Influence of electrospun nanofibers on the interlaminar properties of unidirectional epoxy resin/glass fiber composite laminates

Nylon 6,6 nanofibers were interleaved in the mid-plane of glass fiber/epoxy matrix composite laminates for Mode I and II fracture mechanic tests. The present study investigates the effect of the nanofibers on the laminates' mechanical response. Results showed that Nylon 6,6 nanofibers improved specimen's fracture mechanic behavior: the initial energy release rates GIC and GIIC increased 62% and 109%, respectively, when nanofibrous interlayer was used. Scanning electron microscope micrographs showed that nanofiber bridging mechanism enhances performances of the nanomodified specimens, still able to link the layers when the matrix is broken

Toughening behavior of carbon/epoxy laminates interleaved by PSF/PVDF composite nanofibers

This paper presents an investigation on fracture behavior of carbon/epoxy composite laminates interleaved with electrospun nanofibers. Three different mats were manufactured and interleaved, using only polyvinylidene fluoride (PVDF), only polysulfone (PSF), and their combination. Mode-I and Mode-II fracture mechanics tests were conducted on virgin and nanomodified samples, and the results showed that PVDF and PSF nanofibers enhance the Mode-I critical energy release rate (GIC) by 66% and 51%, respectively, while using a combination of the two registered a 78% increment. The same phenomenon occurred under Mode-II loading. SEM micrographs were taken, to investigate the toughening mechanisms provided by the nanofibers

Focus on the Use of Resveratrol in Bladder Cancer

Bladder cancer is the most common tumor of the urinary system, with a high incidence in the male population. Surgery and intravesical instillations can eradicate it, although recurrences are very common, with possible progression. For this reason, adjuvant therapy should be considered in all patients. Resveratrol displays a biphasic dose response both in vitro and in vivo (intravesical application) with an antiproliferative effect at high concentrations and antiangiogenic action in vivo (intraperitoneal application) at a low concentration, suggesting a potential role for it in clinical management as an adjuvant to conventional therapy. In this review, we examine the standard therapeutical approach to bladder cancer and the preclinical studies that have investigated resveratrol in xenotransplantation models of bladder cancer. Molecular signals are also discussed, with a particular focus on the STAT3 pathway and angiogenic growth factor modulation

Damage assessment based on general signal correlation : Application for delamination diagnosis in composite structures

This work presents a Vibration-Based Structural Health Monitoring (VSHM) technique which is developed and applied for delamination assessment in composite laminate structures. It suggests the mutual information as a measure for nonlinear signal cross correlation. The mutual information between two signals measured on a vibrating structure is suggested as a damage metric and its application for the purposes of damage assessment is discussed and compared to the application of the traditional linear signal cross-correlation. The cross correlation is capable to detect linear dependence between two signals and thus can be used for diagnosing damage on linearly vibrating structures. On the other hand the mutual information is a nonlinear metric, and it is shown that it can detect linear as well as nonlinear signal dependence and thus it is particularly appropriate for structures with nonlinear dynamic behaviour and for composite structures as such. The application of the mutual information as a damage metric is demonstrated and discussed first for the case of a simple 2 DOF system with a nonlinear stiffness. Eventually the application of the suggested damage metric is developed and demonstrated for the purposes of delamination diagnosis in a composite laminate beam

Electrospun nanofibrous interleaves in composite laminate materials

The present work aims for investigate the influence of electrospun Nylon 6,6 nanofibrous mat on the behavior of composite laminates. The main idea is that nanofibrous interleaved into particular ply-to-ply interfaces of a laminate can lead to significant improvements of mechanical properties and delamination/damage resistance. Experimental campaigns were performed to investigate how nanofibers affect both the static and dynamic behavior of the laminate in which they are interleaved. Mode I and Mode II fracture mechanics tests were initially performed on virgin and 8 different configuration of nanomodified specimens. The purposes of this first step of the work are (1) to understand which geometrical parameters of the nanointerleave influence the behavior of the laminate and, (2) to find the optimal architecture of the nanofibrous mat in order to obtain the best reinforcement. In particular, 3 morphological parameters are investigated: nanofibers diameter, nanofibers orientation and thickness of the reinforce. Two different values for each parameter have been used, and it leads to 8 different configurations of nanoreinforce. Acoustic Emission technique is also used to monitor the tests. Once the optimum configuration has been found, attention is focused on the mechanism of reinforce played by the nanofibers during static and dynamic tests. Low velocity impacts and free decay tests are performed to attest the effect of nanointerlayers and the reinforce mechanism during the dynamic loads. Bump tests are performed before and after the impact on virgin and two different nanomodified laminates configurations. The authors focused their attention on: vibrational behavior, low velocity impact response and post impact vibration behavior of the nano-interleaved laminates with respect to the response of non-nanomodified ones. Experiments attest that nanofibers significantly strength the delamination resistance of the laminates and increase some of their mechanical properties, such as energy absorbing capability, GIC, maximum stress before material crisis, absorbed energy during impact and residual strength. It is demonstrated that the nanofibers are capable to continue to carry on the loads even when the matrix around them is broken

Delamination assessment in structures made of composites based on general signal correlation

This paper considers a vibration-based damage assessment approach which is based on the general idea for signal cross-correlation. Here the method is demonstrated and validated on a composite laminate beam and it is applied for the purposes of delamination assessment in composite structures. The method uses two measures of cross-correlation between two vibration signals measured in different points on the structure in order to diagnose the delamination. The linear cross-correlation as well as a new measure for nonlinear cross-correlation, the mutual information, are introduced and applied for the purposes of delamination assessment. The delamination assessment is based on the comparison of the measures for the healthy and the damaged state of the structure. In this study the method is applied using the free decay responses of the beam. Two delamination indexes are introduced and they are used for the purposes of delamination detection and localization