Connections of activated hopping processes with the breakdown of the Stokes-Einstein relation and with aspects of dynamical heterogeneities

We develop a new extended version of the mode-coupling theory (MCT) for glass transition, which incorporates activated hopping processes via the dynamical theory originally formulated to describe diffusion-jump processes in crystals. The dynamical-theory approach adapted here to glass-forming liquids treats hopping as arising from vibrational fluctuations in quasi-arrested state where particles are trapped inside their cages, and the hopping rate is formulated in terms of the Debye-Waller factors characterizing the structure of the quasi-arrested state. The resulting expression for the hopping rate takes an activated form, and the barrier height for the hopping is ``self-generated'' in the sense that it is present only in those states where the dynamics exhibits a well defined plateau. It is discussed how such a hopping rate can be incorporated into MCT so that the sharp nonergodic transition predicted by the idealized version of the theory is replaced by a rapid but smooth crossover. We then show that the developed theory accounts for the breakdown of the Stokes-Einstein relation observed in a variety of fragile glass formers. It is also demonstrated that characteristic features of dynamical heterogeneities revealed by recent computer simulations are reproduced by the theory. More specifically, a substantial increase of the non-Gaussian parameter, double-peak structure in the probability distribution of particle displacements, and the presence of a growing dynamic length scale are predicted by the extended MCT developed here, which the idealized version of the theory failed to reproduce. These results of the theory are demonstrated for a model of the Lennard-Jones system, and are compared with related computer-simulation results and experimental data.Comment: 13 pages, 5 figure

Professional boundaries: research report

In 2008 the General Social Care Council (GSCC) published Raising standards: Social work conduct in England 2003-2008. This constituted the GSCC’s first report covering the work undertaken to uphold standards and protect people who use social care services. The GSCC’s analysis revealed that a considerable proportion of conduct cases, some 40%, involved allegations of 'inappropriate relations'. In the light of this finding, and the release by the Council for Healthcare Regulatory Excellence (CHRE) of sexual boundaries guidance for healthcare workers at the beginning of this year (Halter et al, 2009), the GSCC committed itself to exploring the possibility of producing professional boundaries guidance for social workers. To begin this exploration, the GSCC commissioned a study in early 2009.This is the report of that study. There were two main purposes. First, to establish what professional boundaries1 guidance currently exists for social workers, or for sections of the workforce that includes social workers in the United Kingdom, and the content of any such guidance. Secondly, to identify and discuss a number of other examples of professional boundaries guidance to act as points of reference for the GSCC’s project. The aim was to identify and discuss examples relevant to the GSCC’s project

A dynamical and kinematical model of the Galactic stellar halo and possible implications for galaxy formation scenarios

We re-analyse the kinematics of the system of blue horizontal branch field (BHBF) stars in the Galactic halo (in particular the outer halo), fitting the kinematics with the model of radial and tangential velocity dispersions in the halo as a function of galactocentric distance r proposed by Sommer-Larsen, Flynn & Christensen (1994), using a much larger sample (almost 700) of BHBF stars. The basic result is that the character of the stellar halo velocity ellipsoid changes markedly from radial anisotropy at the sun to tangential anisotropy in the outer parts of the Galactic halo (r greater than approx 20 kpc). Specifically, the radial component of the stellar halo's velocity ellipsoid decreases fairly rapidly beyond the solar circle, from approx 140 +/- 10 km/s at the sun, to an asymptotic value of 89 +/- 19 km/s at large r. The rapid decrease in the radial velocity dispersion is matched by an increase in the tangential velocity dispersion, with increasing r. Our results may indicate that the Galaxy formed hierarchically (partly or fully) through merging of smaller subsystems - the 'bottom-up' galaxy formation scenario, which for quite a while has been favoured by most theorists and recently also has been given some observational credibility by HST observations of a potential group of small galaxies, at high redshift, possibly in the process of merging to a larger galaxy (Pascarelle et al 1996).Comment: Latex, 16 pages. 2 postscript figures. Submitted to the Astrophysical Journal. also available at http://astro.utu.fi/~cflynn/outerhalo.htm

Thresholds, switches and hysteresis in hydrology from the pedon to the catchment scale: a non-linear systems theory

International audienceHysteresis is a rate-independent non-linearity that is expressed through thresholds, switches, and branches. Exceedance of a threshold, or the occurrence of a turning point in the input, switches the output onto a particular output branch. Rate-independent branching on a very large set of switches with non-local memory is the central concept in the new definition of hysteresis. Hysteretic loops are a special case. A self-consistent mathematical description of hydrological systems with hysteresis demands a new non-linear systems theory of adequate generality. The goal of this paper is to establish this and to show how this may be done. Two results are presented: a conceptual model for the hysteretic soil-moisture characteristic at the pedon scale and a hysteretic linear reservoir at the catchment scale. Both are based on the Preisach model. A result of particular significance is the demonstration that the independent domain model of the soil moisture characteristic due to Childs, Poulavassilis, Mualem and others, is equivalent to the Preisach hysteresis model of non-linear systems theory, a result reminiscent of the reduction of the theory of the unit hydrograph to linear systems theory in the 1950s. A significant reduction in the number of model parameters is also achieved. The new theory implies a change in modelling paradigm

Second order perturbation theory for spin-orbit resonances

We implement Lie transform perturbation theory to second order for the planar spin-orbit problem. The perturbation parameter is the asphericity of the body, with the orbital eccentricity entering as an additional parameter. We study first and second order resonances for different values of these parameters. For nearly spherical bodies like Mercury and the Moon first order perturbation theory is adequate, whereas for highly aspherical bodies like Hyperion the spin is mostly chaotic and perturbation theory is of limited use. However, in between, we identify a parameter range where second order perturbation theory is useful and where as yet unidentified objects may be in second order resonances.Comment: To appear in A

Movement demands and perceived wellness associated with preseason training camp in NCAA Division I college football players

The aims of this study were to examine the movement demands of preseason practice in National Collegiate Athletic Association Division I college football players using portable global positioning system (GPS) technology and to assess perceived wellness associated with preseason practice to determine whether GPS-derived variables from the preceding day influence perceived wellness the following day. Twenty-nine players were monitored using GPS receivers (Catapult Innovations, Melbourne, Australia) during 20 preseason practices. Individual observations (n = 550) were divided into offensive and defensive position groups. Movement variables including low-, medium-, high-intensity, and sprint distance, player load, and acceleration and deceleration distance were assessed. Perceived wellness ratings (n = 469) were examined using a questionnaire which assessed fatigue, soreness, sleep quality, sleep quantity, stress, and mood. A 1-way analysis of variance for positional movement demands and multilevel regressions for wellness measures were used, followed by post hoc testing to evaluate the relational significance between categorical outcomes of perceived wellness scores and movement variables. Results demonstrated significantly (p ≤ 0.05) greater total, high-intensity, and sprint distance, along with greater acceleration and deceleration distances for the defensive back and wide receiver position groups compared with their respective offensive and defensive counterparts. Significant (p ≤ 0.05) differences in movement variables were demonstrated for individuals who responded more or less favorably on each of the 6 factors of perceived wellness. Data from this study provide novel quantification of the position-specific physical demands and perceived wellness associated with college football preseason practice. Results support the use of position-specific training and individual monitoring of college football players

Impact of Hired Foreign Labor on Milk Production and Herd Size in the United States

Foreign labor has become increasingly important component of U.S. agriculture. Disruption in the supply of agricultural labor has been argued to significantly affect agricultural production. This study analyzes the impacts of foreign labor shortages on the dairy industry using national survey data. The results suggest that a 30 percent hired foreign labor shortage will result in 10.1 billion pound decline in total U.S. milk production. This is equivalent to a loss of 458.9 thousand dairy cows. One of the key implications of this study is the need for immigration or labor policies that help maintain consistent labor availability and stability of the dairy farm workforce.Agricultural and Food Policy, Financial Economics, Productivity Analysis,

Computable knowledge: An imperative for Learning Health Systems

Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/151989/1/lrh210203.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/151989/2/lrh210203_am.pd

A Kuiper Belt Source for Solar Flare Track-Rich Interplanetary Dust Particles

The presence of solar flare particle tracks in mineral grains within interplanetary dust particles (IDPs) has long been accepted as proof of their extraterrestrial origin [e.g. 1]. The 10-20 micrometers diameter IDPs released by dust producing objects in the solar system (mainly comets and asteroids) spiral in towards the Sun under the influence of Poynting-Robertson (PR) drag forces [2] and accumulate solar flare energetic particle tracks during their journey. The number of IDPs with well-constrained track density measurements is small, owing to the difficulty in the measurements and the lack of appropriatelysized crystals in which to image them. In order to use track densities as a chronometer of space exposure, the track production rate must be known. All previous work relied on track production rates determined by chemical etching techniques [e.g. 3], but tracks in IDPs are measured using TEM imaging. Here we report measurements of track densities in IDPs from both the anhydrous and hydrated IDP groups. Using the track production calibration determined from TEM observations of anorthite and olivine in lunar rock 64455 [4] we estimate space exposure times for these IDPs to constrain their parent body sources