Vibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium(III) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium(III) ion

Hexakis(dimethyl sulfoxide) scandium(III) iodide, [Sc(OS(CH3)(2))(6)]I-3 contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) Angstrom. EXAFS spectra yield a mean Sc-O bond distance of 2.09(1) Angstrom for solvated scandium(III) ions in dimethyl sulfoxide solution, consistent with six-coordination. Raman and infrared absorption spectra have been recorded, also of the deuterated compound, and analysed by means of normal coordinate methods, together with spectra of dimethyl sulfoxide. The effects on the vibrational spectra of the weak intermolecular C-H...O interactions and of the dipole dipole interactions in liquid dimethyl sulfoxide have been evaluated, in particular for the S O stretching mode. The strong Raman band at 1043.6 cm(-1) and the intense IR absorption at 1062.6 cm(-1) have been assigned as the S-O stretching frequencies of the dominating species in liquid dimethyl sulfoxide, evaluated as centrosymmetric dimers with antiparallel polar S-O groups. The shifts of vibrational frequencies and force constants for coordinated dimethyl sulfoxide ligands in hexasolvated trivalent metal ion complexes are discussed. Hexasolvated scandium( III) ions are found in dimethyl sulfoxide solution and in [Sc(OSMe2)(6)]I-3. The iodide ion dipole attraction shifts the methyl group C H stretching frequency for (S-)C-H...I- more than for the intermolecular (S-)C-H...O interactions in liquid dimethyl sulfoxide

Probing the topological exciton condensate via Coulomb drag

The onset of exciton condensation in a topological insulator thin film was recently predicted. We calculate the critical temperature for this transition, taking into account screening effects. Furthermore, we show that the proximity to this transition can be probed by measuring the Coulomb drag resistivity between the surfaces of the thin film as a function of temperature. This resistivity shows an upturn upon approaching the exciton-condensed state.Comment: 4 pages, 3 figure

Spin transport in a unitary Fermi gas close to the BCS transition

We consider spin transport in a two-component ultracold Fermi gas with attractive interspecies interactions close to the BCS pairing transition. In particular, we consider the spin-transport relaxation rate and the spin-diffusion constant. Upon approaching the transition, the scattering amplitude is enhanced by pairing fluctuations. However, as the system approaches the transition, the spectral weight for excitations close to the Fermi level is decreased by the formation of a pseudogap. To study the consequence of these two competing effects, we determine the spin-transport relaxation rate and the spin-diffusion constant using both a Boltzmann approach and a diagrammatic approach. The former ignores pseudogap physics and finite lifetime effects. In the latter, we incorporate the full pseudogap physics and lifetime effects, but we ignore vertex corrections, so that we effectively calculate single-particle relaxation rates instead of transport relaxation rates. We find that there is qualitative agreement between these two approaches although the results for the transport coefficients differ quantitatively.Comment: 9 pages, 10 figure

Forming short-period Wolf-Rayet X-ray binaries and double black holes through stable mass transfer

We show that black-hole High-Mass X-ray Binaries (HMXBs) with O- or B-type donor stars and relatively short orbital periods, of order one week to several months may survive spiral in, to then form Wolf-Rayet (WR) X-ray binaries with orbital periods of order a day to a few days; while in systems where the compact star is a neutron star, HMXBs with these orbital periods never survive spiral-in. We therefore predict that WR X-ray binaries can only harbor black holes. The reason why black-hole HMXBs with these orbital periods may survive spiral in is: the combination of a radiative envelope of the donor star, and a high mass of the compact star. In this case, when the donor begins to overflow its Roche lobe, the systems are able to spiral in slowly with stable Roche-lobe overflow, as is shown by the system SS433. In this case the transferred mass is ejected from the vicinity of the compact star (so-called "isotropic re-emission" mass loss mode, or "SS433-like mass loss"), leading to gradual spiral-in. If the mass ratio of donor and black hole is $>3.5$, these systems will go into CE evolution and are less likely to survive. If they survive, they produce WR X-ray binaries with orbital periods of a few hours to one day. Several of the well-known WR+O binaries in our Galaxy and the Magellanic Clouds, with orbital periods in the range between a week and several months, are expected to evolve into close WR-Black-Hole binaries,which may later produce close double black holes. The galactic formation rate of double black holes resulting from such systems is still uncertain, as it depends on several poorly known factors in this evolutionary picture. It might possibly be as high as $\sim 10^{-5}$ per year.Comment: MNRAS in pres

Interaction effects on dynamic correlations in non-condensed Bose gases

We consider dynamic, i.e., frequency-dependent, correlations in non-condensed ultracold atomic Bose gases. In particular, we consider the single-particle correlation function and its power spectrum. We compute this power spectrum for a one-component Bose gas, and show how it depends on the interatomic interactions that lead to a finite single-particle relaxation time. As another example, we consider the power spectrum of spin-current fluctuations for a two-component Bose gas and show how it is determined by the spin-transport relaxation time.Comment: 9 pages, 3 figure

Vortex-lattice pinning in two-component Bose-Einstein condensates

We investigate the vortex-lattice structure for single- and two-component Bose-Einstein condensates in the presence of an optical lattice, which acts as a pinning potential for the vortices. The problem is considered in the mean-field quantum-Hall regime, which is reached when the rotation frequency $\Omega$ of the condensate in a radially symmetric trap approaches the (radial) trapping frequency $\omega$ and the interactions between the atoms are weak. We determine the vortex-lattice phase diagram as a function of optical-lattice strength and geometry. In the limit of strong pinning the vortices are always pinned at the maxima of the optical-lattice potential, similar to the slow-rotation case. At intermediate pinning strength, however, due to the competition between interactions and pinning energy, a structure arises for the two-component case where the vortices are pinned on lines of minimal potential