434 research outputs found
Evaluation of a Liquid Amine System for Spacecraft Carbon Dioxide Control
The analytical and experimental studies are described which were directed toward the acquisition of basic information on utilizing a liquid amine sorbent for in use in a CO2 removal system for manned spacecraft. Liquid amine systems are successfully used on submarines for control of CO2 generated by the crew, but liquid amines were not previously considered for spacecraft applications due to lack of development of satisfactory rotary phase separators. Developments in this area now make consideration of liquid amines practical for spacecraft system CO2 removal. The following major tasks were performed to evaluate liquid amine systems for spacecraft: (1) characterization, through testing, of the basic physical and thermodynamic properties of the amine solution; (2) determination of the dynamic characteristics of a cocurrent flow absorber; and (3) evaluation, synthesis, and selection of a liquid amine system concept oriented toward low power requirements. A low weight, low power system concept was developed. Numerical and graphical data are accompanied by pertinent observations
Celebrating Economies of Change: Brave Visions for Inclusive Futures
This issue has been inspired by a path-breaking conference held by the Canadian Society for Ecologi-cal Economics (CANSEE), which took place this past May 2019 in Waterloo, Ontario. Entitled Engaging Economies of Change, the conference aimed to ex-pand existing research networks in the economy-environment nexus by building connections beyond the academy in order to meaningfully engage with the practicalities of building and implementing change. This issue captures the rich content shared during the event, as well as descriptions of the pro-cesses and efforts made to create a welcoming and respectful space where academics and community activists could build alliances and discuss common challenges. The conference organizers â all graduate students and activists themselves -- called this âbuilding a brave spaceâ.This research was supported by the Social Sciences and Humanities Research Council of Canad
The helium atom in a strong magnetic field
We investigate the electronic structure of the helium atom in a magnetic
field b etween B=0 and B=100a.u. The atom is treated as a nonrelativistic
system with two interactin g electrons and a fixed nucleus. Scaling laws are
provided connecting the fixed-nucleus Hamiltonia n to the one for the case of
finite nuclear mass. Respecting the symmetries of the electronic Ham iltonian
in the presence of a magnetic field, we represent this Hamiltonian as a matrix
with res pect to a two-particle basis composed of one-particle states of a
Gaussian basis set. The corresponding generalized eigenvalue problem is solved
numerically, providing in the present paper results for vanish ing magnetic
quantum number M=0 and even or odd z-parity, each for both singlet and triplet
spin symmetry. Total electronic energies of the ground state and the first few
excitations in each su bspace as well as their one-electron ionization energies
are presented as a function of the magnetic fie ld, and their behaviour is
discussed. Energy values for electromagnetic transitions within the M=0 sub
space are shown, and a complete table of wavelengths at all the detected
stationary points with respect to their field dependence is given, thereby
providing a basis for a comparison with observed ab sorption spectra of
magnetic white dwarfs.Comment: 21 pages, 4 Figures, acc.f.publ.in J.Phys.
Electronic Structure of Atoms in Magnetic Quadrupole Traps
We investigate the electronic structure and properties of atoms exposed to a
magnetic quadrupole field. The spin-spatial as well as generalized time
reversal symmetries are established and shown to lead to a two-fold degeneracy
of the electronic states in the presence of the field. Low-lying as well as
highly excited Rydberg states are computed and analyzed for a broad regime of
field gradients. The delicate interplay between the Coulomb and various
magnetic interactions leads to complex patterns of the spatial spin
polarization of individual excited states. Electromagnetic transitions in the
quadrupole field are studied in detail thereby providing the selection rules
and in particular the transition wavelengths and corresponding dipole
strengths. The peculiar property that the quadrupole magnetic field induces
permanent electric dipole moments of the atoms is derived and discussed.Comment: 17 pages, 13 figures, accepted for publication in PR
H^+_2$ in a strong magnetic field described via a solvable model
We consider the hydrogen molecular ion in the presence of a strong
homogeneous magnetic field. In this regime, the effective Hamiltonian is almost
one dimensional with a potential energy which looks like a sum of two Dirac
delta functions. This model is solvable, but not close enough to our exact
Hamiltonian for relevant strenght of the magnnetic field. However we show that
the correct values of the equilibrium distance as well as the binding energy of
the ground state of the ion, can be obtained when incorporating perturbative
corrections up to second order. Finally, we show that exists for
sufficiently large magnetic fields
Hydrogen atom moving across a strong magnetic field: analytical approximations
Analytical approximations are constructed for binding energies,
quantum-mechanical sizes and oscillator strengths of main radiative transitions
of hydrogen atoms arbitrarily moving in magnetic fields 10^{12}-10^{13} G.
Examples of using the obtained approximations for determination of maximum
transverse velocity of an atom and for evaluation of absorption spectra in
magnetic neutron star atmospheres are presented.Comment: 17 pages, 3 figures, 5 tables, LaTeX with IOP style files (included).
In v.2, Fig.1 and Table 5 have been corrected. In v.3, a misprint in the fit
for oscillator strengths, Eq.(21), has been correcte
Hydrogen and Helium atoms in strong magnetic fields
The energy levels of hydrogen and helium atoms in strong magnetic fields are
calculated in this study. The current work contains estimates of the binding
energies of the first few low-lying states of these systems that are
improvements upon previous estimates. The methodology involves computing the
eigenvalues and eigenvectors of the generalized two-dimensional Hartree-Fock
partial differential equations for these one- and two-electron systems in a
self-consistent manner. The method described herein is applicable to
calculations of atomic structure in magnetic fields of arbitrary strength as it
exploits the natural symmetries of the problem without assumptions of any basis
functions for expressing the wave functions of the electrons or the commonly
employed adiabatic approximation. The method is found to be readily extendable
to systems with more than two electrons.Comment: 15 pages, 6 figure
Exchange and correlation energies of ground states of atoms and molecules in strong magnetic fields
Using a Hartree-Fock mesh method and a configuration interaction approach
based on a generalized Gaussian basis set we investigate the behaviour of the
exchange and correlation energies of small atoms and molecules, namely th e
helium and lithium atom as well as the hydrogen molecule, in the presence of a
magnetic field covering the regime B=0-100a.u. In general the importance of the
exchange energy to the binding properties of at oms or molecules increases
strongly with increasing field strength. This is due to the spin-flip
transitions and in particular due to the contributions of the tightly bound
hydrogenic state s which are involved in the corresponding ground states of
different symmetries. In contrast to the exchange energy the correlation energy
becomes less relevant with increasing field strength. This holds for the
individual configurations constituting the ground state and for the crossovers
of the global ground state.Comment: 4 Figures acc.f.publ.in Phys.Rev.
The ground state of the carbon atom in strong magnetic fields
The ground and a few excited states of the carbon atom in external uniform
magnetic fields are calculated by means of our 2D mesh Hartree-Fock method for
field strengths ranging from zero up to 2.35 10^9 T. With increasing field
strength the ground state undergoes six transitions involving seven different
electronic configurations which belong to three groups with different spin
projections S_z=-1,-2,-3. For weak fields the ground state configuration arises
from the field-free 1s^2 2s^2 2p_0 2p_{-1}, S_z=-1 configuration. With
increasing field strength the ground state involves the four S_z=-2
configurations 1s^22s2p_0 2p_{-1}2p_{+1}, 1s^22s2p_0 2p_{-1}3d_{-2}, 1s^22p_0
2p_{-1}3d_{-2}4f_{-3} and 1s^22p_{-1}3d_{-2}4f_{-3}5g_{-4}, followed by the two
fully spin polarized S_z=-3 configurations 1s2p_02p_{-1}3d_{-2}4f_{-3}5g_{-4}
and 1s2p_{-1}3d_{-2}4f_{-3}5g_{-4}6h_{-5}. The last configuration forms the
ground state of the carbon atom in the high field regime \gamma>18.664. The
above series of ground state configurations is extracted from the results of
numerical calculations for more than twenty electronic configurations selected
due to some general energetical arguments.Comment: 6 figures,acc. Phys.Rev.
Ion Collisions in Very Strong Electric Fields
A Classical Trajectory Monte Carlo (CTMC) simulation has been made of
processes of charge exchange and ionization between an hydrogen atom and fully
stripped ions embedded in very strong static electric fields (
V/m), which are thought to exist in cosmic and laser--produced plasmas.
Calculations show that the presence of the field affects absolute values of the
cross sections, enhancing ionization and reducing charge exchange. Moreover,
the overall effect depends upon the relative orientation between the field and
the nuclear motion. Other features of a null-field situation, such as scaling
laws, are revisited.Comment: Latex, 13 pages, 11 figures (available upon request), to be published
in Journal of Physics
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