57 research outputs found
Does EELS haunt your photoemission measurements?
It has been argued in a recent paper by R. Joynt (R. Joynt, Science 284, p
777 (1999)) that in the case of poorly conducting solids the photoemission
spectrum close to the Fermi Energy may be strongly influenced by extrinsic loss
processes similar to those occurring in High Resolution Electron Energy Loss
Spectroscopy (HR-EELS), thereby obscuring information concerning the density of
states or one electron Green's function sought for. In this paper we present a
number of arguments, both theoretical and experimental, that demonstrate that
energy loss processes occurring once the electron is outside the solid,
contribute only weakly to the spectrum and can in most cases be either
neglected or treated as a weak structureless background.Comment: 6 pages, figures included. Submitted to PR
Exchange Splitting and Charge Carrier Spin Polarization in EuO
High quality thin films of the ferromagnetic semiconductor EuO have been
prepared and were studied using a new form of spin-resolved spectroscopy. We
observed large changes in the electronic structure across the Curie and
metal-insulator transition temperature. We found that these are caused by the
exchange splitting of the conduction band in the ferromagnetic state, which is
as large as 0.6 eV. We also present strong evidence that the bottom of the
conduction band consists mainly of majority spins. This implies that doped
charge carriers in EuO are practically fully spin polarized.Comment: 4 pages, 5 figure
Tuning dissipation dilution in 2D material resonators by MEMS-induced tension
Resonators based on two-dimensional (2D) materials have exceptional
properties for application as nanomechanical sensors, which allows them to
operate at high frequencies with high sensitivity. However, their performance
as nanomechanical sensors is currently limited by their low quality
()-factor. Here, we make use of micro-electromechanical systems (MEMS) to
apply pure in-plane mechanical strain, enhancing both their resonance frequency
and Q-factor. In contrast to earlier work, the 2D material resonators are
fabricated on the MEMS actuators without any wet processing steps, using a
dry-transfer method. A platinum clamp, that is deposited by electron
beam-induced deposition, is shown to be effective in fixing the 2D membrane to
the MEMS and preventing slippage. By in-plane straining the membranes in a
purely mechanical fashion, we increase the tensile energy, thereby diluting
dissipation. This way, we show how dissipation dilution can increase the
-factor of 2D material resonators by 91\%. The presented MEMS actuated
dissipation dilution method does not only pave the way towards higher
-factors in resonators based on 2D materials, but also provides a route
toward studies of the intrinsic loss mechanisms of 2D materials in the
monolayer limit.Comment: 20 pages, 15 figure
Metal-insulator transition in EuO
It is shown that the spectacular metal-insulator transition in Eu-rich EuO
can be simulated within an extended Kondo lattice model. The different orders
of magnitude of the jump in resistivity in dependence on the concentration of
oxygen vacancies as well as the low-temperature resistance minimum in
high-resistivity samples are reproduced quantitatively. The huge colossal
magnetoresistance (CMR) is calculated and discussed
Highly Anisotropic Mechanical Response of the Van der Waals Magnet CrPS4
Semiconducting van der Waals magnets exhibit a rich physical phenomenology with different collective excitations, as magnons or excitons, that can be coupled, thereby offering new opportunities for optoelectronic, spintronic, and magnonic devices. In contrast with the well-studied van der Waals magnets CrI3 or Fe3GeTe2, CrPS4 is a layered metamagnet with a high optical and magnon transport anisotropy. Here, the structural anisotropy of CrPS4 above and below the magnetic phase transition is investigated by fabricating nanomechanical resonators. A large anisotropy is observed in the resonance frequency of resonators oriented along the crystalline a- and b-axis, indicative of a lattice expansion along the b-axis, boosted at the magnetic phase transition, and a rather small continuous contraction along the a-axis. This behavior in the mechanical response differs from that previously reported in van der Waals magnets, as FePS3 or CoPS3, and can be understood from the quasi-1D nature of CrPS4. The results pinpoint CrPS4 as a promising material in the field of low-dimensional magnetism and show the potential of mechanical resonators for unraveling the in-plane structural anisotropy coupled to the magnetic ordering that, in a broader context, can be extended to studying structural modifications in other 2D materials and van der Waals heterostructures
Chemical Design and Magnetic Ordering in Thin Layers of 2D Metal−Organic Frameworks (MOFs)
Through rational chemical design, and thanks to the hybrid nature of metal-organic frameworks (MOFs), it is possible to prepare molecule-based 2D magnetic materials stable at ambient conditions. Here, we illustrate the versatility of this approach by changing both the metallic nodes and the ligands in a family of layered MOFs that allows the tuning of their magnetic properties. Specifically, the reaction of benzimidazole-type ligands with different metal centers (MII = Fe, Co, Mn, Zn) in a solvent-free synthesis produces a family of crystalline materials, denoted as MUV-1(M), which order antiferromagnetically with critical temperatures that depend on M. Furthermore, the incorporation of additional substituents in the ligand results in a novel system, denoted as MUV-8, formed by covalently bound magnetic double layers interconnected by van der Waals interactions, a topology that is very rare in the field of 2D materials and unprecedented for 2D magnets. These layered materials are robust enough to be mechanically exfoliated down to a few layers with large lateral dimensions. Finally, the robustness and crystallinity of these layered MOFs allow the fabrication of nanomechanical resonators that can be used to detect─through laser interferometry─the magnetic order in thin layers of these 2D molecule-based antiferromagnets
Work function changes in the double layered manganite La1.2Sr1.8Mn2O7
We have investigated the behaviour of the work function of La1.2Sr1.8Mn2O7 as
a function of temperature by means of photoemission. We found a decrease of 55
+/- 10 meV in going from 60 K to just above the Curie temperature (125 K) of
the sample. Above T_C the work function appears to be roughly constant. Our
results are exactly opposite to the work function changes calculated from the
double-exchange model by Furukawa, but are consistent with other measurements.
The disagreement with double-exchange can be explained using a general
thermodynamic relation valid for second order transitions and including the
extra processes involved in the manganites besides double-exchange interaction.Comment: 6 pages, 4 figures included in tex
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