Sequestration of Martian CO2 by mineral carbonation

Carbonation is the water-mediated replacement of silicate minerals, such as olivine, by carbonate, and is commonplace in the Earth’s crust. This reaction can remove significant quantities of CO2 from the atmosphere and store it over geological timescales. Here we present the first direct evidence for CO2 sequestration and storage on Mars by mineral carbonation. Electron beam imaging and analysis show that olivine and a plagioclase feldspar-rich mesostasis in the Lafayette meteorite have been replaced by carbonate. The susceptibility of olivine to replacement was enhanced by the presence of smectite veins along which CO2-rich fluids gained access to grain interiors. Lafayette was partially carbonated during the Amazonian, when liquid water was available intermittently and atmospheric CO2 concentrations were close to their present-day values. Earlier in Mars’ history, when the planet had a much thicker atmosphere and an active hydrosphere, carbonation is likely to have been an effective mechanism for sequestration of CO2

Origin of acidic surface waters and the evolution of atmospheric chemistry on early Mars

Observations from in situ experiments and planetary orbiters have shown that the sedimentary rocks found at Meridiani Planum, Mars were formed in the presence of acidic surface waters. The water was thought to be brought to the surface by groundwater upwelling, and may represent the last vestiges of the widespread occurrence of liquid water on Mars. However, it is unclear why the surface waters were acidic. Here we use geochemical calculations, constrained by chemical and mineralogical data from the Mars Exploration Rover Opportunity, to show that Fe oxidation and the precipitation of oxidized iron (Fe^(3+)) minerals generate excess acid with respect to the amount of base anions available in the rocks present in outcrop. We suggest that subsurface waters of near-neutral pH and rich in Fe^(2+) were rapidly acidified as iron was oxidized on exposure to O_2 or photo-oxidized by ultraviolet radiation at the martian surface. Temporal variation in surface acidity would have been controlled by the availability of liquid water, and as such, low-pH fluids could be a natural consequence of the aridification of the martian surface. Finally, because iron oxidation at Meridiani would have generated large amounts of gaseous H_2, ultimately derived from the reduction of H_2O, we conclude that surface geochemical processes would have affected the redox state of the early martian atmosphere

Lost cold Antarctic deserts inferred from unusual sulfate formation and isotope signatures

The Antarctic ice cap significantly affects global ocean circulation and climate. Continental glaciogenic sedimentary deposits provide direct physical evidence of the glacial history of the Antarctic interior, but these data are sparse. Here we investigate a new indicator of ice sheet evolution: sulfates within the glaciogenic deposits from the Lewis Cliff Ice Tongue of the central Transantarctic Mountains. The sulfates exhibit unique isotope signatures, including I 34 S up to +50‰ for mirabilite evaporites, I " 17 O up to +2.3‰ for dissolved sulfate within contemporary melt-water ponds, and extremely negative I 18 O as low as a '22.2‰. The isotopic data imply that the sulfates formed under environmental conditions similar to todaya € s McMurdo Dry Valleys, suggesting that ice-free cold deserts may have existed between the South Pole and the Transantarctic Mountains since the Miocene during periods when the ice sheet size was smaller than today, but with an overall similar to modern global hydrological cycle

The Mawrth Vallis Region of Mars: A Potential Landing Site for the Mars Science Laboratory (MSL) Mission

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Groundwater activity on Mars and implications for a deep biosphere

By the time eukaryotic life or photosynthesis evolved on Earth, the martian surface had become extremely inhospitable, but the subsurface of Mars could potentially have contained a vast microbial biosphere. Crustal fluids may have welled up from the subsurface to alter and cement surface sediments, potentially preserving clues to subsurface habitability. Here we present a conceptual model of subsurface habitability of Mars and evaluate evidence for groundwater upwelling in deep basins. Many ancient, deep basins lack evidence for groundwater activity. However, McLaughlin Crater, one of the deepest craters on Mars, contains evidence for Mg-Fe-bearing clays and carbonates that probably formed in an alkaline, groundwater-fed lacustrine setting. This environment strongly contrasts with the acidic, water-limited environments implied by the presence of sulphate deposits that have previously been suggested to form owing to groundwater upwelling. Deposits formed as a result of groundwater upwelling on Mars, such as those in McLaughlin Crater, could preserve critical evidence of a deep biosphere on Mars. We suggest that groundwater upwelling on Mars may have occurred sporadically on local scales, rather than at regional or global scales. © 2013 Macmillan Publishers Limited. All rights reserved.Link_to_subscribed_fulltex