Magnetic Structure and Spin Waves in the Kagom\'{e} Jarosite compound KFe3(SO4)2(OH)6{\bf KFe_3(SO_4)_2(OH)_6}

We present a detailed study of the magnetic structure and spin waves in the Fe jarosite compound ${\rm KFe_3(SO_4)_2(OH)_6}$ for the most general Hamiltonian involving one- and two-spin interactions which are allowed by symmetry. We compare the calculated spin-wave spectrum with the recent neutron scattering data of Matan {\it et al.} for various model Hamiltonians which include, in addition to isotropic Heisenberg exchange interactions between nearest ($J_1$) and next-nearest ($J_2$) neighbors, single ion anisotropy and Dzyaloshinskii-Moriya (DM) interactions. We concluded that DM interactions are the dominant anisotropic interaction, which not only fits all the splittings in the spin-wave spectrum but also reproduces the small canting of the spins out of the Kagom\'e plane. A brief discussion of how representation theory restricts the allowed magnetic structure is also given.Comment: 23 pages, 17 figures, submitted to Phys. Rev. B (March 2006

Formation of pyrene excimers in mesoporous ormosil thin films for visual detection of nitro-explosives

Cataloged from PDF version of article.We report the preparation of mesoporous thin films with bright pyrene excimer emission and their application in visual and rapid detection of nitroaromatic explosive vapors. The fluorescent films were produced by physically encapsulating pyrene molecules in the organically modified silica (ormosil) networks which were prepared via a facile template-free sol-gel method. Formation and stability of pyrene excimer emission were investigated in both porous and nonporous ormosil thin films. Excimer emission was significantly brighter and excimer formation ability was more stable in porous films compared to nonporous films. Rapid and selective quenching was observed in the excimer emission against vapors of nitroaromatic molecules; trinitrotoluene (TNT), dinitrotoluene (DNT), and nitrobenzene (NB). Fluorescence quenching of the films can be easily observed under UV light, enabling the naked-eye detection of nitro-explosives. Furthermore, excimer emission signal can be recovered after quenching and the films can be reused at least five times

Nanoconfinement of pyrene in mesostructured silica nanoparticles for trace detection of TNT in aqueous phase

Cataloged from PDF version of article.This article describes the preparation of pyrene confined mesostructured silica nanoparticles for the trace detection of trinitrotoluene (TNT) in the aqueous phase. Pyrene confined mesostructured silica nanoparticles were prepared using a facile one-pot method where pyrene molecules were first encapsulated in the hydrophobic parts of cetyltrimethylammonium micelles and then silica polymerized around these micelles. The resulting hybrid particles have sizes of around 75 nm with fairly good size distribution. Also, they are highly dispersible and colloidally stable in water. More importantly, they exhibit bright and highly stable pyrene excimer emission. We demonstrated that excimer emission of the particles exhibits a rapid, sensitive and visual quenching response against TNT. The detection limit for TNT was determined to be 12 nM. Furthermore, excimer emission of pyrene shows significantly high selectivity for TNT

Exo-hydrogenated Single Wall Carbon Nanotubes

An extensive first-principles study of fully exo-hydrogenated zigzag (n,0) and armchair (n,n) single wall carbon nanotubes (C$_n$H$_n$), polyhedral molecules including cubane, dodecahedrane, and C$_{60}$H$_{60}$ points to crucial differences in the electronic and atomic structures relevant to hydrogen storage and device applications. C$_n$H$_n$'s are estimated to be stable up to the radius of a (8,8) nanotube, with binding energies proportional to 1/R. Attaching a single hydrogen to any nanotube is always exothermic. Hydrogenation of zigzag nanotubes is found to be more likely than armchair nanotubes with similar radius. Our findings may have important implications for selective functionalization and finding a way of separating similar radius nanotubes from each other.Comment: 5 pages, 4 postscript figures, Revtex file, To be appear in Physical Review

A bibliometric analysis of drought indices, risk, and forecast as components of drought early warning systems

In this study, we apply a bibliometric analysis to characterize publication data on droughts, mainly focusing on drought indices (DIs), drought risk (DR), and drought forecast (DF). Data on publications on these selected topics were obtained through the Scopus database, covering the period from 1963 to June 2021. The DI-related publications, based on meteorological, soil moisture, hydrological, remote sensing, and composite/modeled Dis, accounted for 57%, 8%, 4%, 29%, and 2% of the scientific sources, respectively. DI-related studies showed a notable increase since the 1990s, due perhaps to a higher number of major droughts during the last three decades. It was found that USA and China were the two leading countries in terms of publication count and academic influence on the DI, DR, and DF studies. A network analysis of the country of residence of co-authors on DR and DF research highlighted the top three countries, which were the USA, China, and the United Kingdom. The most productive journal for the DI studies was found to be the International Journal of Climatology, whereas Natural Hazards was identified as the first-ranked journal for the DR and DF studies. In relation to individual researchers, Singh VP from the USA was found to be the most prolific author, having the greatest academic influence on DF study, whereas Zhang Q from China was identified as the most productive author on DR study. This bibliometric analysis reveals that further research is needed on droughts in the areas of risk management, water management, and drought management. This review maps trends of previous research in drought science, covering several important aspects, such as drought indices, geographic regions, authors and their collaboration paths, and sub-topics of interest. This article is expected to serve as an index of the current state of knowledge on drought warning systems and as guidance for future research needs

Pressure-Induced Interlinking of Carbon Nanotubes

We predict new forms of carbon consisting of one and two dimensional networks of interlinked single wall carbon nanotubes, some of which are energetically more stable than van der Waals packing of the nanotubes on a hexagonal lattice. These interlinked nanotubes are further transformed with higher applied external pressures to more dense and complicated stable structures, in which curvature-induced carbon sp$^{3}$ re-hybridizations are formed. We also discuss the energetics of the bond formation between nanotubes and the electronic properties of these predicted novel structures.Comment: 4 pages, 4 postscript figures; To be appear in PR

Meteorological and hydrological drought hazard, frequency and propagation analysis : a case study in southeast Australia

Study region: Southeast Australia.Study focus: We investigated meteorological and hydrological drought characteristics using Standardized Precipitation Index (SPI), Standardized Streamflow Index (SSFI) and Effective Drought Index (EDI). Drought Hazard Index (DHI) was derived based on the probability of drought occurrence and Thiessen polygons using SPI/EDI, whereas Drought Frequency Index (DFI) was derived based on number of drought events, and data length using SPI, EDI, and SSFI. The modified Mann-Kendall test was applied to detect trends in streamflow data and hydrological droughts. Furthermore, correlation between meteorological and hydrological drought indices for different timesteps was assessed through Pearson's and Spearman's rank correlation analysis. Finally, the drought propagation time (DPT) from meteorological to hydrological drought was estimated by 'theory of run.'New hydrological insights for the region: Our major findings include: (i) The spatial coverage of DHI and DFI, based on SPI/EDI, illustrate that mainly south and coastal regions of the study area are the most 'drought-prone' (ii) A considerable proportion of streamflow stations shows a significant trend of decrease in annual streamflow, with the most dominant year of abrupt change is 1996; (iii) Hydrological droughts are increasing in the study area; (iv) Performance of EDI with SSFI is found to be better than SPI at 3-month timestep; and (v) DPT can be found using 'theory of run' however, defined DPT cannot be directly applied to other regions

Influence of local fullerene orientation on the electronic properties of A3C60 compounds

We have investigated sodium containing fullerene superconductors Na2AC60, A = Cs, Rb, and K, by Na-23 nuclear magnetic resonance (NMR) spectroscopy at 7.5 T in the temperature range of 10 to 400 K. Despite the structural differences from the Rb3C60 class of fullerene superconductors, in these compounds the NMR line of the tetrahedrally coordinated alkali nuclei also splits into two lines (T and T') at low temperature. In Na2CsC60 the splitting occurs at 170 K; in the quenched cubic phase of Na2RbC60 and Na2KC60 we observe split lines at 80 K. Detailed investigations of the spectrum, spin-spin and spin-lattice relaxation as well as spin-echo double resonance (SEDOR) in Na2CsC60 we show that these two different tetrahedral sites are mixed on a microscopic scale. The T and T' sites differ in the orientation of first-neighbor C60 molecules. We present evidence that the orientations of neighboring molecules are uncorrelated. Thermally activated molecular reorientations cause an exchange between the T and T' sites and motional narrowing at high temperature. We infer the same activation energy, 3300 K, in the temperature range 125 to 300 K. The spin lattice relaxation rate is the same for T and T' down to 125 K but different below. Both the spin-lattice relaxation rate and Knight shift are strongly temperature dependent in the whole range investigated. We interpret this temperature variation by the effect of phonon excitations involving the rigid librational motion of the C60 molecules. By extending the understanding of the structure and molecular dynamics of C60 superconductors, these results may help in clarifying the effects of the structure on the superconducting properties.Comment: 13 pages, 10 figures, submitted to PR