Bromide and other ions in the snow, firn air, and atmospheric boundary layer at Summit during GSHOX

Measurements of gas phase soluble bromide in the boundary layer and in firn air, and Br− in aerosol and snow, were made at Summit, Greenland (72.5° N, 38.4° W, 3200 m a.s.l.) as part of a larger investigation into the influence of Br chemistry on HOx cycling. The soluble bromide measurements confirm that photochemical activation of Br− in the snow causes release of active Br to the overlying air despite trace concentrations of Br− in the snow (means 15 and 8 nmol Br− kg−1 of snow in 2007 and 2008, respectively). Mixing ratios of soluble bromide above the snow were also found to be very small (mean \u3c1 ppt both years, with maxima of 3 and 4 ppt in 2007 and 2008, respectively), but these levels clearly oxidize and deposit long-lived gaseous elemental mercury and may perturb HOx partitioning. Concentrations of Br− in surface snow tended to increase/decrease in parallel with the specific activities of the aerosol-associated radionuclides 7Be and 210Pb. Earlier work has shown that ventilation of the boundary layer causes simultaneous increases in 7Be and 210Pb at Summit, suggesting there is a pool of Br in the free troposphere above Summit in summer time. Speciation and the source of this free tropospheric Br− are not well constrained, but we suggest it may be linked to extensive regions of active Br chemistry in the Arctic basin which are known to cause ozone and mercury depletion events shortly after polar sunrise. If this hypothesis is correct, it implies persistence of the free troposphere Br− for several months after peak Br activation in March/April. Alternatively, there may be a ubiquitous pool of Br− in the free troposphere, sustained by currently unknown sources and processes

Nitric oxide and peroxynitrite in health and disease

The discovery that mammalian cells have the ability to synthesize the free radical nitric oxide (NO) has stimulated an extraordinary impetus for scientific research in all the fields of biology and medicine. Since its early description as an endothelial-derived relaxing factor, NO has emerged as a fundamental signaling device regulating virtually every critical cellular function, as well as a potent mediator of cellular damage in a wide range of conditions. Recent evidence indicates that most of the cytotoxicity attributed to NO is rather due to peroxynitrite, produced from the diffusion-controlled reaction between NO and another free radical, the superoxide anion. Peroxynitrite interacts with lipids, DNA, and proteins via direct oxidative reactions or via indirect, radical-mediated mechanisms. These reactions trigger cellular responses ranging from subtle modulations of cell signaling to overwhelming oxidative injury, committing cells to necrosis or apoptosis. In vivo, peroxynitrite generation represents a crucial pathogenic mechanism in conditions such as stroke, myocardial infarction, chronic heart failure, diabetes, circulatory shock, chronic inflammatory diseases, cancer, and neurodegenerative disorders. Hence, novel pharmacological strategies aimed at removing peroxynitrite might represent powerful therapeutic tools in the future. Evidence supporting these novel roles of NO and peroxynitrite is presented in detail in this review

An Empirical Relation Between The Large-Scale Magnetic Field And The Dynamical Mass In Galaxies

The origin and evolution of cosmic magnetic fields as well as the influence of the magnetic fields on the evolution of galaxies are unknown. Though not without challenges, the dynamo theory can explain the large-scale coherent magnetic fields which govern galaxies, but observational evidence for the theory is so far very scarce. Putting together the available data of non-interacting, non-cluster galaxies with known large-scale magnetic fields, we find a tight correlation between the integrated polarized flux density, S(PI), and the rotation speed, v(rot), of galaxies. This leads to an almost linear correlation between the large-scale magnetic field B and v(rot), assuming that the number of cosmic ray electrons is proportional to the star formation rate, and a super-linear correlation assuming equipartition between magnetic fields and cosmic rays. This correlation cannot be attributed to an active linear alpha-Omega dynamo, as no correlation holds with global shear or angular speed. It indicates instead a coupling between the large-scale magnetic field and the dynamical mass of the galaxies, B ~ M^(0.25-0.4). Hence, faster rotating and/or more massive galaxies have stronger large-scale magnetic fields. The observed B-v(rot) correlation shows that the anisotropic turbulent magnetic field dominates B in fast rotating galaxies as the turbulent magnetic field, coupled with gas, is enhanced and ordered due to the strong gas compression and/or local shear in these systems. This study supports an stationary condition for the large-scale magnetic field as long as the dynamical mass of galaxies is constant.Comment: 23 pages, 4 figures, accepted for publication in the Astrophysical Journal Letter

Inequalities that test locality in quantum mechanics

Quantum theory violates Bell's inequality, but not to the maximum extent that is logically possible. We derive inequalities (generalizations of Cirel'son's inequality) that quantify the upper bound of the violation, both for the standard formalism and the formalism of generalized observables (POVMs). These inequalities are quantum analogues of Bell inequalities, and they can be used to test the quantum version of locality. We discuss the nature of this kind of locality. We also go into the relation of our results to an argument by Popescu and Rohrlich (Found. Phys. 24, 379 (1994)) that there is no general connection between the existence of Cirel'son's bound and locality.Comment: 5 pages, 1 figure; the argument has been made clearer in the revised version; 1 reference adde

Mixed Early and Late-Type Properties in the Bar of NGC 6221: Evidence for Evolution along the Hubble Sequence?

Rotation curves and velocity dispersion profiles are presented for both the stellar and gaseous components along five different position angles (P.A.=5, 50, 95, 125 and 155 degrees) of the nearby barred spiral NGC 6221. The observed kinematics extends out to about 80" from the nucleus. Narrow and broad-band imaging is also presented. The radial profiles of the fluxes ratio [NII]/Halpha reveal the presence of a ring-like structure of ionized gas, with a radius of about 9" and a deprojected circular velocity of about 280 km/s. The analysis of the dynamics of the bar indicates this ring is related to the presence of an inner Lindblad resonance (ILR) at 1.3 kpc. NGC6221 is found to exhibit intermediate properties between those of the early-type barred galaxies: the presence of a gaseous ring at an ILR, the bar edge located between the ILR's and the corotation radius beyond the steep rising portion of the rotation curve, the dust-lane pattern, and those of the late-type galaxies: an almost exponential surface brightness profile, the presence of Halpha regions along all the bar, the spiral-arm pattern. It is consistent with scenarios of bar-induced evolution from later to earlier-type galaxies.Comment: 1 File ds7406.tar.gz which contains: one latex file (ds7406.tex), and 10 encsulated postscript figures (ds7406f**.eps). To be compiled with aa-l latex2e macro style. To be published in A&A Sup. Serie

On the Environmental Dependence of Cluster Galaxy Assembly Timescale

We present estimates of CN and Mg overabundances with respect to Fe for early-type galaxies in 8 clusters over a range of richness and morphology. Spectra were taken from the Sloan Digital Sky Survey (SDSS) DR1, and from WHT and CAHA observations. Abundances were derived from absorption lines and single burst population models, by comparing galaxy spectra with appropriately broadened synthetic model spectra. We detect correlations between [Mg/CN] and [CN/Fe] and cluster X-ray luminosity. No correlation is observed for [Mg/Fe]. We also see a clear trend with the richness and morphology of the clusters. This is interpreted given varying formation timescales for CN, Mg and Fe, and a varying star formation history in early-type galaxies as a function of their environment: intermediate-mass early-type galaxies in more massive clusters are assembled on shorter timescales than in less massive clusters, with an upper limit of ~1 Gyr.Comment: Accepted for publication in ApJ Letter

Stability of undissociated screw dislocations in zinc-blende covalent materials from first principle simulations

The properties of perfect screw dislocations have been investigated for several zinc-blende materials such as diamond, Si, $\beta$-SiC, Ge and GaAs, by performing first principles calculations. For almost all elements, a core configuration belonging to shuffle set planes is favored, in agreement with low temperature experiments. Only for diamond, a glide configuration has the lowest defect energy, thanks to an sp$^2$ hybridization in the core