Effect of fibre treatments on interfacial shear strength of hemp fibre reinforced polylactide and unsaturated polyester composites

Surface treatment of hemp fibres was investigated as a means of improving interfacial shear strength (IFSS) of hemp fibre reinforced polylactide (PLA) and unsaturated polyester (UPE) composites. Fibres were treated with sodium hydroxide, acetic anhydride, maleic anhydride and silane. A combined treatment using sodium hydroxide and silane was also carried out. IFSS of PLA/hemp fibre samples increased after treatment, except in the case of maleic anhydride treatment. Increased IFSS could be explained by better bonding of PLA with treated fibres and increased PLA transcrystallinity. The highest IFSS was 11.4 MPa which was obtained for the PLA/alkali treated fibre samples. IFSS of UPE/hemp fibre samples increased for all treated fibres. This is believed to be due to the improvement of chemical bonding between the treated fibres and the UPE as supported by FT-IR results. The highest IFSS (20.3 MPa) was found for the combined sodium hydroxide and silane treatment fibre/UPE samples

Curing kinetics and effects of fibre surface treatment and curing parameters on the interfacial and tensile properties of hemp/epoxy composites

The curing kinetics of neat epoxy (NE) and hemp fibre/epoxy composites was studied and assessed using two dynamic models (the Kissinger and Flynn-Wall-Ozawa Models) and an isothermal model (the Autocatalytic Model) which was generally supported by the experimental data obtained from dynamic and isothermal differential scanning calorimetry (DSC) scans. The activation energies for the curing of composites exhibited lower values compared to curing of NE which is believed to be due to higher nucleophilic activity of the amine groups of the curing agent in the presence of fibres. The highest tensile strength, σ was obtained with composites produced with an epoxy to curing agent ratio of 1:1 and the highest Young's modulus, E was obtained with an epoxy to curing agent ratio of 1:1.2. Alkali treated hemp fibre/epoxy (ATFE) composites were found to have higher σ and E values compared to those for untreated hemp fibre/epoxy (UTFE) composites which was consistent with the trend for interfacial shear strength (IFSS) values. Composites σ and E were found to be higher for a processing temperature of 70°C than for 25°C for both UTFE and ATFE composites, but were found to decrease as the curing temperature was increased further to 120°C

Carbonisation of biomass-derived chars and the thermal reduction of a graphene oxide sample studied using Raman spectroscopy

Chars and carbonised chars were produced from three different oxygen-rich precursors (Pinus radiata wood, Phormium tenax leaf fibres, and sucrose crystals). These non-graphitisable carbons were analysed with Raman spectroscopy in order to study the nanostructural development which occurs with increasingly severe heat treatments up to approximately 1000 °C. The thermal reduction of a graphene oxide sample was similarly studied, as this is considered to involve the development of nanometre-scale graphene-like domains within a different oxygen-rich precursor. Increasing the heat treatment temperatures used in the charring and carbonisation processes, led to significant changes in a number of parameters measured in the Raman spectra. Correlations based on these parameter changes could have future applications in evaluating various char samples and estimating the heat treatment temperatures employed during their manufacture. After production heat treatment temperatures exceeded 700 °C, the Raman spectra of the carbonised chars appeared to be largely precursor independent. The spectra of these carbonised chars were similar to the spectra obtained from thermally-reduced graphene oxides, especially when compared to a wide range of other carbonaceous materials analysed using this particular methodology. Partial reduction of a graphene oxide sample due to reasonably mild laser exposures during Raman analysis was also observed

Influence of accelerated ageing on the physico-mechanical properties of alkali-treated industrial hemp fibre reinforced poly(lactic acid) (PLA) composites

30 wt% aligned untreated long hemp fibre/PLA (AUL) and aligned alkali treated long hemp fibre/PLA (AAL) composites were produced by film stacking and subjected to accelerated ageing. Accelerated ageing was carried out using UV irradiation and water spray at 50 °C for four different time intervals (250, 500, 750 and 1000 h). After accelerated ageing, tensile strength (TS), flexural strength, Young's modulus (YM), flexural modulus and mode I fracture toughness (KIc) were found to decrease and impact strength (IS) was found to increase for both AUL and AAL composites. AUL composites had greatest overall reduction in mechanical properties than that for AAL composites upon exposure to accelerated ageing environment. FTIR analysis and crystallinity contents of the accelerated aged composites support the results of the deterioration of mechanical properties upon exposure to accelerated ageing environment

Influence of loading rate, alkali fibre treatment and crystallinity on fracture toughness of random short hemp fibre reinforced polylactide bio-composites

Plane-strain fracture toughness (KIc) of random short hemp fibre reinforced polylactide (PLA) bio-composites was investigated along with the effect of loading rate, fibre treatment and PLA crystallinity. Fracture toughness testing was carried out at loading rates varying from 0.5 to 20 mm/min using single-edge-notched bending specimens with 0 to 30 wt% fibre. KQ (trial KIc) of composites decreased as loading rate increased, until stabilising to give KIc values at a loading rate of 10 mm/min and higher. The reduction of crazing and stress whitening, as well as a more direct crack path observed in PLA samples combined with reduced plastic deformation observed in composites provided explanation for this reduction. KIc of composites was found to decrease with increased fibre content and fibre treatment with sodium hydroxide. Studies controlling the degree of PLA crystallinity by heat treatment or “annealing” showed that reduction of KIc can be attributed to increased crystallinity

Analysis of rheological behaviour of titanium feedstocks formulated with a water-soluble binder system for powder injection moulding

Binder selection and formulation are critical in powder injection moulding. Binders play a key role in controlling the rheological properties of a feedstock and influence whether the resulting feedstock can be successfully injection moulded, debound and sintered without defects. A four-step process was used to mix hydride-dehydride titanium alloy (processed) powder (Ti-6Al-4 V) with a polyethylene glycol (PEG) based water soluble binder system. The rheological properties, including flow behaviour index, flow activation energy, fluidity and melt flow index of the homogeneous feedstock, were determined with a capillary rheometer. All feedstock formulations exhibited shear thinning flow behaviour. The optimum feedstock consisting of 60 vol.% powder content, 32 vol.% PEG, 6 vol.% polyvinyl butyryl and 2 vol.% stearic acid was suitable for titanium injection moulding

Using Geomagnetics to Identify a Previously unrecognized Fault within the Olympic Penninsula

The most prominent geologic feature in the Olympic Peninsula is the Crescent Formation. The Crescent Formation (CF) is a massive unit of basalt up to 18 km thick which was accreted 52-48Ma. The Blue Mountain Unit (BMU) is a unit of continentally derived sediments which has previously been believed to be the sedimentary basement upon which the Crescent Formation (CF) was deposited ~50 Ma.(Fig.1) Recent research conducted by Prof. Ken Clark, Michael Eddy, Michael Polenz and multiple UPS grads found discontinuities which suggest that the BMU and CF are not part to the same coherent unit. Previous work suggests that a chemical and temporal discontinuity indicative of a major fault exists between the CF and the BMU. This study aimed to discover geophysical and geochemical evidence of this fault between the CF and BMU in the eastern Olympics. (Fig.1) This previously unidentified thrust fault is herein referred to as the Dusk Point Fault (DPF

Studying carbonisation with raman spectroscopy

Raman spectroscopy can provide fast and non-destructive analysis of carbonaceous materials. As it is able to detect nanometre-sized structural features, Raman spectroscopy is widely used in the study of carbon nanotubes, fullerenes, graphenes, and many other carbon-rich materials. Raman analysis has previously shown potential for estimating the heat treatment temperatures (HTT) employed in the preparation of Japanese cedar charcoals which suggested future usefulness in quality control . In the current work, Raman spectroscopy was used to investigate the nanostructural development which had occurred within various chars prepared and carbonised at a range of heat treatment temperatures between ≈ 340°C and 1000°C. Chars were produced from sucrose sugar as standard precursor of high purity and two sources of biomass common in New Zealand (Radiata pine wood and Harakeke leaf fibres). In chars produced at lower HTTs, signals could be detected which were interpreted as representing hydrogen-rich amorphous carbon structures. In contrast, the Raman spectra of well-carbonised chars produced at higher HTTs featured signals consistent with graphene-like structures with coherent domains limited in size to below a few nanometres across. Measurement of such signals provides the ability to evaluate the extent of nanostructural development, identify char samples which are ‘undercooked’ when compared to other char samples, and estimate effective HTTs used in the production of a given char sample. More detailed Raman analysis of Radiata-derived chars was carried out, including analysis of chars produced from carbonising pyrolysis tars. Results of Raman analysis were correlated to H/C atom ratios obtained through elemental analysis for these chars produced from Radiata pine

The Bright and the Dark Side of Malin 1

Malin 1 has long been considered a prototype giant, dark matter dominated Low Surface Brightness galaxy. Two recent studies, one based on a re-analysis of VLA HI observations and the other on an archival Hubble I-band image, throw a new light on this enigmatic galaxy and on its dark/luminous matter properties.Comment: 4 pages, 3 figures, to appear in the Proceedings of the 41st ESLAB Symposium "The Impact of HST on European Astronomy", 29 May to 1 June 2007, ESTEC, Noordwijk, N