Lightning and charge processes in brown dwarf and exoplanet atmospheres

The study of the composition of brown dwarf atmospheres helped to understand their formation and evolution. Similarly, the study of exoplanet atmospheres is expected to constrain their formation and evolutionary states. We use results from 3D simulations, kinetic cloud formation and kinetic ion-neutral chemistry to investigate ionisation processes which will affect their atmosphere chemistry: The dayside of super-hot Jupiters is dominated by atomic hydrogen, and not H$_2$O. Such planetary atmospheres exhibit a substantial degree of thermal ionisation and clouds only form on the nightside where lightning leaves chemical tracers (e.g. HCN) for possibly long enough to be detectable. External radiation may cause exoplanets to be enshrouded in a shell of highly ionised, H$_3^+$-forming gas and a weather-driven aurora may emerge. Brown dwarfs enable us to study the role of electron beams for the emergence of an extrasolar, weather-system driven aurora-like chemistry, and the effect of strong magnetic fields on cold atmospheric gases. Electron beams trigger the formation of H$_3^+$ in the upper atmosphere of a brown dwarf (e.g. LSR-J1835) which may react with it to form hydronium, H$_3$O$^+$, as a longer lived chemical tracer. Brown dwarfs and super-hot gas giants may be excellent candidates to search for H$_3$O$^+$ as an H$_3^+$ product.Comment: 16 pages, accepted for publication in the Philosophical Transactions A of the Royal Society, (some typos corrected

Small hydrocarbon molecules in cloud-forming Brown Dwarf and giant gas planet atmospheres

We study the abundances of complex carbon-bearing molecules in the oxygen-rich dust- forming atmospheres of Brown Dwarfs and giant gas planets. The inner atmospheric re- gions that form the inner boundary for thermochemical gas-phase models are investigated. Results from Drift-phoenix atmosphere simulations, which include the feedback of phase- non-equilibrium dust cloud formation on the atmospheric structure and the gas-phase abun- dances, are utilised. The resulting element depletion leads to a shift in the carbon-to-oxygen ratio such that several hydrocarbon molecules and cyanopolycyanopolyynene molecules can be present. An increase in surface gravity and/or a decrease in metallicity support the increase in the partial pressures of these species. CO, CO2, CH4, and HCN contain the largest fraction of carbon. In the upper atmosphere of low-metallicity objects, more carbon is contained in C4H than in CO, and also CH3 and C2H2 play an increasingly important role as carbon-sink. We determine chemical relaxation time-scales to evaluate if hydrocarbon molecules can be affected by transport-induced quenching. Our results suggest that a considerable amount of C2H6 and C2H2 could be expected in the upper atmospheres not only of giant gas planets, but also of Brown Dwarfs. However, the exact quenching height strongly depends on the data source used. These results will have an impact on future thermo-kinetic studies, as they change the inner boundary condition for those simulations.Comment: 17 pages, 13 figures, 1 table, accepted to MNRA

Exo-lightning radio emission: the case study of HAT-P-11b

Lightning induced radio emission has been observed on solar system planets. Lecavelier des Etangs et al. [2013] carried out radio transit observations of the exoplanet HAT-P-11b, and suggested a tentative detection of a radio signal. Here, we explore the possibility of the radio emission having been produced by lightning activity on the exoplanet, following and expanding the work of Hodos\'an et al. [2016a]. After a summary of our previous work [Hodos\'an et al. 2016a], we extend it with a parameter study. The lightning activity of the hypothetical storm is largely dependent on the radio spectral roll-off, $n$, and the flash duration, $\tau_\mathrm{fl}$. The best-case scenario would require a flash density of the same order of magnitude as can be found during volcanic eruptions on Earth. On average, $3.8 \times 10^6$ times larger flash densities than the Earth-storms with the largest lightning activity is needed to produce the observed signal from HAT-P-11b. Combined with the results of Hodos\'an et al. [2016a] regarding the chemical effects of planet-wide thunderstorms, we conclude that future radio and infrared observations may lead to lightning detection on planets outside the solar system.Comment: Accepted to the Conference Proceedings of the 8th International Workshop on Planetary, Solar and Heliospheric Radio Emissions (PRE 8), held in Seggauberg near Leibnitz/Graz, Austria, October 25-27, 2016. 12 pages, 2 figure

Jupiter as a Giant Cosmic Ray Detector

We explore the feasibility of using the atmosphere of Jupiter to detect Ultra-High-Energy Cosmic Rays (UHECR's). The large surface area of Jupiter allows us to probe cosmic rays of higher energies than previously accessible. Cosmic ray extensive air showers in Jupiter's atmosphere could in principle be detected by the Large Area Telescope (LAT) on the Fermi observatory. In order to be observed, these air showers would need to be oriented toward the Earth, and would need to occur sufficiently high in the atmosphere that the gamma rays can penetrate. We demonstrate that, under these assumptions, Jupiter provides an effective cosmic ray "detector" area of $3.3 \times 10^7$ km$^2$. We predict that Fermi-LAT should be able to detect events of energy $>10^{21}$ eV with fluence $10^{-7}$ erg cm$^{-2}$ at a rate of about one per month. The observed number of air showers may provide an indirect measure of the flux of cosmic rays $\gtrsim 10^{20}$ eV. Extensive air showers also produce a synchrotron signature that may be measurable by ALMA. Simultaneous observations of Jupiter with ALMA and Fermi-LAT could be used to provide broad constraints on the energies of the initiating cosmic rays.Comment: 8 pages, 5 figures. Accepted for publication in the Astrophysical Journal Letter

Mediating exposure in public interactions

Mobile computing and public interactions together open up a new range of challenges in interaction design. To date a very gregarious model of interaction has been assumed. However, the public setting will invoke feelings of shyness and a desire to control the personal exposure associated with interactions. In this paper we discuss these issues and our initial tests of a system which affords a control beyond "engage or don't engage"

Nitrogen Oxide Concentrations in Natural Waters on Early Earth

A key challenge in origins-of-life studies is estimating the abundances of species relevant to the chemical pathways proposed to have contributed to the emergence of life on early Earth. Dissolved nitrogen oxide anions (NO$_{X}^{-}$), in particular nitrate (NO$_{3}^{-}$) and nitrite (NO$_{2}^{-}$), have been invoked in diverse origins-of-life chemistry, from the oligomerization of RNA to the emergence of protometabolism. Recent work has calculated the supply of NO$_{X}^{-}$ from the prebiotic atmosphere to the ocean, and reported steady-state [NO$_{X}^{-}$] to be high across all plausible parameter space. These findings rest on the assumption that NO$_{X}^{-}$ is stable in natural waters unless processed at a hydrothermal vent. Here, we show that NO$_{X}^{-}$ is unstable in the reducing environment of early Earth. Sinks due to UV photolysis and reactions with reduced iron (Fe$^{2+}$) suppress [NO$_{X}^{-}$] by several orders of magnitude relative to past predictions. For pH$=6.5-8$ and $T=0-50^\circ$C, we find that it is most probable that NO$_{X}^{-}$]$<1~\mu$M in the prebiotic ocean. On the other hand, prebiotic ponds with favorable drainage characteristics may have sustained [NO$_{X}^{-}$]$\geq 1~\mu$M. As on modern Earth, most NO$_{X}^{-}$ on prebiotic Earth should have been present as NO$_{3}^{-}$, due to its much greater stability. These findings inform the kind of prebiotic chemistries that would have been possible on early Earth. We discuss the implications for proposed prebiotic chemistries, and highlight the need for further studies of NO$_{X}^{-}$ kinetics to reduce the considerable uncertainties in predicting [NO$_{X}^{-}$] on early Earth.Comment: In review for publication at Geochemistry, Geophysics, and Geosystems (G-cubed). Comments, questions, and criticism solicited; please contact corresponding author at [email protected]. SI at: https://web-cert.mit.edu/sukrit/Public/nox_si.pdf. GitHub at: https://github.com/sukritranjan/no

Can comets deliver prebiotic molecules to rocky exoplanets?

In this work we consider the potential of cometary impacts to deliver complex organic molecules and the prebiotic building blocks required for life to rocky exoplanets. Numerical experiments have demonstrated that for these molecules to survive, impacts at very low velocities are required. This work shows that for comets scattered from beyond the snow-line into the habitable zone, the minimum impact velocity is always lower for planets orbiting Solar-type stars than M-dwarfs. Using both an analytical model and numerical N-body simulations, we show that the lowest velocity impacts occur onto planets in tightly-packed planetary systems around high-mass (i.e. Solar-mass) stars, enabling the intact delivery of complex organic molecules. Impacts onto planets around low-mass stars are found to be very sensitive to the planetary architecture, with the survival of complex prebiotic molecules potentially impossible in loosely-packed systems. Rocky planets around M-dwarfs also suffer significantly more high velocity impacts, potentially posing unique challenges for life on these planets. In the scenario that cometary delivery is important for the origins of life, this study predicts the presence of biosignatures will be correlated with i) decreasing planetary mass (i.e. escape velocity), ii) increasing stellar-mass, and iii) decreasing planetary separation (i.e. exoplanets in tightly-packed systems).Comment: Accepted by Proceedings A of the Royal Society. 17 pages, 5 figure

Prebiosignature Molecules Can Be Detected in Temperate Exoplanet Atmospheres with JWST

The search for biosignatures on exoplanets connects the fields of biology and biochemistry to astronomical observation, with the hope that we might detect evidence of active biological processes on worlds outside the solar system. Here we focus on a complementary aspect of exoplanet characterisation connecting astronomy to prebiotic chemistry: the search for molecules associated with the origin of life, prebiosignatures. Prebiosignature surveys in planetary atmospheres offer the potential to both constrain the ubiquity of life in the galaxy and provide important tests of current prebiotic syntheses outside of the laboratory setting. Here, we quantify the minimum abundance of identified prebiosignature molecules that would be required for detection by transmission spectroscopy using JWST. We consider prebiosignatures on five classes of terrestrial planet: an ocean planet, a volcanic planet, a post-impact planet, a super-Earth, and an early Earth analogue. Using a novel modelling and detection test pipeline, with simulated JWST noise, we find the detection thresholds of hydrogen cyanide (HCN), hydrogen sulfide (H2S), cyanoacetylene (HC3N), ammonia (NH3), methane (CH4), acetylene (C2H2), sulfur dioxide (SO2), nitric oxide (NO), formaldehyde (CH2O), and carbon monoxide (CO) in a variety of low mean molecular weight (<5) atmospheres. We test the dependence of these detection thresholds on M dwarf target star and the number of observed transits, finding that a modest number of transits (1-10) are required to detect prebiosignatures in numerous candidate planets, including TRAPPIST-1e with a high mean molecular weight atmosphere. We find that the NIRSpec G395M/H instrument is best suited for detecting most prebiosignatures.Comment: 28 pages, 12 figures, accepted for publication in A