of sampling, peaking between samples collected 180 days apart, before gradually declining between samples collected up to one year apart. The primary environmental driver of the temporal pattern in beta diversity was temperature, followed by dissolved nitrogen and chlorophyll a concentrations. Particle-associated bacterial production corresponded strongly to temperature, while free-living production was much lower and constant over time. We conclude that particle-associated and free-living bacterioplankton assemblages of the LMR vary in richness, composition, and production at distinct timescales in response to differing sets of environmental factors. This is the first temporal longitudinal study of microbial assemblage structure and dynamics in the LMR
Examining a Peak-Luminosity/Decline-Rate Relationship for Tidal Disruption Events
We compare the luminosity, radius, and temperature evolution of the
UV/optical blackbodies for 21 well-observed tidal disruption events (TDEs), 8
of which were discovered by the All-Sky Automated Survey for Supernovae. We
find that the blackbody radii generally increase prior to peak and slowly
decline at late times. The blackbody temperature evolution is generally flat,
with a few objects showing small-scale variations. The bolometric UV/optical
luminosities generally evolve smoothly and flatten out at late times. Finally,
we find an apparent correlation between the peak luminosity and the decline
rate of TDEs. This relationship is strongest when comparing the peak luminosity
to its decline over 40 days. A linear fit yields in cgs, where
.Comment: 10 pages, 4 figures. Updated to reflect changes made in the published
ApJL version. Six new objects added to sample. Updated video description can
be found at https://youtu.be/TtZU22eyHv
Revealing AGNs Through TESS Variability
We used Transiting Exoplanet Survey Satellite (TESS) data to identify 29
candidate active galactic nuclei (AGNs) through their optical variability. The
high-cadence, high-precision TESS light curves present a unique opportunity for
the identification of AGNs, including those not selected through other methods.
Of the candidates, we found that 18 have either previously been identified as
AGNs in the literature or could have been selected based on emission-line
diagnostics, mid-IR colors, or X-ray luminosity. AGNs in low-mass galaxies
offer a window into supermassive black hole (SMBH) and galaxy co-evolution and
8 of the 29 candidates have estimated black hole masses . The low-mass galaxies NGC 4395 and NGC 4449 are two of our
five "high-confidence" candidates. By applying our methodology to the entire
TESS main and extended mission datasets, we expect to identify 45 more
AGN candidates, of which 26 will be new and 8 will be in low-mass
galaxies.Comment: 21 pages, 17 figures, 6 tables. Will be submitted to AAS journals.
Comments welcom
TERMS Photometry of Known Transiting Exoplanets
The Transit Ephemeris Refinement and Monitoring Survey (TERMS) conducts
radial velocity and photometric monitoring of known exoplanets in order to
refine planetary orbits and predictions of possible transit times. This effort
is primarily directed towards planets not known to transit, but a small sample
of our targets consist of known transiting systems. Here we present precision
photometry for 6 WASP planets acquired during their transit windows. We perform
a Markov Chain Monte Carlo (MCMC) analysis for each planet and combine these
data with previous measurements to redetermine the period and ephemerides for
these planets. These observations provide recent mid-transit times which are
useful for scheduling future observations. Our results improve the ephemerides
of WASP-4b, WASP-5b and WASP-6b and reduce the uncertainties on the mid-transit
time for WASP-29b. We also confirm the orbital, stellar and planetary
parameters of all 6 systems.Comment: 12 pages; 6 figures; 9 tables; accepted for publication in AJ; two
references updated and minor improvements made to match the version to be
publishe
Chandra, HST/STIS, NICER, Swift, and TESS Detail the Flare Evolution of the Repeating Nuclear Transient ASASSN-14ko
ASASSN-14ko is a nuclear transient at the center of the AGN ESO 253-G003 that
undergoes periodic flares. Optical flares were first observed in 2014 by the
All-Sky Automated Survey for Supernovae (ASAS-SN) and their peak times are
well-modeled with a period of days and period derivative
of . Here we present ASAS-SN, Chandra, HST/STIS, NICER,
Swift, and TESS data for the flares that occurred in December 2020, April 2021,
July 2021, and November 2021. The HST/STIS UV spectra evolve from blue shifted
broad absorption features to red shifted broad emission features over 10
days. The Swift UV/optical light curves peaked as predicted by the timing
model, but the peak UV luminosities varied between flares and the UV flux in
July 2021 was roughly half the brightness of all other peaks. The X-ray
luminosities consistently decreased and the spectra became harder during the
UV/optical rise but apparently without changes in absorption. Finally, two
high-cadence TESS light curves from December 2020 and November 2018 showed that
the slopes during the rising and declining phases changed over time, which
indicates some stochasticity in the flare's driving mechanism. ASASSN-14ko
remains observationally consistent with a repeating partial tidal disruption
event, but, these rich multi-wavelength data are in need of a detailed
theoretical model.Comment: 25 pages, 14 figures, 4 tables; Submitted to ApJ, comments welcom
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