Growth and Characterization of PDMS-Stamped Halide Perovskite Single Microcrystals

Recently, halide perovskites have attracted considerable attention for optoelectronic applications, but further progress in this field requires a thorough understanding of the fundamental properties of these materials. Studying perovskites in their single-crystalline form provides a model system for building such an understanding. In this work, a simple solution-processed method combined with PDMS (polydimethyl­siloxane) stamping was used to prepare thin single microcrystals of halide perovskites. The method is general for a broad array of materials including CH₃NH₃PbBr₃, CH₃NH₃PbCl₃, CH₃NH₃Pb­(Br_0.5Cl_0.5)₃, CH₃NH₃Pb­(Br_0.75Cl_0.25)₃, CsPbBr₃, Cs₃Bi₂Br₉, and Cs₃Bi₂I₉. Electron backscatter diffraction (EBSD) was used to investigate the microstructure of the crystals. In order to characterize the microcrystals of CH₃NH₃PbBr₃ electrically, the crystals were grown on prefabricated electrodes creating single-crystal devices contacted from the back. This back-contacted platform circumvents the incompatibility between halide perovskites and the aqueous chemistry used in standard microfabriation processes. It also allows <i>in situ</i> characterization of the perovskite crystal while it operates as a microscopic solar cell

Perovskite Nanowire Extrusion

The defect tolerance of halide perovskite materials has led to efficient optoelectronic devices based on thin-film geometries with unprecedented speed. Moreover, it has motivated research on perovskite nanowires because surface recombination continues to be a major obstacle in realizing efficient nanowire devices. Recently, ordered vertical arrays of perovskite nanowires have been realized, which can benefit from nanophotonic design strategies allowing precise control over light propagation, absorption, and emission. An anodized aluminum oxide template is used to confine the crystallization process, either in the solution or in the vapor phase. This approach, however, results in an unavoidable drawback: only nanowires embedded inside the AAO are obtainable, since the AAO cannot be etched selectively. The requirement for a support matrix originates from the intrinsic difficulty of controlling precise placement, sizes, and shapes of free-standing nanostructures during crystallization, especially in solution. Here we introduce a method to fabricate free-standing solution-based vertical nanowires with arbitrary dimensions. Our scheme also utilizes AAO; however, in contrast to embedding the perovskite inside the matrix, we apply a pressure gradient to extrude the solution from the free-standing templates. The exit profile of the template is subsequently translated into the final semiconductor geometry. The free-standing nanowires are single crystalline and show a PLQY up to ∼29%. In principle, this rapid method is not limited to nanowires but can be extended to uniform and ordered high PLQY single crystalline perovskite nanostructures of different shapes and sizes by fabricating additional masking layers or using specifically shaped nanopore endings