3,154 research outputs found
Antifouling bastadin congeners target blue mussel phenoloxidase and complex copper(II) ions
Synthetically prepared congeners of spongederived bastadin derivatives such as 5,5'-dibromohemibastadin- 1 (DBHB) that suppress the settling of barnacle larvae were identified in this study as strong inhibitors of blue mussel phenoloxidase that is involved in the firm attachment of mussels to a given substrate. The IC50 value of DBHB as the most active enzyme inhibitor encountered in this study amounts to 0.84 mu M. Inhibition of phenoloxidase by DBHB is likely due to complexation of copper(II) ions from the catalytic centre of the enzyme by the a-oxo-oxime moiety of the compound as shown here for the first time by structure activity studies and by X-ray structure determination of a copper(II) complex of DBHB.Biotechnology & Applied MicrobiologyMarine & Freshwater BiologySCI(E)EI0ARTICLE61148-11581
Nanoscale Weibull Statistics
In this paper a modification of the classical Weibull Statistics is developed
for nanoscale applications. It is called Nanoscale Weibull Statistics. A
comparison between Nanoscale and classical Weibull Statistics applied to
experimental results on fracture strength of carbon nanotubes clearly shows the
effectiveness of the proposed modification. A Weibull's modulus around 3 is,
for the first time, deduced for nanotubes. The approach can treat (also) a
small number of structural defects, as required for nearly defect free
structures (e.g., nanotubes) as well as a quantized crack propagation (e.g., as
a consequence of the discrete nature of matter), allowing to remove the
paradoxes caused by the presence of stress-intensifications
Electromagnetic showers in a strong magnetic field
We present the results concerning the main shower characteristics in a strong
magnetic field obtained through shower simulation. The processes of magnetic
bremsstrahlung and pair production were taken into account for values of the
parameter . We compare our simulation results with a recently
developed cascade theory in a strong magnetic field.Comment: 11 pages, 9 eps figures, LaTex2e, Iopart.cls, Iopart12.clo,
Iopams.st
Plantas de cobertura e adubação verde para citros.
bitstream/item/135173/1/Documento-383-Com-capa.pd
Charge Order Driven spin-Peierls Transition in NaV2O5
We conclude from 23Na and 51V NMR measurements in NaxV2O5(x=0.996) a charge
ordering transition starting at T=37 K and preceding the lattice distortion and
the formation of a spin gap Delta=106 K at Tc=34.7 K. Above Tc, only a single
Na site is observed in agreement with the Pmmn space group of this first
1/4-filled ladder system. Below Tc=34.7 K, this line evolves into eight
distinct 23Na quadrupolar split lines, which evidences a lattice distortion
with, at least, a doubling of the unit cell in the (a,b) plane. A model for
this unique transition implying both charge density wave and spin-Peierls order
is discussed.Comment: 4 pages, 3 figures, submitted to Phys. Rev. Let
Coherent strong-field control of multiple states by a single chirped femtosecond laser pulse
We present a joint experimental and theoretical study on strong-field
photo-ionization of sodium atoms using chirped femtosecond laser pulses. By
tuning the chirp parameter, selectivity among the population in the highly
excited states 5p, 6p, 7p and 5f, 6f is achieved. Different excitation pathways
enabling control are identified by simultaneous ionization and measurement of
photoelectron angular distributions employing the velocity map imaging
technique. Free electron wave packets at an energy of around 1 eV are observed.
These photoelectrons originate from two channels. The predominant 2+1+1
Resonance Enhanced Multi-Photon Ionization (REMPI) proceeds via the strongly
driven two-photon transition , and subsequent
ionization from the states 5p, 6p and 7p whereas the second pathway involves
3+1 REMPI via the states 5f and 6f. In addition, electron wave packets from
two-photon ionization of the non-resonant transiently populated state 3p are
observed close to the ionization threshold. A mainly qualitative five-state
model for the predominant excitation channel is studied theoretically to
provide insights into the physical mechanisms at play. Our analysis shows that
by tuning the chirp parameter the dynamics is effectively controlled by dynamic
Stark-shifts and level crossings. In particular, we show that under the
experimental conditions the passage through an uncommon three-state "bow-tie"
level crossing allows the preparation of coherent superposition states
Bayes-optimal inverse halftoning and statistical mechanics of the Q-Ising model
On the basis of statistical mechanics of the Q-Ising model, we formulate the
Bayesian inference to the problem of inverse halftoning, which is the inverse
process of representing gray-scales in images by means of black and white dots.
Using Monte Carlo simulations, we investigate statistical properties of the
inverse process, especially, we reveal the condition of the Bayes-optimal
solution for which the mean-square error takes its minimum. The numerical
result is qualitatively confirmed by analysis of the infinite-range model. As
demonstrations of our approach, we apply the method to retrieve a grayscale
image, such as standard image `Lenna', from the halftoned version. We find that
the Bayes-optimal solution gives a fine restored grayscale image which is very
close to the original.Comment: 13pages, 12figures, using elsart.cl
Excitonic photoluminescence in symmetric coupled double quantum wells subject to an external electric field
The effect of an external electric field F on the excitonic photoluminescence
(PL) spectra of a symmetric coupled double quantum well (DQW) is investigated
both theoretically and experimentally. We show that the variational method in a
two-particle electron-hole wave function approximation gives a good agreement
with measurements of PL on a narrow DQW in a wide interval of F including
flat-band regime. The experimental data are presented for an MBE-grown DQW
consisting of two 5 nm wide GaAs wells, separated by a 4 monolayers (MLs) wide
pure AlAs central barrier, and sandwiched between Ga_{0.7}Al_{0.3}As layers.
The bias voltage is applied along the growth direction. Spatially direct and
indirect excitonic transitions are identified, and the radius of the exciton
and squeezing of the exciton in the growth direction are evaluated
variationally. The excitonic binding energies, recombination energies,
oscillator strengths, and relative intensities of the transitions as functions
of the applied field are calculated. Our analysis demonstrates that this simple
model is applicable in case of narrow DQWs not just for a qualitative
description of the PL peak positions but also for the estimation of their
individual shapes and intensities.Comment: 5 pages, 4 figures (accepted in Phys. Rev. B
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