Kinetic Regimes and Cross-Over Times in Many-Particle Reacting Systems

We study kinetics of single species reactions ("A+A -> 0") for general local reactivity Q and dynamical exponent z (rms displacement x_t ~ t^{1/z}.) For small molecules z=2, whilst z=4,8 for certain polymer systems. For dimensions d above the critical value d_c=z, kinetics are always mean field (MF). Below d_c, the density n_t initially follows MF decay, n_0 - n_t ~ n_0^2 Q t. A 2-body diffusion-controlled regime follows for strongly reactive systems (Q>Qstar ~ n_0^{(z-d)/d}) with n_0 - n_t ~ n_0^2 x_t^d. For Q<Qstar, MF kinetics persist, with n_t ~ 1/Qt. In all cases n_t ~ 1/x_t^d at the longest times. Our analysis avoids decoupling approximations by instead postulating weak physically motivated bounds on correlation functions.Comment: 10 pages, 1 figure, uses bulk2.sty, minor changes, submitted to Europhysics Letter

Proportion of Unaffected Sites in a Reaction-Diffusion Process

We consider the probability $P(t)$ that a given site remains unvisited by any of a set of random walkers in $d$ dimensions undergoing the reaction $A+A\to0$ when they meet. We find that asymptotically $P(t)\sim t^{-\theta}$ with a universal exponent \theta=\ffrac12-O(\epsilon) for $d=2-\epsilon$, while, for $d>2$, $\theta$ is non-universal and depends on the reaction rate. The analysis, which uses field-theoretic renormalisation group methods, is also applied to the reaction $kA\to0$ with $k>2$. In this case, a stretched exponential behaviour is found for all $d\geq1$, except in the case $k=3$, $d=1$, where P(t)\sim {\rm e}^{-\const (\ln t)^{3/2}}.Comment: 10 pages, (revised version with abstract included) OUTP-94-35

A non-monotonic constitutive model is not necessary to obtain shear banding phenomena in entangled polymer solutions

In 1975 Doi and Edwards predicted that entangled polymer melts and solutions can have a constitutive instability, signified by a decreasing stress for shear rates greater than the inverse of the reptation time. Experiments did not support this, and more sophisticated theories incorporated Marrucci's idea (1996) of removing constraints by advection; this produced a monotonically increasing stress and thus stable constitutive behavior. Recent experiments have suggested that entangled polymer solutions may possess a constitutive instability after all, and have led some workers to question the validity of existing constitutive models. In this Letter we use a simple modern constitutive model for entangled polymers, the non-stretching Rolie-Poly model with an added solvent viscosity, and show that (1) instability and shear banding is captured within this simple class of models; (2) shear banding phenomena is observable for weakly stable fluids in flow geometries that impose a sufficiently inhomogeneous total shear stress; (3) transient phenomena can possess inhomogeneities that resemble shear banding, even for weakly stable fluids. Many of these results are model-independent.Comment: 5 figure

Cluster mean-field approximations with the coherent-anomaly-method analysis for the driven pair contact process with diffusion

The cluster mean-field approximations are performed, up to 13 cluster sizes, to study the critical behavior of the driven pair contact process with diffusion (DPCPD) and its precedent, the PCPD in one dimension. Critical points are estimated by extrapolating our data to the infinite cluster size limit, which are in good accordance with recent simulation results. Within the cluster mean-field approximation scheme, the PCPD and the DPCPD share the same mean-field critical behavior. The application of the coherent anomaly method, however, shows that the two models develop different coherent anomalies, which lead to different true critical scaling. The values of the critical exponents for the particle density, the pair density, the correlation length, and the relaxation time are fairly well estimated for the DPCPD. These results support and complement our recent simulation results for the DPCPD

The A+B -> 0 annihilation reaction in a quenched random velocity field

Using field-theoretic renormalization group methods the long-time behaviour of the A+B -> 0 annihilation reaction with equal initial densities n_A(0) = n_B(0) = n_0 in a quenched random velocity field is studied. At every point (x, y) of a d-dimensional system the velocity v is parallel or antiparallel to the x-axis and depends on the coordinates perpendicular to the flow. Assuming that v(y) have zero mean and short-range correlations in the y-direction we show that the densities decay asymptotically as n(t) ~ A n_0^(1/2) t^(-(d+3)/8) for d<3. The universal amplitude A is calculated at first order in \epsilon = 3-d.Comment: 19 pages, LaTeX using IOP-macros, 5 eps-figures. It is shown that the amplitude of the density is universal, i.e. independent of the reaction rat

Effective Edwards-Wilkinson equation for single-file diffusion

In this work, we present an effective discrete Edwards-Wilkinson equation aimed to describe the single-file diffusion process. The key physical properties of the system are captured defining an effective elasticity, which is proportional to the single particle diffusion coefficient and to the inverse squared mean separation between particles. The effective equation gives a description of single-file diffusion using the global roughness of the system of particles, which presents three characteristic regimes, namely normal diffusion, subdiffusion and saturation, separated by two crossover times. We show how these regimes scale with the parameters of the original system. Additional repulsive interaction terms are also considered and we analyze how the crossover times depend on the intensity of the additional terms. Finally, we show that the roughness distribution can be well characterized by the Edwards-Wilkinson universal form for the different single-file diffusion processes studied here.Comment: 9 pages, 9 figure

CP Violations in Lepton Number Violation Processes and Neutrino Oscillations

We examine the constraints on the MNS lepton mixing matrix from the present and future experimental data of the neutrino oscillation and lepton number violation processes. We introduce a graphical representation of the CP violation phases which appear in the lepton number violation processes such as neutrinoless double beta decay, the $\mu^--e^+$ conversion, and the K decay, $K^-\to\pi^+\mu^-\mu^-.$ Using this graphical representation, we derive the constraints on the CP violation phases in the lepton sector.Comment: 21pp, REVTeX, 9 Figure

Does changing the pulling direction give better insight into biomolecules?

Single molecule manipulation techniques reveal that the mechanical resistance of a protein depends on the direction of the applied force. Using a lattice model of polymers, we show that changing the pulling direction leads to different phase diagrams. The simple model proposed here indicates that in one case the system undergoes a transition akin to the unzipping of a $\beta$ sheet, while in the other case the transition is of a shearing (slippage) nature. Our results are qualitatively similar to experimental results. This demonstrates the importance of varying the pulling direction since this may yield enhanced insights into the molecular interactions responsible for the stability of biomolecules.Comment: RevTeX v4, 10 pages with 6 eps figure