Light weight fire resistant graphite composites

Composite structures with a honeycomb core and characterized by lightweight and excellent fire resistance are provided. These sandwich structures employ facesheets made up of bismaleimide-vinyl styrylpyridine copolymers with fiber reinforcement such as carbon fiber reinforcement. In preferred embodiments the facesheets are over layered with a decorative film. The properties of these composites make them attractive materials of construction aircraft and spacecraft

Sources of Guns to Dangerous People: What We Learn By Asking Them

Gun violence exacts a lethal toll on public health. This paper focuses on reducing access to firearms by dangerous offenders, contributing original empirical data on the gun transactions that arm offenders in Chicago. Conducted in the fall of 2013, analysis of an open-ended survey of 99 inmates of Cook County Jail focuses on a subset of violence-prone individuals with the goal of improving law enforcement actions. Among our principal findings:Our respondents (adult offenders living in Chicago or nearby) obtain most of their guns from their social network of personal connections. Rarely is the proximate source either direct purchase from a gun store, or theft.Only about 60% of guns in the possession of respondents were obtained by purchase or trade. Other common arrangements include sharing guns and holding guns for others.About one in seven respondents report selling guns, but in only a few cases as a regular source of income.Gangs continue to play some role in Chicago in organizing gun buys and in distributing guns to members as needed.The Chicago Police Department has a considerable effect on the workings of the underground gun market through deterrence. Transactions with strangers and less-trusted associates are limited by concerns over arrest risk (if the buyer should happen to be an undercover officer or a snitch), and about being caught with a "dirty" gun (one that has been fired in a crime)

Magnetic Cataclysmic Variable Accretion Flows

We have used a magnetic accretion model to investigate the accretion flows of magnetic cataclysmic variables (mCVs) throughout a range of parameter space. The results of our numerical simulations demonstrate that broadly four types of flow are possible: discs, streams, rings and propellers. We show that the equilibrium spin periods in asynchronous mCVs, for a given orbital period and magnetic moment, occur where the flow changes from a type characterised by spin-up (i.e. disc or stream) to one characterised by spin-down (i.e. propeller or ring). 'Triple points' occur in the plane of spin-to-orbital period ratio versus magnetic moment, at which stream-disc-propeller flows or stream-ring-propeller flows can co-exist. The first of these is identified as corresponding to when the corotation radius is equal to the circularisation radius, and the second as where the corotation radius is equal to the distance from white dwarf to the L1 point. If mCVs are accreting at their equilibrium spin rates, then for a mass ratio of 0.5, those with Pspin/Porb < 0.1 will be disc-like, those with 0.1 < Pspin/Porb < 0.5 will be stream-like, and those with Pspin/Porb ~ 0.5 will be ring-like. In each case, some material is also lost from the binary in order to maintain angular momentum balance. The spin to orbital period ratio at which the systems transition between these flow types decreases as the mass ratio of the stellar components increases, and vice versa

The Role of Functional, Social, and Mobility Dynamics in Facilitating Older African Americans Participation in Clinical Research

Purpose: Older African Americans experience disproportionately higher incidence of morbidity and mortality related to chronic and infectious diseases, yet are significantly underrepresented in clinical research compared to other racial and ethnic groups. This study aimed to understand the extent to which social support, transportation access, and physical impediments function as barriers or facilitators to clinical trial recruitment of older African Americans. Methods: Participants (N=221) were recruited from six African American churches in Atlanta and surveyed on various influences on clinical trial participation

Cosmological Acceleration Through Transition to Constant Scalar Curvature

As shown by Parker and Raval, quantum field theory in curved spacetime gives a possible mechanism for explaining the observed recent acceleration of the universe. This mechanism, which differs in its dynamics from quintessence models, causes the universe to make a transition to an accelerating expansion in which the scalar curvature, R, of spacetime remains constant. This transition occurs despite the fact that we set the renormalized cosmological constant to zero. We show that this model agrees very well with the current observed type-Ia supernova (SNe-Ia) data. There are no free parameters in this fit, as the relevant observables are determined independently by means of the current cosmic microwave background radiation (CMBR) data. We also give the predicted curves for number count tests and for the ratio, w(z), of the dark energy pressure to its density, as well as for dw(z)/dz versus w(z). These curves differ significantly from those obtained from a cosmological constant, and will be tested by planned future observations.Comment: 31 pages, 7 figures; to appear in ApJ. Corrected numerical results; described quantum basis of theory; 18 references added; 2 figures adde

Direct versus Delayed pathways in Strong-Field Non-Sequential Double Ionization

We report full-dimensionality quantum and classical calculations for double ionization of laser-driven helium at 390 nm. Good qualitative agreement is observed. We show that the classical double ionization trajectories can be divided into two distinct pathways: direct and delayed. The direct pathway, with an almost simultaneous ejection of both electrons, emerges from small laser intensities. With increasing intensity its relative importance, compared to the delayed ionization pathway, increases until it becomes the predominant pathway for total electron escape energy below around 5.25 $U_{p}$. However the delayed pathway is the predominant one for double ionization above a certain cut-off energy at all laser intensities

Effect of longitudinal surface finish on elastohydrodynamic lubrication

The effect of longitudinal-lay surface finish on the elastohydrodynamic film thickness and the percentage of film between rolling disks in contact were evaluated using a rolling disk apparatus. Film thickness was measured by transmitted X-rays, and percentage of film was monitored by an alternating-current continuity circuit. Disk finish was varied on both the crowned upper disk and the cylindrical lower disk. A type-2 ester and a synthetic paraffinic oil were used as lubricants. It was shown that the roughness with longitudinal lay has a deleterious effect on both film thickness and percentage of film. Measured film thicknesses for the two lubricants were comparable at equivalent test conditions. The percentage of film where a change in surface topography was observed was approximately 20 percent for the synthetic paraffinic oil and 10 percent for the type-2 ester

Absence of strong magnetic fluctuations in the iron phosphide superconductors LaFePO and Sr2ScO3FeP

We report neutron inelastic scattering measurements on polycrystalline LaFePO and Sr2ScO3FeP, two members of the iron phosphide families of superconductors. No evidence is found for any magnetic fluctuations in the spectrum of either material in the energy and wavevector ranges probed. Special attention is paid to the wavevector at which spin-density-wave-like fluctuations are seen in other iron-based superconductors. We estimate that the magnetic signal, if present, is at least a factor of four (Sr2ScO3FeP) or seven (LaFePO) smaller than in the related iron arsenide and chalcogenide superconductors. These results suggest that magnetic fluctuations are not as influential on the electronic properties of the iron phosphide systems as they are in other iron-based superconductors.Comment: 7 pages, 5 figure

The Generation of Magnetic Fields Through Driven Turbulence

We have tested the ability of driven turbulence to generate magnetic field structure from a weak uniform field using three dimensional numerical simulations of incompressible turbulence. We used a pseudo-spectral code with a numerical resolution of up to $144^3$ collocation points. We find that the magnetic fields are amplified through field line stretching at a rate proportional to the difference between the velocity and the magnetic field strength times a constant. Equipartition between the kinetic and magnetic energy densities occurs at a scale somewhat smaller than the kinetic energy peak. Above the equipartition scale the velocity structure is, as expected, nearly isotropic. The magnetic field structure at these scales is uncertain, but the field correlation function is very weak. At the equipartition scale the magnetic fields show only a moderate degree of anisotropy, so that the typical radius of curvature of field lines is comparable to the typical perpendicular scale for field reversal. In other words, there are few field reversals within eddies at the equipartition scale, and no fine-grained series of reversals at smaller scales. At scales below the equipartition scale, both velocity and magnetic structures are anisotropic; the eddies are stretched along the local magnetic field lines, and the magnetic energy dominates the kinetic energy on the same scale by a factor which increases at higher wavenumbers. We do not show a scale-free inertial range, but the power spectra are a function of resolution and/or the imposed viscosity and resistivity. Our results are consistent with the emergence of a scale-free inertial range at higher Reynolds numbers.Comment: 14 pages (8 NEW figures), ApJ, in press (July 20, 2000?

Inelastic neutron scattering studies of methyl chloride synthesis over alumina

Not only is alumina the most widely used catalyst support material in the world, it is also an important catalyst in its own right. One major chemical process that uses alumina in this respect is the industrial production of methyl chloride. This is a large scale process (650 000 metric tons in 2010 in the United States), and a key feedstock in the production of silicones that are widely used as household sealants. In this Account, we show how, in partnership with conventional spectroscopic and reaction testing methods, inelastic neutron scattering (INS) spectroscopy can provide additional insight into the active sites present on the catalyst, as well as the intermediates present on the catalyst surface.&lt;p&gt;&lt;/p&gt; INS spectroscopy is a form of vibrational spectroscopy, where the spectral features are dominated by modes involving hydrogen. Because of this, most materials including alumina are largely transparent to neutrons. Advantageously, in this technique, the entire “mid-infrared”, 0–4000 cm&lt;sup&gt;–1&lt;/sup&gt;, range is accessible; there is no cut-off at 1400 cm&lt;sup&gt;–1&lt;/sup&gt; as in infrared spectroscopy. It is also straightforward to distinguish fundamental modes from overtones and combinations. &lt;p&gt;&lt;/p&gt; A key parameter in the catalyst’s activity is the surface acidity. In infrared spectroscopy of adsorbed pyridine, the shifts in the ring stretching modes are dependent on the strength of the acid site. However, there is a very limited spectral range available. We discuss how we can observe the low energy ring deformation modes of adsorbed pyridine by INS spectroscopy. These modes can undergo shifts that are as large as those seen with infrared inspectroscopy, potentially enabling finer discrimination between acid sites. &lt;p&gt;&lt;/p&gt; Surface hydroxyls play a key role in alumina catalysis, but in infrared spectroscopy, the presence of electrical anharmonicity complicates the interpretation of the O–H stretch region. In addition, the deformations lie below the infrared cut-off. Both of these limitations are irrelevant to INS spectroscopy, and all the modes are readily observable. When we add HCl to the catalyst surface, the acid causes changes in the spectra. We can then deduce both that the surface chlorination leads to enhanced Lewis acidity and that the hydroxyl group must be threefold coordinated. &lt;p&gt;&lt;/p&gt; When we react η-alumina with methanol, the catalyst forms a chemisorbed methoxy species. Infrared spectroscopy clearly shows its presence but also indicates the possible coexistence of a second species. Because of INS spectroscopy’s ability to discriminate between fundamental modes and combinations, we were able to unambiguously show that there is a single intermediate present on the surface of the active catalyst. This work represents a clear example where an understanding of the chemistry at the molecular level can help rationalize improvements in a large scale industrial process with both financial and environmental benefits. &lt;p&gt;&lt;/p&gt