A model for predicting changes in the electrical conductivity, practical salinity, and absolute salinity of seawater due to variations in relative chemical composition

Salinity determination in seawater has been carried out for almost 30 years using the Practical Salinity Scale 1978. However, the numerical value of so-called practical salinity, computed from electrical conductivity, differs slightly from the true or absolute salinity, defined as the mass of dissolved solids per unit mass of seawater. The difference arises because more recent knowledge about the composition of seawater is not reflected in the definition of practical salinity, which was chosen to maintain historical continuity with previous measures, and because of spatial and temporal variations in the relative composition of seawater. Accounting for these spatial variations in density calculations requires the calculation of a correction factor δ<i>S</i><sub>A</sub>, which is known to range from 0 to 0.03 g kg<sup>−1</sup> in the world oceans. Here a mathematical model relating compositional perturbations to δ<i>S</i><sub>A</sub> is developed, by combining a chemical model for the composition of seawater with a mathematical model for predicting the conductivity of multi-component aqueous solutions. Model calculations for this estimate of δ<i>S</i><sub>A</sub>, denoted δ<i>S</i><sub>R</sub><sup>soln</sup>, generally agree with estimates of δ<i>S</i><sub>A</sub> based on fits to direct density measurements, denoted δ<i>S</i><sub>R</sub><sup>dens</sup>, and show that biogeochemical perturbations affect conductivity only weakly. However, small systematic differences between model and density-based estimates remain. These may arise for several reasons, including uncertainty about the biogeochemical processes involved in the increase in Total Alkalinity in the North Pacific, uncertainty in the carbon content of IAPSO standard seawater, and uncertainty about the haline contraction coefficient for the constituents involved in biogeochemical processes. This model may then be important in constraining these processes, as well as in future efforts to improve parameterizations for δ<i>S</i><sub>A</sub>

A global algorithm for estimating Absolute Salinity

The International Thermodynamic Equation of Seawater – 2010 has defined the thermodynamic properties of seawater in terms of a new salinity variable, Absolute Salinity, which takes into account the spatial variation of the composition of seawater. Absolute Salinity more accurately reflects the effects of the dissolved material in seawater on the thermodynamic properties (particularly density) than does Practical Salinity. <br><br> When a seawater sample has standard composition (i.e. the ratios of the constituents of sea salt are the same as those of surface water of the North Atlantic), Practical Salinity can be used to accurately evaluate the thermodynamic properties of seawater. When seawater is not of standard composition, Practical Salinity alone is not sufficient and the Absolute Salinity Anomaly needs to be estimated; this anomaly is as large as 0.025 g kg<sup>−1</sup> in the northernmost North Pacific. Here we provide an algorithm for estimating Absolute Salinity Anomaly for any location (<i>x, y, p</i>) in the world ocean. <br><br> To develop this algorithm, we used the Absolute Salinity Anomaly that is found by comparing the density calculated from Practical Salinity to the density measured in the laboratory. These estimates of Absolute Salinity Anomaly however are limited to the number of available observations (namely 811). In order to provide a practical method that can be used at any location in the world ocean, we take advantage of approximate relationships between Absolute Salinity Anomaly and silicate concentrations (which are available globally)

Improved Well Plugging Equipment and Waste Mangement Techniques Exceed Alara Goals at the Oak Ridge National Laboratory

In 2000, Bechtel Jacobs Company LLC (BJC) contracted Tetra Tech NUS, Inc. (TtNUS) and their sub-contractor, Texas World Operations, Inc. (TWO), to plug and abandon (P&A) 111 wells located in the Melton Valley area of Oak Ridge National Laboratory (ORNL). One hundred and seven of those wells were used to monitor fluid movement and subsurface containment of the low level radioactive liquid waste/grout slurry that was injected into the Pumpkin Valley Shale Formation, underlying ORNL. Four wells were used as hydrofracture injection wells to emplace the waste in the shale formation. Although the practice of hydrofracturing was and is considered by many to pose no threat to human health or the environment, the practice was halted in 1982 after the Federal Underground Injection Control regulations were enacted by United States Environmental Protection Agency (USEPA) making it necessary to properly close the wells. The work is being performed for the United States Department of Energy Oak Ridge Operations (DOE ORO). The project team is using the philosophy of minimum waste generation and the principles of ALARA (As Low As Reasonably Achievable) as key project goals to minimize personnel and equipment exposure, waste generation, and project costs. Achievement of these goals was demonstrated by the introduction of several new pieces of custom designed well plugging and abandonment equipment that were tested and used effectively during field operations. Highlights of the work performed and the equipment used are presented

Ocean Science Preface An historical perspective on the development of the Thermodynamic Equation of Seawater -2010

Abstract. Oceanography is concerned with understanding the mechanisms controlling the movement of seawater and its contents. A fundamental tool in this process is the characterization of the thermophysical properties of seawater as functions of measured temperature and electrical conductivity, the latter used as a proxy for the concentration of dissolved matter in seawater. For many years a collection of algorithms denoted the Equation of State 1980 (EOS-80) has been the internationally accepted standard for calculating such properties. However, modern measurement technology now allows routine observations of temperature and electrical conductivity to be made to at least one order of magnitude more accurately than the uncertainty in this standard. Recently, a new standard has been developed, the Thermodynamical Equation of Seawater 2010 (TEOS-10). This new standard is thermodynamically consistent, valid over a wider range of temperature and salinity, and includes a mechanism to account for composition variations in seawater. Here we review the scientific development of this standard, and describe the literature involved in its development, which includes many of the articles in this special issue

The effects of biogeochemical processes on oceanic conductivity/salinity/density relationships and the characterization of real seawater

As seawater circulates through the global ocean, its relative composition undergoes small variations. This results in changes to the conductivity/salinity/density relationship, which is currently well-defined only for Standard Seawater obtained from a particular area in the North Atlantic. These changes are investigated here by analysis of laboratory experiments in which salts are added to seawater, by analysis of oceanic observations of density and composition anomalies, and by mathematical investigation using a model relating composition, conductivity, and density of arbitrary seawaters. Mathematical analysis shows that understanding and describing the effect of changes in relative composition on operational estimates of salinity using the Practical Salinity Scale 1978 and on density using an equation of state for Standard Seawater require the use of a number of different salinity variables and a family of haline contraction coefficients. These salinity variables include an absolute salinity <i>S</i><sub>A</sub><sup>soln</sup>, a density salinity <i>S</i><sub>A</sub><sup>dens</sup>, the reference salinity <i>S</i><sub>R</sub>, and an added-mass salinity <i>S</i><sub>A</sub><sup>add</sup>. In addition, a new salinity variable <i>S</i><sub>∗</sub> is defined, which represents the preformed salinity of a Standard Seawater component to which biogeochemical processes add material. In spite of this complexity, observed correlations between different ocean biogeochemical processes allow the creation of simple formulas that can be used to convert between the different salinity and density measures, allowing for the operational reduction of routine oceanographic observations

Ancient crops provide first archaeological signature of the westward Austronesian expansion

The Austronesian settlement of the remote island of Madagascar remains one of the great puzzles of Indo-Pacific prehistory. Although linguistic, ethnographic, and genetic evidence points clearly to a colonization of Madagascar by Austronesian language-speaking people from Island Southeast Asia, decades of archaeological research have failed to locate evidence for a Southeast Asian signature in the island's early material record. Here, we present new archaeobotanical data that show that Southeast Asian settlers brought Asian crops with them when they settled in Africa. These crops provide the first, to our knowledge, reliable archaeological window into the Southeast Asian colonization of Madagascar. They additionally suggest that initial Southeast Asian settlement in Africa was not limited to Madagascar, but also extended to the Comoros. Archaeobotanical data may support a model of indirect Austronesian colonization of Madagascar from the Comoros and/or elsewhere in eastern Africa

Tidal controls on the flow of ice streams

The flow of many Antarctic ice streams is known to be significantly influenced by tides. In the past, modeling studies have implemented the tidal forces acting on a coupled ice stream/ice shelf system in a number of different ways, but the consequences that this has on the modeled response of ice streams to tides have, until now, not been considered. Here we investigate for the first time differences in model response that are only due to differences in the way tidal forcings are implemented. We find that attempts to simplify the problem by neglecting flexural stresses are generally not valid and forcing models with only changes in ocean back pressure will not capture either the correct amplitudes or length scale

Observations of tidal variability on the New England shelf

Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 109 (2004): C06010, doi:10.1029/2003JC001972.Observations from the Coastal Mixing and Optics experiment moored array, deployed from August 1996 through June 1997, are used to describe barotropic and baroclinic tidal variability over the New England shelf. The dominant M 2 tidal elevations decrease toward the northeast to a minimum over the Nantucket shoals (about 34 cm), and barotropic tidal current amplitudes increase strongly toward the northeast to a maximum over the shoals (about 35 cm s−1). Estimates of the depth-averaged M 2 momentum balance indicate that tidal dynamics are linear, and along-shelf pressure gradients are as large as cross-shelf pressure gradients. In addition, tidal current ellipses are weakly polarized, confirming that the dynamics are more complex than simple plane waves. The vertical structure of the M 2 currents decreases in amplitude and phase (phase lead near bottom) over the bottom 20 m. The M 2 momentum deficit near the bottom approximately matches direct covariance estimates of stress, confirming the effects of stress on current structure in the tidally driven bottom boundary layer. Baroclinic current variability at tidal frequencies is small (2 cm s−1 amplitude), with a predominantly mode 1 vertical structure. High-frequency (approaching the buoyancy frequency) internal solitons are observed following the pycnocline. The internal solitons switch from waves of depression to waves of elevation when the depth of maximum stratification is deeper than half the water column depth. Both low-mode baroclinic tidal and high-frequency internal wave energy decrease linearly with bottom depth across the shelf.Funding for the CMO experiment and subsequent analysis was provided by the Office of Naval Research under grants N00014-95-1-0339 and N00014-01-1-0140

Calculating Reynolds stresses from ADCP measurements in the presence of surface gravity waves using the cospectra-fit method

Author Posting. © American Meteorological Society, 2010. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Atmospheric and Oceanic Technology 27 (2010): 889-907, doi:10.1175/2009JTECHO682.1.Recently, the velocity observations of acoustic Doppler current profilers (ADCPs) have been successfully used to estimate turbulent Reynolds stresses in estuaries and tidal channels. However, the presence of surface gravity waves can significantly bias stress estimates, limiting application of the technique in the coastal ocean. This work describes a new approach to estimate Reynolds stresses from ADCP velocities obtained in the presence of waves. The method fits an established semiempirical model of boundary layer turbulence to the measured turbulent cospectra at frequencies below those of surface gravity waves to estimate the stress. Applied to ADCP observations made in weakly stratified waters and variable significant wave heights, estimated near-bottom and near-surface stresses using this method compared well with independent estimates of the boundary stresses in contrast to previous methods. Additionally, the vertical structure of tidal stress estimated using the new approach matched that inferred from a linear momentum balance at stress levels below the estimated stress uncertainties. Because the method makes an estimate of the horizontal turbulent length scales present as part of the model fit, these results can also enable a direct correction for the mean bias errors resulting from instrument tilt, if these scales are long relative to the beam separation.AK acknowledges support from the WHOI Coastal Ocean Institute, and SL acknowledges support from NSF Ocean Science Grant OCE-0548961