Nanoscale electrochemistry of sp2 carbon materials: from graphite and graphene to carbon nanotubes

Carbon materials have a long history of use as electrodes in electrochemistry, from (bio)electroanalysis to applications in energy technologies, such as batteries and fuel cells. With the advent of new forms of nanocarbon, particularly, carbon nanotubes and graphene, carbon electrode materials have taken on even greater significance for electrochemical studies, both in their own right and as components and supports in an array of functional composites. With the increasing prominence of carbon nanomaterials in electrochemistry comes a need to critically evaluate the experimental framework from which a microscopic understanding of electrochemical processes is best developed. This Account advocates the use of emerging electrochemical imaging techniques and confined electrochemical cell formats that have considerable potential to reveal major new perspectives on the intrinsic electrochemical activity of carbon materials, with unprecedented detail and spatial resolution. These techniques allow particular features on a surface to be targeted and models of structure–activity to be developed and tested on a wide range of length scales and time scales. When high resolution electrochemical imaging data are combined with information from other microscopy and spectroscopy techniques applied to the same area of an electrode surface, in a correlative-electrochemical microscopy approach, highly resolved and unambiguous pictures of electrode activity are revealed that provide new views of the electrochemical properties of carbon materials. With a focus on major sp2 carbon materials, graphite, graphene, and single walled carbon nanotubes (SWNTs), this Account summarizes recent advances that have changed understanding of interfacial electrochemistry at carbon electrodes including: (i) Unequivocal evidence for the high activity of the basal surface of highly oriented pyrolytic graphite (HOPG), which is at least as active as noble metal electrodes (e.g., platinum) for outer-sphere redox processes. (ii) Demonstration of the high activity of basal plane HOPG toward other reactions, with no requirement for catalysis by step edges or defects, as exemplified by studies of proton-coupled electron transfer, redox transformations of adsorbed molecules, surface functionalization via diazonium electrochemistry, and metal electrodeposition. (iii) Rationalization of the complex interplay of different factors that determine electrochemistry at graphene, including the source (mechanical exfoliation from graphite vs chemical vapor deposition), number of graphene layers, edges, electronic structure, redox couple, and electrode history effects. (iv) New methodologies that allow nanoscale electrochemistry of 1D materials (SWNTs) to be related to their electronic characteristics (metallic vs semiconductor SWNTs), size, and quality, with high resolution imaging revealing the high activity of SWNT sidewalls and the importance of defects for some electrocatalytic reactions (e.g., the oxygen reduction reaction). The experimental approaches highlighted for carbon electrodes are generally applicable to other electrode materials and set a new framework and course for the study of electrochemical and interfacial processes

Parametric analysis of closed cycle magnetohydrodynamic (MHD) power plants

A parametric analysis of closed cycle MHD power plants was performed which studied the technical feasibility, associated capital cost, and cost of electricity for the direct combustion of coal or coal derived fuel. Three reference plants, differing primarily in the method of coal conversion utilized, were defined. Reference Plant 1 used direct coal fired combustion while Reference Plants 2 and 3 employed on site integrated gasifiers. Reference Plant 2 used a pressurized gasifier while Reference Plant 3 used a ""state of the art' atmospheric gasifier. Thirty plant configurations were considered by using parametric variations from the Reference Plants. Parametric variations include the type of coal (Montana Rosebud or Illinois No. 6), clean up systems (hot or cold gas clean up), on or two stage atmospheric or pressurized direct fired coal combustors, and six different gasifier systems. Plant sizes ranged from 100 to 1000 MWe. Overall plant performance was calculated using two methodologies. In one task, the channel performance was assumed and the MHD topping cycle efficiencies were based on the assumed values. A second task involved rigorous calculations of channel performance (enthalpy extraction, isentropic efficiency and generator output) that verified the original (task one) assumptions. Closed cycle MHD capital costs were estimated for the task one plants; task two cost estimates were made for the channel and magnet only

Government financial support for civil aircraft research, technology and development in four European countries and the United States

Data on the levels of government financial support for civil aircraft airframe and engine (CAAE) research and technology (R&T) in the United States and Europe (United Kingdom, West Germany, France and The Netherlands) and means of comparing these levels are provided. Data are presented for the years 1974-1977. European R&T expenditure data were obtained through visits to each of the four European countries, to the Washington office of the European Communities, and by a search of applicable literature. CAAE R&T expenditure data for the United States were obtained from NASA and Federal Aviation Administration (FAA)

Unmet need for the treatment of depression in Atlantic Canada

Objective: Most people with depression do not receive treatment, even though effective interventions are available. Population-based data can assist health service planners to improve access to mental health services. This study aimed to examine the determinants of untreated depression in Canada's Atlantic provinces

Method and apparatus for attaching physiological monitoring electrodes Patent

Adhesive spray process for attaching biomedical skin electrode

Comparative Planetary Atmospheres: Models of TrES-1 and HD209458b

We present new self-consistent atmosphere models for transiting planets TrES-1 and HD209458b. The planets were recently observed with the Spitzer Space Telescope in bands centered on 4.5 and 8.0 $\mu$m, for TrES-1, and 24 $\mu$m, for HD209458b. We find that standard solar metallicity models fit the observations for HD209458b. For TrES-1, which has an T_eff ~300 K cooler, we find that models with a metallicity 3-5 times enhanced over solar abundances can match the 1$\sigma$ error bar at 4.5 $\mu$m and 2$\sigma$ at 8.0$\mu$m. Models with solar abundances that included energy deposition into the stratosphere give fluxes that fall within the 2$\sigma$ error bars in both bands. The best-fit models for both planets assume that reradiation of absorbed stellar flux occurs over the entire planet. For all models of both planets we predict planet/star flux ratios in other Spitzer bandpasses.Comment: Accepted to the Astrophysical Journal Letters, May 17, 200

Effects of Planetary Wave-breaking on the Seasonal Variation of Total Column Ozone

The effects of planetary wave breaking on the seasonal variation of total column ozone are investigated using a zonally averaged chemical-radiative-transport model of the atmosphere. The planetary wave breaking effects of zonal wavenumbers k=1 and k=2 are significant in the middle latitude stratosphere during Northern Hemisphere (NH) winter, whereas only wave k=1 is important during Southern Hemisphere (SH) winter. The mixing and induced meridional circulation due to the planetary wave breaking increases the seasonal variation of total column ozone in NH (SH) middle latitudes by ∼20% (∼10%)