1,858 research outputs found
Vibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium(III) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium(III) ion
Hexakis(dimethyl sulfoxide) scandium(III) iodide, [Sc(OS(CH3)(2))(6)]I-3 contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) Angstrom. EXAFS spectra yield a mean Sc-O bond distance of 2.09(1) Angstrom for solvated scandium(III) ions in dimethyl sulfoxide solution, consistent with six-coordination. Raman and infrared absorption spectra have been recorded, also of the deuterated compound, and analysed by means of normal coordinate methods, together with spectra of dimethyl sulfoxide. The effects on the vibrational spectra of the weak intermolecular C-H...O interactions and of the dipole dipole interactions in liquid dimethyl sulfoxide have been evaluated, in particular for the S O stretching mode. The strong Raman band at 1043.6 cm(-1) and the intense IR absorption at 1062.6 cm(-1) have been assigned as the S-O stretching frequencies of the dominating species in liquid dimethyl sulfoxide, evaluated as centrosymmetric dimers with antiparallel polar S-O groups. The shifts of vibrational frequencies and force constants for coordinated dimethyl sulfoxide ligands in hexasolvated trivalent metal ion complexes are discussed. Hexasolvated scandium( III) ions are found in dimethyl sulfoxide solution and in [Sc(OSMe2)(6)]I-3. The iodide ion dipole attraction shifts the methyl group C H stretching frequency for (S-)C-H...I- more than for the intermolecular (S-)C-H...O interactions in liquid dimethyl sulfoxide
Probing the topological exciton condensate via Coulomb drag
The onset of exciton condensation in a topological insulator thin film was
recently predicted. We calculate the critical temperature for this transition,
taking into account screening effects. Furthermore, we show that the proximity
to this transition can be probed by measuring the Coulomb drag resistivity
between the surfaces of the thin film as a function of temperature. This
resistivity shows an upturn upon approaching the exciton-condensed state.Comment: 4 pages, 3 figure
Spin transport in a unitary Fermi gas close to the BCS transition
We consider spin transport in a two-component ultracold Fermi gas with
attractive interspecies interactions close to the BCS pairing transition. In
particular, we consider the spin-transport relaxation rate and the
spin-diffusion constant. Upon approaching the transition, the scattering
amplitude is enhanced by pairing fluctuations. However, as the system
approaches the transition, the spectral weight for excitations close to the
Fermi level is decreased by the formation of a pseudogap. To study the
consequence of these two competing effects, we determine the spin-transport
relaxation rate and the spin-diffusion constant using both a Boltzmann approach
and a diagrammatic approach. The former ignores pseudogap physics and finite
lifetime effects. In the latter, we incorporate the full pseudogap physics and
lifetime effects, but we ignore vertex corrections, so that we effectively
calculate single-particle relaxation rates instead of transport relaxation
rates. We find that there is qualitative agreement between these two approaches
although the results for the transport coefficients differ quantitatively.Comment: 9 pages, 10 figure
Forming short-period Wolf-Rayet X-ray binaries and double black holes through stable mass transfer
We show that black-hole High-Mass X-ray Binaries (HMXBs) with O- or B-type
donor stars and relatively short orbital periods, of order one week to several
months may survive spiral in, to then form Wolf-Rayet (WR) X-ray binaries with
orbital periods of order a day to a few days; while in systems where the
compact star is a neutron star, HMXBs with these orbital periods never survive
spiral-in. We therefore predict that WR X-ray binaries can only harbor black
holes. The reason why black-hole HMXBs with these orbital periods may survive
spiral in is: the combination of a radiative envelope of the donor star, and a
high mass of the compact star. In this case, when the donor begins to overflow
its Roche lobe, the systems are able to spiral in slowly with stable Roche-lobe
overflow, as is shown by the system SS433. In this case the transferred mass is
ejected from the vicinity of the compact star (so-called "isotropic
re-emission" mass loss mode, or "SS433-like mass loss"), leading to gradual
spiral-in. If the mass ratio of donor and black hole is , these systems
will go into CE evolution and are less likely to survive. If they survive, they
produce WR X-ray binaries with orbital periods of a few hours to one day.
Several of the well-known WR+O binaries in our Galaxy and the Magellanic
Clouds, with orbital periods in the range between a week and several months,
are expected to evolve into close WR-Black-Hole binaries,which may later
produce close double black holes. The galactic formation rate of double black
holes resulting from such systems is still uncertain, as it depends on several
poorly known factors in this evolutionary picture. It might possibly be as high
as per year.Comment: MNRAS in pres
Interaction effects on dynamic correlations in non-condensed Bose gases
We consider dynamic, i.e., frequency-dependent, correlations in non-condensed
ultracold atomic Bose gases. In particular, we consider the single-particle
correlation function and its power spectrum. We compute this power spectrum for
a one-component Bose gas, and show how it depends on the interatomic
interactions that lead to a finite single-particle relaxation time. As another
example, we consider the power spectrum of spin-current fluctuations for a
two-component Bose gas and show how it is determined by the spin-transport
relaxation time.Comment: 9 pages, 3 figure
Vortex-lattice pinning in two-component Bose-Einstein condensates
We investigate the vortex-lattice structure for single- and two-component
Bose-Einstein condensates in the presence of an optical lattice, which acts as
a pinning potential for the vortices. The problem is considered in the
mean-field quantum-Hall regime, which is reached when the rotation frequency
of the condensate in a radially symmetric trap approaches the (radial)
trapping frequency and the interactions between the atoms are weak. We
determine the vortex-lattice phase diagram as a function of optical-lattice
strength and geometry. In the limit of strong pinning the vortices are always
pinned at the maxima of the optical-lattice potential, similar to the
slow-rotation case. At intermediate pinning strength, however, due to the
competition between interactions and pinning energy, a structure arises for the
two-component case where the vortices are pinned on lines of minimal potential
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