1,176 research outputs found
Solitonic approach to the dimerization problem in correlated one-dimensional systems
Using exact diagonalizations we consider self-consistently the lattice
distortions in odd Peierls-Hubbard and spin-Peierls periodic rings in the
adiabatic harmonic approximation. From the tails of the inherent spin soliton
the dimerization d_\infty of regular even rings is found by extrapolations to
infinite ring lengths. Considering a wide region of electron-electron onsite
interaction values U>0 compared with the band width 4t_0 at intermediately
strong electron-phonon interaction g, known relationships obtained by other
methods are reproduced and/or refined within one unified approach: such as the
maximum of d_\infty at U \simeq 3 t_0 for g \simeq 0.5 and its shift to zero
for g \to g_c \approx 0.7. The hyperbolic tangent shape of the spin soliton is
retained for any U and g <~ 0.6. In the spin-Peierls limit the d_\infty are
found to be in agreement with results of DMRG computations.Comment: 4 pages, 4 figures, Physical Review B, Rapid Communications, v. 56
(1997) accepte
Sub-cycle optical control of current in a semiconductor: from the multiphoton to the tunneling regime
Nonlinear interactions between ultrashort optical waveforms and solids can be
used to induce and steer electric current on a femtosecond (fs) timescale,
holding promise for electronic signal processing at PHz frequencies [Nature
493, 70 (2013)]. So far, this approach has been limited to insulators,
requiring extremely strong peak electric fields and intensities. Here, we show
all-optical generation and control of directly measurable electric current in a
semiconductor relevant for high-speed and high-power (opto)electronics, gallium
nitride (GaN), within an optical cycle and on a timescale shorter than 2 fs, at
intensities at least an order of magnitude lower than those required for
dielectrics. Our approach opens the door to PHz electronics and metrology,
applicable to low-power (non-amplified) laser pulses, and may lead to future
applications in semiconductor and photonic integrated circuit technologies
Intelligent Financial Fraud Detection Practices: An Investigation
Financial fraud is an issue with far reaching consequences in the finance
industry, government, corporate sectors, and for ordinary consumers. Increasing
dependence on new technologies such as cloud and mobile computing in recent
years has compounded the problem. Traditional methods of detection involve
extensive use of auditing, where a trained individual manually observes reports
or transactions in an attempt to discover fraudulent behaviour. This method is
not only time consuming, expensive and inaccurate, but in the age of big data
it is also impractical. Not surprisingly, financial institutions have turned to
automated processes using statistical and computational methods. This paper
presents a comprehensive investigation on financial fraud detection practices
using such data mining methods, with a particular focus on computational
intelligence-based techniques. Classification of the practices based on key
aspects such as detection algorithm used, fraud type investigated, and success
rate have been covered. Issues and challenges associated with the current
practices and potential future direction of research have also been identified.Comment: Proceedings of the 10th International Conference on Security and
Privacy in Communication Networks (SecureComm 2014
Genuine converging solution of self-consistent field equations for extended many-electron systems
Calculations of the ground state of inhomogeneous many-electron systems
involve a solving of the Poisson equation for Coulomb potential and the
Schroedinger equation for single-particle orbitals. Due to nonlinearity and
complexity this set of equations, one believes in the iterative method for the
solution that should consist in consecutive improvement of the potential and
the electron density until the self-consistency is attained. Though this
approach exists for a long time there are two grave problems accompanying its
implementation to infinitely extended systems. The first of them is related
with the Poisson equation and lies in possible incompatibility of the boundary
conditions for the potential with the electron density distribution. The
analysis of this difficulty and suggested resolution are presented for both
infinite conducting systems in jellium approximation and periodic solids. It
provides the existence of self-consistent solution for the potential at every
iteration step due to realization of a screening effect. The second problem
results from the existence of continuous spectrum of Hamiltonian eigenvalues
for unbounded systems. It needs to have a definition of Hilbert space basis
with eigenfunctions of continuous spectrum as elements, which would be
convenient in numerical applications. The definition of scalar product
specifying the Hilbert space is proposed that incorporates a limiting
transition. It provides self-adjointness of Hamiltonian and, respectively, the
orthogonality of eigenfunctions corresponding to the different eigenvalues. In
addition, it allows to normalize them effectively to delta-function and to
prove in the general case the orthogonality of the 'right' and 'left'
eigenfunctions belonging to twofold degenerate eigenvalues.Comment: 12 pages. Reported on Interdisciplinary Workshop "Nonequilibrium
Green's Functions III", August 22 - 26, 2005, University Kiel, Germany. To be
published in Journal of Physics: Conference Series, 2006; Typos in Eqs. (37),
(53) and (54) are corrected. The content of the footnote is changed.
Published version available free online at
http://www.iop.org/EJ/abstract/1742-6596/35/1/01
The Nature of Electronic States in Atomically Thin MoS2 Field-Effect Transistors
We present low temperature electrical transport experiments in five field
effect transistor devices consisting of monolayer, bilayer and trilayer MoS2
films, mechanically exfoliated onto Si/SiO2 substrate. Our experiments reveal
that the electronic states in all films are localized well up to the room
temperature over the experimentally accessible range of gate voltage. This
manifests in two dimensional (2D) variable range hopping (VRH) at high
temperatures, while below \sim 30 K the conductivity displays oscillatory
structures in gate voltage arising from resonant tunneling at the localized
sites. From the correlation energy (T0) of VRH and gate voltage dependence of
conductivity, we suggest that Coulomb potential from trapped charges in the
substrate are the dominant source of disorder in MoS2 field effect devices,
which leads to carrier localization as well.Comment: 10 pages, 5 figures; ACS Nano (2011
Mechanistic insights into the reversible lithium storage in an open porous carbon via metal cluster formation in all solid-state batteries
Porous carbons are promising anode materials for next generation lithium batteries due to their large lithium storage capacities. However, their high voltage slope during lithiation and delithiation as well as capacity fading due to intense formation of solid electrolyte interphase (SEI) limit their gravimetric and volumetric energy densities. Herein we compare a microporous carbide-derived carbon material (MPC) as promising future anode for all solid-state batteries with a commercial high-performance hard carbon anode. The MPC obtains high and reversible lithiation capacities of 1000 mAh g−1carbon in half-cells exhibiting an extended plateau region near 0 V vs. Li/Li+ preferable for full-cell application. The well-defined micro porosity of the MPC with a specific surface area of >1500 m2 g−1 combines well with the argyrodite-type electrolyte (Li6PS5Cl) suppressing extensive SEI formation to deliver high coulombic efficiencies. Preliminary full-cell measurements vs. nickel-rich NMC-cathodes (LiNi0.9Co0.05Mn0.05O2) provide a considerably improved average potential of 3.76 V leading to a projected energy density as high as 449 Wh kg−1 and reversible cycling for more than 60 cycles. 7Li Nuclear Magnetic Resonance spectroscopy was combined with ex-situ Small Angle X-ray Scattering to elucidate the storage mechanism of lithium inside the carbon matrix. The formation of extended quasi-metallic lithium clusters after electrochemical lithiation was revealed
A crystalline, 2D polyarylimide cathode for ultrastable and ultrafast Li storage
Organic electrode materials are of long‐standing interest for next‐generation sustainable lithium‐ion batteries (LIBs). As a promising cathode candidate, imide compounds have attracted extensive attention due to their low cost, high theoretical capacity, high working voltage, and fast redox reaction. However, the redox active site utilization of imide electrodes remains challenging for them to fulfill their potential applications. Herein, the synthesis of a highly stable, crystalline 2D polyarylimide (2D‐PAI) integrated with carbon nanotube (CNT) is demonstrated for the use as cathode material in LIBs. The synthesized polyarylimide hybrid (2D‐PAI@CNT) is featured with abundant π‐conjugated redox‐active naphthalene diimide units, a robust cyclic imide linkage, high surface area, and well‐defined accessible pores, which render the efficient utilization of redox active sites (82.9%), excellent structural stability, and fast ion diffusion. As a consequence, high rate capability and ultrastable cycle stability (100% capacity retention after 8000 cycles) are achieved in the 2D‐PAI@CNT cathode, which far exceeds the state‐of‐the‐art polyimide electrodes. This work may inspire the development of novel organic electrodes for sustainable and durable rechargeable batteries
Establishing a meaningful human rights due diligence process for corporations : learning from experience of human rights impact assessment
The United Nations Special Representative of the Secretary-General on Business and Human Rights, Professor John Ruggie, has constructed a new international framework, which is set to become the cornerstone for all action on human rights and business at the international level. The principle of human rights due diligence (HRDD) is the central component of the corporate duty to respect human rights within that framework. This article argues that Ruggie's HRDD principle contains the majority of the core procedural elements that a reasonable human rights impact assessment (HRIA) process should incorporate. It is likely that the majority of corporations will adopt HRIA as a mechanism for meeting their due diligence responsibilities. However, in the context of the contentious debate around corporate human rights performance, the current state of the art in HRIA gives rise to concerns about the credibility and robustness of likely practice. Additional requirements are therefore essential if HRDD is to have a significant impact on corporate human rights performance – requirements in relation to transparency; external participation and verification; and independent monitoring and review
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