53,178 research outputs found
Enhanced Optical Dichroism of Graphene Nanoribbons
The optical conductivity of graphene nanoribbons is analytical and exactly
derived. It is shown that the absence of translation invariance along the
transverse direction allows considerable intra-band absorption in a narrow
frequency window that varies with the ribbon width, and lies in the THz range
domain for ribbons 10-100nm wide. In this spectral region the absorption
anisotropy can be as high as two orders of magnitude, which renders the medium
strongly dichroic, and allows for a very high degree of polarization (up to
~85) with just a single layer of graphene. The effect is resilient to level
broadening of the ribbon spectrum potentially induced by disorder. Using a
cavity for impedance enhancement, or a stack of few layer nanoribbons, these
values can reach almost 100%. This opens a potential prospect of employing
graphene ribbon structures as efficient polarizers in the far IR and THz
frequencies.Comment: Revised version. 10 pages, 7 figure
Improvement of the upflow anaerobic sludge blanket reactor performance for azo dye reduction by the presence of low amounts of activated carbon
Activated carbon (AC) was investigated as redox mediator of the azo dye Acid Orange 10 (AO10) anaerobic biodegradation in a laboratory scale Upflow Anaerobic Sludge Blanket (UASB). During reactor operation, the effect of AC concentration and the hydraulic retention time (HRT) were investigated and better results were obtained with 0.15 g of AC per g of Volatile Suspended Solids (VSS) and 10 h, respectively. In the mediated reactor, with an HRT of 10 h, high colour and COD removal was obtained, ~70% and ~85%, respectively. In the control, thought similar COD removal, AO10 decolourisation was only 20%, evidencing the ability of AC to accelerate the reduction reactions in continuous reactors
Anaerobic biotransformation of nitroanilines enhanced by the presence of low amounts of carbon materials
Three microporous activated carbons -original (AC0), chemical oxidized with HNO3 (ACHNO3) and thermal treated (ACH2)-, and three mesoporous carbons - xerogels (CXA and CXB) and nanotubes (CNT)-, were tested on the biological reduction of o-, m- and p-nitroaniline (NoA) at a concentration above the half maximal inhibitory concentration (IC50) for a methanogenic consortium degrading a mixture of volatile fatty acids (VFA) containing acetate, propionate and butyrate. NoAs were only partially reduced in the absence of carbon materials (CM). Rates were dependent on the nitro group position, increasing in the order metha>para>ortho. CM lead to NoAs almost total reduction and at higher rates. With AC0 and ACH2, rates increased 3-fold, 4-fold and 8 fold for o-, m- and p-NoA, respectively
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