69 research outputs found
Evidence for Lattice Effects at the Charge-Ordering Transition in (TMTTF)X
High-resolution thermal expansion measurements have been performed for
exploring the mysterious "structureless transition" in (TMTTF)X (X =
PF and AsF), where charge ordering at coincides with the
onset of ferroelectric order. Particularly distinct lattice effects are found
at in the uniaxial expansivity along the interstack
-direction. We propose a scheme involving a charge
modulation along the TMTTF stacks and its coupling to displacements of the
counteranions X. These anion shifts, which lift the inversion symmetry
enabling ferroelectric order to develop, determine the 3D charge pattern
without ambiguity. Evidence is found for another anomaly for both materials at
0.6 indicative of a phase transition
related to the charge ordering
Resonant inelastic x-ray scattering probes the electron-phonon coupling in the spin-liquid kappa-(BEDT-TTF)2Cu2(CN)3
Resonant inelastic x-ray scattering at the N K edge reveals clearly resolved
harmonics of the anion plane vibrations in the kappa-(BEDT-TTF)2Cu2(CN)3
spin-liquid insulator. Tuning the incoming light energy at the K edge of two
distinct N sites permits to excite different sets of phonon modes. Cyanide CN
stretching mode is selected at the edge of the ordered N sites which are more
strongly connected to the BEDT-TTF molecules, while positionally disordered N
sites show multi-mode excitation. Combining measurements with calculations on
an anion plane cluster permits to estimate the sitedependent electron-phonon
coupling of the modes related to nitrogen excitation
Low temperature structural effects in the (TMTSF)PF and AsF Bechgaard salts
We present a detailed low-temperature investigation of the statics and
dynamics of the anions and methyl groups in the organic conductors
(TMTSF)PF and (TMTSF)AsF (TMTSF :
tetramethyl-tetraselenafulvalene). The 4 K neutron scattering structure
refinement of the fully deuterated (TMTSF)PF-D12 salt allows locating
precisely the methyl groups at 4 K. This structure is compared to the one of
the fully hydrogenated (TMTSF)PF-H12 salt previously determined at the
same temperature. Surprisingly it is found that deuteration corresponds to the
application of a negative pressure of 5 x 10 MPa to the H12 salt. Accurate
measurements of the Bragg intensity show anomalous thermal variations at low
temperature both in the deuterated PF and AsF salts. Two different
thermal behaviors have been distinguished. Low-Bragg-angle measurements reflect
the presence of low-frequency modes at characteristic energies {\theta} =
8.3 K and {\theta} = 6.7 K for the PF-D12 and AsF-D12 salts,
respectively. These modes correspond to the low-temperature methyl group
motion. Large-Bragg-angle measurements evidence an unexpected structural change
around 55 K which probably corresponds to the linkage of the anions to the
methyl groups via the formation of F...D-CD2 bonds observed in the 4 K
structural refinement. Finally we show that the thermal expansion coefficient
of (TMTSF)PF is dominated by the librational motion of the PF
units. We quantitatively analyze the low-temperature variation of the lattice
expansion via the contribution of Einstein oscillators, which allows us to
determine for the first time the characteristic frequency of the PF6
librations: {\theta} = 50 K and {\theta} = 76 K for the PF-D12 and
PF-H12 salts, respectively
Purely antiferromagnetic frustrated Heisenberg model in spin ladder compound BaFeSe
The spin dynamics in the block magnetic phase of the iron-based ladder
compound \bfs\ has been studied by means of single crystal inelastic neutron
scattering. Using linear spin wave theory and Monte-Carlo simulations, our
analysis points to a magnetic Heisenberg model with effective frustrated
antiferromagnetic couplings only, able to describe both the exotic block order
and its dynamics. This new and purely antiferromagnetic picture offers a
fruitful perspective to describe multiferroic properties but also understand
the origin of the stripe-like magnetic instability observed under pressure as
well as in other parent compounds with similar crystalline structure
Ground State of the Quasi-1D \bvs\ resolved by Resonant Magnetic X-ray Scattering
Resonant-magnetic x-ray scattering (RMXS) near the vanadium
-absorption edges has been used to investigate the low temperature
magnetic structure of high quality \bvs\ single crystals. Below = 31 K,
the strong resonance revealed a triple-incommensurate magnetic ordering at wave
vector (0.226 0.226 ) in the hexagonal notation, with = 0.033. The
simulations of the experimental RMXS spectra with a time-dependent density
functional theory indicate an antiferromagnetic order with the spins polarized
along in the monoclinic structure.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let
Microwave dielectric study of spin-Peierls and charge ordering transitions in (TMTTF)PF salts
We report a study of the 16.5 GHz dielectric function of hydrogenated and
deuterated organic salts (TMTTF)PF. The temperature behavior of the
dielectric function is consistent with short-range polar order whose relaxation
time decreases rapidly below the charge ordering temperature. If this
transition has more a relaxor character in the hydrogenated salt, charge
ordering is strengthened in the deuterated one where the transition temperature
has increased by more than thirty percent. Anomalies in the dielectric function
are also observed in the spin-Peierls ground state revealing some intricate
lattice effects in a temperature range where both phases coexist. The variation
of the spin-Peierls ordering temperature under magnetic field appears to follow
a mean-field prediction despite the presence of spin-Peierls fluctuations over
a very wide temperature range in the charge ordered state of these salts.Comment: 7 pages, 6 figure
Charge ordering, symmetry and electronic structure issues and Wigner crystal structure of the quarter-filled band Mott insulators and high pressure metals δ-(EDT-TTF-CONMe2)2X, X = Br and AsF6
We report on the synthesis and application of an internal chemical pressure to effectively control, and reduce, the Mott gap in the system δ-(EDT-TTF-CONMe2)2X, X = Br, AsF6; the detailed accounts of its Pmna, averaged room temperature structure and reversible phase transition at ca. 190 K towards a low tem
Near-Edge X‐ray Absorption Fine Structure Investigation of the Quasi-One-Dimensional Organic Conductor (TMTSF)2PF6
We present high-resolution near-edge X-ray absorption fine structure (NEXAFS) measurements at the P L2/3 edges, F K edge, C K edge, and Se M2/3 edges of the quasi-one-dimensional (1D) conductor and superconductor (TMTSF)2PF6. NEXAFS allows probing the donor and acceptor moieties separately; spectra were recorded between room temperature (RT) and 30 K at normal incidence. Spectra taken around RT were also studied as a function of the angle (θ) between the electric field of the X-ray beam and the 1D conducting direction. In contrast with a previous study of the S L2/3-edges spectra in (TMTTF)2AsF6, the Se M2/3 edges of (TMTSF)2PF6 do not exhibit a well-resolved spectrum. Surprisingly, the C K-edge spectra contain three well-defined peaks exhibiting strong and nontrivial θ and temperature dependence. The nature of these peaks as well as those of the F K-edge spectra could be rationalized on the basis of first-principles DFT calculations. Despite the structural similarity, the NEXAFS spectra of (TMTSF)2PF6 and (TMTTF)2AsF6 exhibit important differences. In contrast with the case of (TMTTF)2AsF6, the F K-edge spectra of (TMTSF)2PF6 do not change with temperature despite stronger donor−anion interactions. All these features reveal subtle differences in the electronic structure of the TMTSF and TMTTF families of salts
A new quantum fluid at high magnetic fields in the marginal charge-density-wave system -(BEDT-TTF)Hg(SCN) (where ~K and Rb)
Single crystals of the organic charge-transfer salts
-(BEDT-TTF)Hg(SCN) have been studied using Hall-potential
measurements (K) and magnetization experiments ( = K, Rb). The data show
that two types of screening currents occur within the high-field,
low-temperature CDW phases of these salts in response to time-dependent
magnetic fields. The first, which gives rise to the induced Hall potential, is
a free current (), present at the surface of the sample.
The time constant for the decay of these currents is much longer than that
expected from the sample resistivity. The second component of the current
appears to be magnetic (), in that it is a microscopic,
quasi-orbital effect; it is evenly distributed within the bulk of the sample
upon saturation. To explain these data, we propose a simple model invoking a
new type of quantum fluid comprising a CDW coexisting with a two-dimensional
Fermi-surface pocket which describes the two types of current. The model and
data are able to account for the body of previous experimental data which had
generated apparently contradictory interpretations in terms of the quantum Hall
effect or superconductivity.Comment: 13 pages, 11 figure
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