Numerical model for solar thermal collectors and thermal energy storages based on phase change slurry

The efficiency of conventional solar thermal collectors and related thermal energy storages is often reduced by the requirement for high irradiation levels and the heat losses due to the relatively high temperature of the heat transfer fluid. In order to overcome those limitations, a solar thermal system capable of working at low temperatures through the exploitation of latent heat storage is presented in this paper. The proposed system was based on a novel heat transfer fluid and storage media, composed by a mixture of water and micro-encapsulated phase change material (PCM), named Phase Change Slurry (PCS). This paper introduces a numerical model capable of accurately describe the physical process and the dynamics of the proposed technology (collector, thermal energy storage and control logics). Results were validated by means of experimental tests and a long-term monitoring on a real full-scale prototype. Furthermore, experimental tests were performed to carry out the actual PCS thermo-dynamical properties that are strongly dependent on the concentration of micro-capsules in the heat transfer fluid

Ecotoxicity of basil (Ocimum Basilicum) extract in aquaculture feeds: Is it really eco-safe for the aquatic environment?

Plant extract and essential oils are gaining application in aquaculture, but data about their environmental impact are limited and their potential effects on aquatic organisms are largely unknown. For this study, ecotoxicity tests were performed under standardized conditions on fish feed supplemented with 3 % w/w of a basil supercritical extract (F1-BEO; substance A), F1-BEO extract (substance B), and fish feed without F1-BEO extract (substance C) on three model species of different trophic levels (bacteria, primary producer, primary consumer) considered representative for freshwater (Aliivibrio fischeri, Raphidocelis subcapitata, Daphnia magna) and marine (A. fischeri, Phaeodactylum tricornutum, Paracentrotus lividus) ecosystems. Ecotoxicological response was largely comparable within the same trophic level (whichever the ecosystem). EC50 was not calculable in the concentration range here tested (3.9–500 mg/L) for freshwater and marine microalgae, suggesting that none of the substances were toxic for primary producers. Reduction of A. fischeri bioluminescence at the tested concentration (0.5–10 mg/L) was observed only for substance A (EC50 9.53 mg/L and 9 mg/L for freshwater and marine ecosystems, respectively). Notably, in P. lividus embryotoxicity was higher for substances A (EC50 1.80 mg/L) and C (EC50 4.6 mg/L) than for substance B (EC50 7.10 mg/L), suggesting a toxic effect due to feed dissolution. In contrast, substance B was more toxic (EC50 0.34 mg/L) in D. magna than substances A (EC50 3.98 mg/L) and C (EC50 5.50 mg/L). Based on the Globally Harmonized System of Classification and Labelling of Chemicals, all substances were categorized Acute 2, except for substance A which was categorized Acute 1 for D. magna. Overall, the substances were found to be potentially toxic for an aquatic ecosystem, especially for primary consumer. Further study of plant extract and essential oils is needed to better understand their effects and fate on the aquatic environment

First Insights Into Trace Element Accumulation by Philoscia affinis (Crustacea, Isopoda): a Novel Tracer to Assess Soil Contamination in Lowland Plains?

Isopods are terrestrial invertebrates that accumulate trace elements in large quantities, thus providing information on levels of soil contamination. However, the accumulation pattern seems to be species dependent. For this study, specimens of Philoscia affinis (Isopoda, Oniscidea) and soil samples were collected from both a protected area (site 1) and urban roadside (site 2) in the low plain of Friuli-Venezia Giulia (northeast Italy) to determine whether P. affinis could serve as a potential candidate for monitoring soil contamination. To do this, the following objectives were achieved: a) the level of trace elements (Al, Cd, Cu, Fe, Hg, Mn, Pb, Zn) were detected in soils and isopods; 2) the difference in trace elements accumulation was compared in the two sampling sites; 3) the bioaccumulation factor (BAF) was calculated for each element. With some exceptions, trace element concentrations were higher in both isopods and soil samples from the urban roadside compared to the protected area. Furthermore, except for Cd, Cu, and Zn, trace element levels were higher in the soil than in the isopod samples. The higher mean BAF values were recorded for Cd (6.169 and 6.974 for site 1 and 2, respectively), Cu (10.324 and 11.452 for site 1 and 2, respectively), and Zn (1.836 and 2: 1.943 for site 1 and 2, respectively), whereas BAF values <1 were recorded for the other elements. Philoscia affinis was found to be a potential candidate to monitor soil contamination as a macro-concentrator of Cu and Cd and a micro-concentrator of Zn

Recent and subfossil diatom assemblages as indicators of environmental change (including fish introduction) in a high-mountain lake

We investigated modern-littoral and subfossil sediment-core diatoms in the shallow (max depth 6.4 m) high-mountain Lake Balma in the Orsiera Rocciavrè Nature Park (Italian Western Alps). Our study provided evidence that might be related to the response of diatom assemblages to fish introduction, in particular the decreasing of the nutrient-enrichment sensitive low-profile life-form/ecological guild and the increase in species known to react positively to the augmented nutrient availability due to fish excretions (e.g., Fragilaria nanana, Pseudostaurosira brevistriata, Staurosirella neopinnata). We are, however, aware that some of these effects could as well have been caused by pastures and cattle watering, and by increased temperatures due to global warming, and we acknowledge the typical complex-interaction pattern among different stressors. High-mountain lakes are ‘‘early warning systems’’ for the whole alpine system and can contribute valuable information also on the interactions between environmental global changes and anthropogenic impacts. Benthic diatoms, in particular, can provide useful indications on the deleterious effects of non-native fish introduction, cattle grazing, and global warming, and thus support an adaptive and sustainable management of high-mountain lakes for the sake of nature conservation

Mussel watch program for microplastics in the Mediterranean sea: Identification of biomarkers of exposure using Mytilus galloprovincialis

Microplastics (MPs) are ubiquitous pollutants that have also been detected in the aquatic ecosystems at high concentrations. The use of shellfish as bioindicators is widespread for assessing and monitoring the environmental quality in both freshwater and marine environments. On this path, biomarkers represent an effective tool in monitoring programs. This minireview would broaden the existing knowledge on biomarkers of MPs in the Mediterranean mussel Mytilus galloprovincialis. This species was selected as it is widely distributed across the Mediterranean Sea and used as a bioindicator to monitor the presence of MPs in the marine environment. The literature search returned only 11 studies, mainly related to oxidative stress biomarkers. Although certain biomarkers were explored to estimate the effects of MPs on M. galloprovincialis, a battery of standardized and validated biomarkers as well as the inclusion of new ones are needed in future studies to obtain more comparable and robust findings across the Mediterranean Sea

Unusual localization of pennella sp. In swordfish (xiphias gladius) hearts

The genus Pennella comprises hematophagous parasites of marine aquatic species, including cephalopods, marine mammals, and pelagic fish. Nine species have been officially included in the genus Pennella plus another six species inquirendae. They are most often found in the host’s musculature, without penetrating internal organs. For the present study, 83 hearts from swordfish (Xiphias gladius) caught in the Mediterranean Sea were sampled and immediately fixed in formalin for histopathological analysis. In total, 10 (12.05%) hearts were found to be parasitized by copepods of the genus Pennella. Macroscopically, there was mild-to-severe fibrinous pericarditis with atrial wall thickening and multiple parasitic nodules. Histologically, the parasitic nodules were surrounded by an inflammatory-necrotizing reaction. Parasitic infestation by Pennella spp. is common in pelagic fish and in swordfish, in particular. Here, however, we report atypical cardiac localization. A future area of focus is the evaluation of cardiac Pennella spp. infestation by histopathology and genetic identification of the parasites

Assessment of Biological and Sanitary Condition of Alien Fish from a High-Mountain Lake (Cottian Alps)

This study aimed to assess the biological and sanitary conditions of alien fish in a high-mountain lake (Balma Lake) located in the Cottian Alps. A single fish sampling session (August 2018) using gillnets collected 90 specimens of brook trout (Salvelinus fontinalis). Sex and age were determined (59 females and 31 males, age class 0+ to 4+). Regression analysis showed no difference in total weight and total length between males and females (ANCOVA: F = 0.453; p = 0.954). The mean condition factor (Kmean) decreased with increasing age for males and females. Terrestrial insects were the main prey found in the fish stomachs. The parasitological exam was negative, and the bacteriological exam was positive for Carnobacterium maltaromaticum and C. divergens in 33% of specimens. The total mercury, cadmium, and lead concentration in muscle tissue was within the maximum limit established by the European Commission for human consumption. The brook trout population was found to be well structured; these findings may help local administrations in the implementation of eradication measures