Sustainable CO2 adsorbents prepared by coating chitosan onto mesoporous silicas for large-scale carbon capture technology

In this article, we report a new sustainable synthesis procedure for manufacturing chitosan/silica CO2 adsorbents. Chitosan is a naturally abundant material and contains amine functionality, which is essential for selective CO2 adsorptions. It is, therefore, ideally suited for manufacturing CO2 adsorbents on a large scale. By coating chitosan onto high-surface-area mesoporous silica supports, including commercial fumed silica (an economical and accessible reagent) and synthetic SBA-15 and MCF silicas, we have prepared a new family of CO2 adsorbents, which have been fully characterised with nitrogen adsorption isotherms, thermogravimetric analysis/differential scanning calorimetry, TEM, FTIR spectroscopy and Raman spectroscopy. These adsorbents have achieved a significant CO2 adsorption capacity of up to 0.98 mmol g−1 at ambient conditions (P=1 atm and T=25 °C). The materials can also be fully regenerated/recycled on demand at temperatures as low as 75 °C with a >85 % retention of the adsorption capacity after 4 cycles, which makes them promising candidates for advanced CO2 capture, storage and utilisation technology

Maslov index, Lagrangians, Mapping Class Groups and TQFT

Given a mapping class f of an oriented surface Sigma and a lagrangian lambda in the first homology of Sigma, we define an integer n_{lambda}(f). We use n_{lambda}(f) (mod 4) to describe a universal central extension of the mapping class group of Sigma as an index-four subgroup of the extension constructed from the Maslov index of triples of lagrangian subspaces in the homology of the surface. We give two descriptions of this subgroup. One is topological using surgery, the other is homological and builds on work of Turaev and work of Walker. Some applications to TQFT are discussed. They are based on the fact that our construction allows one to precisely describe how the phase factors that arise in the skein theory approach to TQFT-representations of the mapping class group depend on the choice of a lagrangian on the surface.Comment: 31 pages, 11 Figures. to appear in Forum Mathematicu

Resonance Searches with an Updated Top Tagger

The performance of top taggers, for example in resonance searches, can be significantly enhanced through an increased set of variables, with a special focus on final-state radiation. We study the production and the decay of a heavy gauge boson in the upcoming LHC run. For constant signal efficiency, the multivariate analysis achieves an increased background rejection by up to a factor 30 compared to our previous tagger. Based on this study and the documentation in the Appendix we release a new HEPTopTagger2 for the upcoming LHC run. It now includes an optimal choice of the size of the fat jet, N-subjettiness, and different modes of Qjets.Comment: 26 page

Stringency and Distribution in the EU Emissions Trading Scheme –The 2005 Evidence

With the release of the verified emissions for installations covered by the EU Emissions Trading Scheme for the first trading year 2005 we are able to compare actual emissions and allowances for each installation. Based on data available for 24 Member States as of January 2007, this paper uses a thorough data analysis for about 9,900 installations to investigate evidence on three issues: first, the stringency of the total allocation cap and allocation differences both among the Member States and a selection of emission intensive sectors; second, the distribution of the size of installations; and third, the spread of allocation discrepancies and possible allocation biases regarding the size of installations.Emission Trading, EU Emissions Trading Scheme, Climate Policy

What do molecular biologists mean when they say 'structure determines function'?

'Structure' and 'function' are both ambiguous terms. Discriminating different meanings of these terms sheds light on research and explanatory practice in molecular biology, as well as clarifying central theoretical concepts in the life sciences like the sequence-structure-function relationship and its corresponding scientific "dogmas". The overall project is to answer three questions, primarily with respect to proteins: (1) What is structure? (2) What is function? (3) What is the relation between structure and function? The results of addressing these questions lead to an answer to the title question, what the statement 'structure determines function' means

Thermally regenerable carbon dioxide absorbent system Final report, 1 May 1964 - 31 Jan. 1966

Carbon dioxide absorption by solid state ion exchange resin

Structural and Functional Analysis of BipA, a Regulator of Virulence in Enteropathogenic Escherichia coli.

The translational GTPase BipA regulates the expression of virulence and pathogenicity factors in several eubacteria. BipA-dependent expression of virulence factors occurs under starvation conditions, such as encountered during infection of a host. Under these conditions, BipA associates with the small ribosomal subunit. BipA also has a second function to promote the efficiency of late steps in biogenesis of large ribosomal subunits at low temperatures, presumably while bound to the ribosome. During starvation, the cellular concentration of stress alarmone guanosine-3', 5'-bis pyrophosphate (ppGpp) is increased. This increase allows ppGpp to bind to BipA and switch its binding specificity from ribosomes to small ribosomal subunits. A conformational change of BipA upon ppGpp binding could explain the ppGpp regulation of the binding specificity of BipA. Here, we present the structures of the full-length BipA from Escherichia coli in apo, GDP-, and ppGpp-bound forms. The crystal structure and small-angle x-ray scattering data of the protein with bound nucleotides, together with a thermodynamic analysis of the binding of GDP and of ppGpp to BipA, indicate that the ppGpp-bound form of BipA adopts the structure of the GDP form. This suggests furthermore, that the switch in binding preference only occurs when both ppGpp and the small ribosomal subunit are present. This molecular mechanism would allow BipA to interact with both the ribosome and the small ribosomal subunit during stress response

Spin-nematic order in the frustrated pyrochlore-lattice quantum rotor model

As an example of ordering due to quantum fluctuations, we examine the nearest-neighbor antiferromagnetic quantum O(n) rotor model on the pyrochlore lattice. Classically, this system remains disordered even at zero temperature; we find that adding quantum fluctuations induces an ordered phase that survives to positive temperature, and we determine how its phase diagram scales with the coupling constant and the number of spin components. We demonstrate, using quantum Monte Carlo simulations, that this phase has long-range spin-nematic order, and that the phase transition into it appears to be first order.Comment: 10 pages, 8 figure