Pressure induced magnetic phase separation in La0.75_{0.75}Ca0.25_{0.25}MnO3_{3} manganite

The pressure dependence of the Curie temperature T$_{C}(P)$ in La$_{0.75}$Ca$_{0.25}$MnO$_{3}$ was determined by neutron diffraction up to 8 GPa, and compared with the metallization temperature T$_{IM}(P)$ \cite{irprl}. The behavior of the two temperatures appears similar over the whole pressure range suggesting a key role of magnetic double exchange also in the pressure regime where the superexchange interaction is dominant. Coexistence of antiferromagnetic and ferromagnetic peaks at high pressure and low temperature indicates a phase separated regime which is well reproduced with a dynamical mean-field calculation for a simplified model. A new P-T phase diagram has been proposed on the basis of the whole set of experimental data.Comment: 5 pages, 4 figure

Uncovering nitrogen accumulation in a large mixed land-use catchment: Implications for national-scale budget studies and environmental management

Accurately quantifying the location and extent of nitrogen accumulation is crucial for mitigating its severe impacts on climate and the environment. Here we estimated a spatial total N budget and its input/output fluxes from different land uses on a 1 km2 grid scale across the whole of a large, mixed land use catchment (Trent, UK). With a long history of water quality monitoring, the Trent catchment provides a unique and ideal test bed for developing a detailed nitrogen budget and determining where N accumulation occurs. In 2015, a significant 35 (±5) ktonnes N accumulation was found, with 31 % of the area acting as a net source and 69 % as a net sink. The spatial budget ranged from −16 (±5) to 45 (±7) tonnes N/km2/year. Using this budget, we identified N accumulation and loss areas under diverse land uses and conducted strategic soil sampling and C/N analysis. Notably, grassland subsoil exhibited nitrogen buildup compared to arable land, spotlighting intricate land use, nitrogen, and soil dynamics. The study emphasizes the need for targeted nutrient management to prevent potential environmental repercussions linked to subsoil nitrogen accumulation, especially in grassland contexts

Half-Seed Analysis for Comparing Linolenic Acid Synthesis Between High and Low Oleic Acid Sunflower Inbred Lines

The modification of fatty acid composition of two sunflowers inbred lines, HA89 and R978, low oleic acid (normal) and high oleic acid (mutant) respectively, in seeds and during the first stages of growth (A1-B2) was studied under controlled conditions. Enzymatic mechanisms have great effect on the catabolism of seed stored lipids. Temperature and oxygen regulation influence developing sunflower seeds. For simultaneous study of seed and developing seed, half-seed analysis technique was used. The behavior of the fatty acids during the germination in cotyledon of seed showed the increase of linolenic acid in both lines, demonstrating the activity of linoleic acid desaturase (\uc46-desaturase). But linoleic acid as a substrate for linoleate desaturase increased during all stages of developing only in mutant line that revealed higher activity of oleic acid desaturase (\uc412-desaturase) in transforming oleic acid to linoleic acid in this line, and lower activity of this enzyme in low oleic acid line, the reasons probably being the low availability of substrate of this enzyme in low oleic acid line and the complexity of enzymatic mechanisms. The modification of fatty acids in developing sunflower, depends not only on ambient conditions such as temperature and oxygen regulation as described by many authors, but also on the genotype. \ua9 2004, by Walter de Gruyter Berlin/Boston. All rights reserved