GMOR-like relation in IR-conformal gauge theories

A generalization of the GMOR relation to the case of infrared-conformal gauge theories is discussed. The starting point is the chiral Ward identity connecting the isovector pseudoscalar susceptibility to the chiral condensate, in a mass-deformed theory. A renormalization-group analysis shows that the pseudoscalar susceptibility is not saturated by the lightest state, but a contribution from the continuum part of the spectrum survives in the chiral limit. The computation also shows how infrared-conformal gauge theories behave differently, depending on whether the anomalous dimension of the chiral condensate be smaller or larger than 1.Comment: 28 pages, 1 PDF figur

Experimental and Numerical Studies on a Centrifugal Pump with 2D-Curved Blades in Cavitating Condition

In the presented study a special test-pump with 2D curvature blade geometry in cavitating and non-cavitating conditions was investigated using different experimental techniques and a 3D numerical model of cavitating flows. Experimental and numerical results concerning pump characteristics and performance breakdown were compared at different flow conditions. Appearing types of cavitation and the spatial distribution of vapour structures within the runner were also analysed

Anodic Alumina Membranes: From Electrochemical Growth to Use as Template for Fabrication of Nanostructured Electrodes

The great success of anodic alumina membranes is due to their morphological features coupled to both thermal and chemical stability. The electrochemical fabrication allows accurate control of the porous structure: in fact, the membrane morphological characteristics (pore length, pore diameter and cell density) can be controlled by adjusting the anodizing parameters (bath, temperature, voltage and time). This article deals with both the fabrication and use of anodic alumina membranes. In particular, we will show the specific role of the addition of aluminum ions to phosphoric acid-based anodizing solution in modifying the morphology of anodic alumina membranes. Anodic alumina membranes were obtained at −1◦ C in aqueous solutions of 0.4 M H3 PO4 added with different amounts of Al(OH)3 . For sake of completeness, the formation of PAA in pure 0.4 M H3 PO4 in otherwise identical conditions was also investigated. We found that the presence of Al(OH)3 in solution highly affects the morphology of the porous layer. In particular, at high Al(OH)3 concentration (close to saturation) more compact porous layers were formed with narrow pores separated by thick oxide. The increase in the electric charge from 20 to 160 C cm−2 also contributes to modifying the morphology of porous oxide. The obtained anodic alumina membranes were used as a template to fabricate a regular array of PdCo alloy nanowires that is a valid alternative to Pt for hydrogen evolution reaction. The PdCo alloy was obtained by electrodeposition and we found that the composition of the nanowires depends on the concentration of two metals in the deposition solution

Numerical and experimental investigations on the cavitating flow in a cascade of hydrofoils

The cavitating flow in a cascade of three hydrofoils was investigated by experimental means and numerical simulation. Experiments on the 2D-hydrofoils cascade were carried out at Darmstadt University of Technology in a rectangular test section of a cavitation tunnel. A numerical model developed at LEGI (Grenoble) to describe the unsteady behaviour of cavitation including the shedding of vapour structures was applied to the hydrofoils cascade geometry. Results of both experimental and numerical studies show a strong interaction between the cavities of each flow channel besides the typical self-oscillation of cloud cavitation. A detailed comparison of the results allows proposing an interpretation of the interaction mechanisms

Fabrication of CZTSe/CIGS Nanowire Arrays by One-Step Electrodeposition for Solar-Cell Application

The paper reports some preliminary results concerning the manufacturing process of CuZnSnSe (CZTSe) and CuInGaSe (CIGS) nanowire arrays obtained by one-step electrodeposition for p-n junction fabrication. CZTSe nanowires were obtained through electrodeposition in a polycarbonate membrane by applying a rectangular pulsed current, while their morphology was optimized by appropriately setting the potential and the electrolyte composition. The electrochemical parameters, including pH and composition of the solution, were optimized to obtain a mechanically stable array of nanowires. The samples were characterized by scanning electron microscopy, Raman spectroscopy, and energy-dispersion spectroscopy. The nanostructures obtained showed a cylindrical shape with an average diameter of about 230 nm and a length of about 3 m, and were interconnected due to the morphology of the polycarbonate membrane. To create the p-n junctions, first a thin film of CZTSe was electrodeposited to avoid direct contact between the ZnS and Mo. Subsequently, an annealing process was carried out at 500 °C in a S atmosphere for 40 min. The ZnS was obtained by chemical bath deposition at 95 °C for 90 min. Finally, to complete the cell, ZnO and ZnO:Al layers were deposited by magnetron-sputtering

Nanostructured Lead Electrodes with Reduced Graphene Oxide for High-Performance Lead–Acid Batteries

Nanostructured Pb electrodes consisting of nanowire arrays were obtained by electrodeposition, to be used as negative electrodes for lead–acid batteries. Reduced graphene oxide was added to improve their performances. This was achieved via the electrochemical reduction of graphene oxide directly on the surface of nanowire arrays. The electrodes with and without reduced graphene oxide were tested in a 5 M sulfuric acid solution using a commercial pasted positive plate and an absorbed glass mat separator in a zero-gap configuration. The electrodes were tested in deep cycling conditions with a very low cut-off potential. Charge–discharge tests were performed at 5C. The electrode with reduced graphene oxide outperformed the electrode without reduced graphene oxide, as it was able to work with a very high utilization of active mass and efficiency. A specific capacity of 258 mAhg−1–very close to the theoretical one–was achieved, and the electrode lasted for more than 1000 cycles. On the other hand, the electrode without reduced graphene oxide achieved a capacity close to 230 mAhg−1, which corresponds to a 90% of utilization of active mass

High-performance lead-acid batteries enabled by Pb and PbO2 nanostructured electrodes: Effect of operating temperature

Lead-acid batteries are now widely used for energy storage, as result of an established and reliable technology. In the last decade, several studies have been carried out to improve the performance of this type of batteries, with the main objective to replace the conventional plates with innovative electrodes with improved stability, increased capacity and a larger active surface. Such studies ultimately aim to improve the kinetics of electrochemical conversion reactions at the electrode-solution interface and to guarantee a good electrical continuity during the repeated charge/discharge cycles. To achieve these objectives, our contribution focuses on the employment of nanostructured electrodes. In particular, we have obtained nanostructured electrodes in Pb and PbO2 through electrosynthesis in a template consisting of a nanoporous polycarbonate membrane. These electrodes are characterized by a wider active surface area, which allows for a better use of the active material, and for a consequent increased specific energy compared to traditional batteries. In this research, the performance of lead-acid batteries with nanostructured electrodes was studied at 10 C at temperatures of 25, −20 and 40 °C in order to evaluate the efficiency and the effect of temperature on electrode morphology. The batteries were assembled using both nanostructured electrodes and an AGM-type separator used in commercial batteries

Modulation of endothelial organelle size as an antithrombotic strategy

BACKGROUND: It is long-established that Von Willebrand Factor (VWF) is central to haemostasis and thrombosis. Endothelial VWF is stored in cell-specific secretory granules, Weibel-Palade bodies (WPBs), organelles generated in a wide range of lengths (0.5 to 5.0 μm). WPB size responds to physiological cues and pharmacological treatment, and VWF secretion from shortened WPBs dramatically reduces platelet and plasma VWF adhesion to an endothelial surface. OBJECTIVE: We hypothesised that WPB-shortening represented a novel target for antithrombotic therapy. Our objective was to determine whether compounds exhibiting this activity do exist. METHODS: Using a microscopy approach coupled to automated image analysis, we measured the size of WPB bodies in primary human endothelial cells treated with licensed compounds for 24 h. RESULTS AND CONCLUSIONS: A novel approach to identification of antithrombotic compounds generated a significant number of candidates with the ability to shorten WPBs. In vitro assays of two selected compounds confirm that they inhibit the pro-haemostatic activity of secreted VWF. This set of compounds acting at a very early stage of the haemostatic process could well prove to be a useful adjunct to current antithrombotic therapeutics. Further, in the current SARS-CoV-2 pandemic, with a considerable fraction of critically ill COVID-19 patients affected by hypercoagulability, these WPB size-reducing drugs might also provide welcome therapeutic leads for frontline clinicians and researchers