Influence of Particle Size on Optical Constants From Pellets Measured With Terahertz Pulsed Spectroscopy

Particle size is shown to influence both the overall value and the measurement precision of the refractive index and absorption coefficient of a sample diluted with high density polyethylene (HDPE) powder and compressed in a pellet. However, excessive grinding of a sample before it is mixed with HDPE powder can result in the formation of large particle clusters. These aggregates can induce internal scattering of the terahertz pulse within the pellet as well as lead to different mechanical properties of the pellet, which may change the distribution of air pores. These phenomena result in extracted optical constants with low accuracy and precision. The present work introduces a simple experimental procedure to improve the precision and accuracy of optical constants from spectroscopic pellets. This procedure consists of moderately grinding the sample powder in fine HDPE powder with a pestle and mortar. The standard deviation of the refractive index of Prussian blue has been observed to reduce from 0.14 to 0.02 following this procedure

Contrast in Terahertz Images of Archival Documents-Part II: Influence of Topographic Features

We investigate the potential of terahertz time-domain imaging in reflection mode to reveal archival information in documents in a non-invasive way. In particular, this study explores the parameters and signal processing tools that can be used to produce well-contrasted terahertz images of topographic features commonly found in archival documents, such as indentations left by a writing tool, as well as sieve lines. While the amplitude of the waveforms at a specific time delay can provide the most contrasted and legible images of topographic features on flat paper or parchment sheets, this parameter may not be suitable for documents that have a highly irregular surface, such as water- or fire-damaged documents. For analysis of such documents, cross-correlation of the time-domain signals can instead yield images with good contrast. Analysis of the frequency-domain representation of terahertz waveforms can also provide well-contrasted images of topographic features, with improved spatial resolution when utilising high-frequency content. Finally, we point out some of the limitations of these means of analysis for extracting information relating to topographic features of interest from documents

Contrast in Terahertz Images of Archival Documents—Part I: Influence of the Optical Parameters from the Ink and Support

This study aims to objectively inform curators when terahertz time-domain (TD) imaging set in reflection mode is likely to give well-contrasted images of inscriptions in a complex archival document and is a useful non-invasive alternative to current digitisation processes. To this end, the dispersive refractive indices and absorption coefficients from various archival materials are assessed and their influence on contrast in terahertz images from historical documents is explored. Sepia ink and inks produced with bistre or verdigris mixed with a solution of Arabic gum or rabbit skin glue are unlikely to lead to well-contrasted images. However, dispersions of bone black, ivory black, iron gall ink, malachite, lapis lazuli, minium and vermilion are likely to lead to well-contrasted images. Inscriptions written with lamp black, carbon black and graphite give the best imaging results. The characteristic spectral signatures from iron gall ink, minium and vermilion pellets between 5 and 100 cm−1 relate to a ringing effect at late collection times in TD waveforms transmitted through these pellets. The same ringing effect can be probed in waveforms reflected from iron gall, minium and vermilion ink deposits at the surface of a document. Since TD waveforms collected for each scanning pixel can be Fourier-transformed into spectral information, terahertz TD imaging in reflection mode can serve as a hyperspectral imaging tool. However, chemical recognition and mapping of the ink is currently limited by the fact that the morphology of the document influences more the terahertz spectral response of the document than the resonant behaviour of the ink

Coating and Density Distribution Analysis of Commercial Ciprofloxacin Hydrochloride Monohydrate Tablets by Terahertz Pulsed Spectroscopy and Imaging

Terahertz pulsed spectroscopy was used to qualitatively detect ciprofloxacin hydrochloride monohydrate (CPFX·HCl·H2O) in tablets, and terahertz pulsed imaging (TPI) was used to scrutinize not only the coating state but also the density distribution of tablets produced by several manufacturers. TPI was also used to evaluate distinguishability among these tablets. The same waveform, which is a unique terahertz absorption spectrum derived from pure CPFX·HCl·H2O, was observed in all of the crushed tablets and in pure CPFX·HCl·H2O. TPI can provide information about the physical states of coated tablets. Information about the uniformity of parameters such as a coating thickness and density can be obtained. In this study, the authors investigated the coating thickness distributions of film-coated CPFX·HCl·H2O from four different manufacturers. Unique terahertz images of the density distributions in these commercial tablets were obtained. Moreover, B-scan (depth) images show the status of the coating layer in each tablet and the density map inside the tablets. These features would reflect differences resulting from different tablet-manufacturing processes

Quantum Rings in Electromagnetic Fields

This is the author accepted manuscript. The final version is available from Springer via the DOI in this recordThis chapter is devoted to optical properties of so-called Aharonov-Bohm quantum rings (quantum rings pierced by a magnetic flux resulting in AharonovBohm oscillations of their electronic spectra) in external electromagnetic fields. It studies two problems. The first problem deals with a single-electron AharonovBohm quantum ring pierced by a magnetic flux and subjected to an in-plane (lateral) electric field. We predict magneto-oscillations of the ring electric dipole moment. These oscillations are accompanied by periodic changes in the selection rules for inter-level optical transitions in the ring allowing control of polarization properties of the associated terahertz radiation. The second problem treats a single-mode microcavity with an embedded Aharonov-Bohm quantum ring which is pierced by a magnetic flux and subjected to a lateral electric field. We show that external electric and magnetic fields provide additional means of control of the emission spectrum of the system. In particular, when the magnetic flux through the quantum ring is equal to a half-integer number of the magnetic flux quanta, a small change in the lateral electric field allows for tuning of the energy levels of the quantum ring into resonance with the microcavity mode, thus providing an efficient way to control the quantum ring-microcavity coupling strength. Emission spectra of the system are discussed for several combinations of the applied magnetic and electric fields