3,819 research outputs found
Structure and dielectric properties of polar fluids with extended dipoles: results from numerical simulations
The strengths and short-comings of the point-dipole model for polar fluids of
spherical molecules are illustrated by considering the physically more relevant
case of extended dipoles formed by two opposite charges separated by a
distance (dipole moment ). Extensive Molecular Dynamics
simulations on a high density dipolar fluid are used to analyse the dependence
of the pair structure, dielectric constant \eps and dynamics as a function of
the ratio (\sig is the molecular diameter), for a fixed dipole
moment . The point dipole model is found to agree well with the extended
dipole model up to d/\sig \simeq 0.3. Beyond that ratio, \eps shows a
non-trivial variation with d/\sig. When d/\sig>0.6, a transition is
observed towards a hexagonal columnar phase; the corresponding value of the
dipole moment, \mu^2/\sig^3 k T=3, is found to be substantially lower than
the value of the point dipole required to drive a similar transition.Comment: 10 pages, 11 figures; Paper submitted to Molecular Physic
Strong pressure-energy correlations in van der Waals liquids
Strong correlations between equilibrium fluctuations of the configurational
parts of pressure and energy are found in the Lennard-Jones liquid and other
simple liquids, but not in hydrogen-bonding liquids like methanol and water.
The correlations, that are present also in the crystal and glass phases,
reflect an effective inverse power-law repulsive potential dominating
fluctuations, even at zero and slightly negative pressure. In experimental data
for supercritical Argon, the correlations are found to be approximately 96%.
Consequences for viscous liquid dynamics are discussed.Comment: Phys. Rev. Lett., in pres
Mixed quantum-classical dynamics of an amide-I vibrational excitation in a protein a-helix
Adenosine triphosphate sATPd is known to be the main energy currency of the living cell, and is used as a coenzyme to generate energy for many cellular processes through hydrolysis to adenosine diphosphate sADPd,although the mechanism of energy transfer is not well understood. It has been proposed that following hydrolysis of the ATP cofactor bound to a protein, up to two quanta of amide-I vibrational energy are excited and utilized to bring about important structural changes in the protein. To study whether, and how, amide-I vibrational excitations are capable of leading to protein structural changes, we have added components arising from quantum-mechanical amide-I vibrational excitations to the total energy and force terms within a moleculardynamics simulation. This model is applied to helical deca-alanine as a test case to investigate how its dynamics differs in the presence or absence of an amide-I excitation. We find that the presence of an amide-I excitation can bias the structure toward a more helical state
Trans-phonon effects in ultrafast nano-devices
We report a novel phenomenon in carbon nanotube (CNT) based devices, the
transphonon effects, which resemble the transonic effects in aerodynamics. It
is caused by dissipative resonance of nanotube phonons similar to the radial
breathing mode, and subsequent drastic surge of the dragging force on the
sliding tube, and multiple phonon barriers are encountered as the intertube
sliding velocity reaches critical values. It is found that the transphonon
effects can be tuned by applying geometric constraints or varying chirality
combinations of the nanotubes
Density scaling as a property of strongly correlating viscous liquids
We address a recent conjecture according to which the relaxation time
of a viscous liquid obeys density scaling ( where
is density) if the liquid is ``strongly correlating,'' i.e., has almost 100%
correlation between equilibrium virial and potential-energy fluctuations
[Pedersen {\it et al.}, PRL {\bf 100}, 011201 (2008)]. Computer simulations of
two model liquids - an asymmetric dumbbell model and the Lewis-Wahnstr\"om OTP
model - confirm the conjecture and demonstrate that the scaling exponent
can be accurately predicted from equilibrium fluctuations.Comment: 5 pages, 5 figures. Data added for Lewis-Wahnstrom OT
Molecular dynamics simulation of nanocolloidal amorphous silica particles: Part II
Explicit molecular dynamics simulations were applied to a pair of amorphous
silica nanoparticles of diameter 3.2 nm immersed in a background electrolyte.
Mean forces acting between the pair of silica nanoparticles were extracted at
four different background electrolyte concentrations. Dependence of the
inter-particle potential of mean force on the separation and the silicon to
sodium ratio, as well as on the background electrolyte concentration, are
demonstrated. The pH was indirectly accounted for via the ratio of silicon to
sodium used in the simulations. The nature of the interaction of the
counter-ions with charged silica surface sites (deprotonated silanols) was also
investigated. The effect of the sodium double layer on the water ordering was
investigated for three Si:Na+ ratios. The number of water molecules trapped
inside the nanoparticles was investigated as the Si:Na+ ratio was varied.
Differences in this number between the two nanoparticles in the simulations are
attributed to differences in the calculated electric dipole moment. The
implications of the form of the potentials for aggregation are also discussed.Comment: v1. 33 pages, 7 figures (screen-quality PDF), submitted to J. Chem.
Phys v2. 15 pages, 4 tables, 6 figures. Content, author list and title
changed; single space
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IPEP: The integrated performance evaluation program for the Department of Energy`s Office of Environmental Management
The quality of the analytical data being provided to DOE`s Office of Environmental Management (EM) for environmental restoration activities and the extent to which these data meet the data quality objectives are critical in the decision-making process. One of several quality metrics that can be used in evaluating a laboratory is its performance in performance evaluation (PE) programs. In support of DOE`s environmental restoration and waste management efforts, EM has been charged with developing and implementing a program to assess the performance of participating laboratories. Argonne National Laboratory (ANL) and DOE`s Environmental Measurements Laboratory (EML) and Radiological and Environmental Sciences Laboratory (RESL) have been collaborating on the development and implementation of a comprehensive Integrated Performance Evaluation Program (IPEP) for DOE-wide implementation. The IPEP will use results from existing inorganic, organic, and radiological PE programs when these are available and appropriate for the analytes and matrices being determined for DOE`s EM activities. Existing programs include the U.S. Environmental Protection Agency`s (EPA`s) Contract Laboratory Program (CLP), the Water Supply (WS) and Water Pollution (WP) PE studies for inorganic and organic analytes, and DOE`s Quality Assessment Program (QAP) for radiological analytes. In addition, DOE has begun the development of the Mixed Analyte Performance Evaluation Program (MAPEP) to address the needs of the DOE Complex. These PE programs provide a spectrum of matrices and analytes covering the various inorganic, organic, and low-level radiologic categories found in routine environmental and waste samples. These PE programs already provide some assessment of laboratory performance; IPEP will expand these assessments by evaluating historical performance, as well as results from multiple PE programs, thereby providing an enhanced usage of the PE program information
Long Distance Correlations in Molecular Orientations of Liquid Water and Shape Dependant Hydrophobic Force
Liquid water, at ambient conditions, has short-range density correlations
which are well known in literature. Surprisingly, large scale molecular
dynamics simulations reveal an unusually long-distance correlation in
`longitudinal' part of dipole-dipole orientational correlations. It is
non-vanishing even at 75 \AA{} and falls-off exponentially with a correlation
length of about 24 \AA{} beyond solvation region. Numerical evidence suggests
that the long range nature of dipole-dipole correlation is due to underlying
fluctuating network of hydrogen-bonds in the liquid phase. This correlation is
shown to give a shape dependant attraction between two hydrophobic surfaces at
large distances of separation and the range of this attractive force is in
agreement with experiments. In addition it is seen that quadrupolar
fluctuations vanish within the first solvation peak (3 \AA{})Comment: 11 pages, 3 figure
The AMANDA Neutrino Telescope and the Indirect Search for Dark Matter
With an effective telescope area of order 10^4 m^2, a threshold of ~50 GeV
and a pointing accuracy of 2.5 degrees, the AMANDA detector represents the
first of a new generation of high energy neutrino telescopes, reaching a scale
envisaged over 25 years ago. We describe its performance, focussing on the
capability to detect halo dark matter particles via their annihilation into
neutrinos.Comment: Latex2.09, 16 pages, uses epsf.sty to place 15 postscript figures.
Talk presented at the 3rd International Symposium on Sources and Detection of
Dark Matter in the Universe (DM98), Santa Monica, California, Feb. 199
Characterization by rapid-kinetic and equilibrium methods of the interaction between N-terminally truncated forms of chicken cystatin and the cysteine proteinases papain and actinidin
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