406 research outputs found
Very large ensemble ocean forecasting experiment using the Grid computing infrastructure
Atmospheric and oceanic ensemble forecasting is a way to deal with uncertainty related
to inaccurate knowledge of the initial state of the atmosphere and the ocean, the lateral
and vertical boundary condition errors and the model physics shortfalls (Lewis, 2005,
Epstein, 1969). Since the atmosphere and the ocean are extremely non-linear systems
(Lorenz, 1993, Saravanan et al., 2000) initial uncertainties can amplify and limit the
predictability of short term forecasts (Kleeman and Majda, 2005).
For the ocean, ensemble forecasting is a novel field. Ensemble methods are used
to compute the background error covariance matrix in data assimilation schemes
(Evensen, 2003) but are not used yet to quantify the forecast uncertainty in short term
ocean forecasting systems. Initial conditions uncertainty is a major source of
unpredictability for ocean currents due to the limited observations available for
nowcasting and the highly non-linear physics. In this study we explore the short term
ensemble forecast variance generated by perturbing the initial conditions using a new
computational facility, so-called Grid infrastructure (http://grid.infn.it/), distributed over
the Italian territory. This infrastructure allowed us to perform several ensemble forecast
experiments with 1000 members: they are completed within 5 hours of wall-clock time
after their submission and the ensemble variance peaks at the mesoscales
Eliopoulosite, V7S8, A New Sulfide from the Podiform Chromitite of the Othrys Ophiolite, Greece
The new mineral species, eliopoulosite, V7S8, was discovered in the abandoned chromium mine of Agios Stefanos of the Othrys ophiolite, located in central Greece. The investigated samples consist of massive chromitite hosted in a strongly altered mantle tectonite, and are associated with nickelphosphide, awaruite, tsikourasite, and grammatikopoulosite. Eliopoulosite is brittle and has a metallic luster. In plane-reflected polarized light, it is grayish-brown and shows no internal reflections, bireflectance, and pleochroism. It is weakly anisotropic, with colors varying from light to dark greenish. Reflectance values of mineral in air (Ro, Re’ in %) are: 34.8–35.7 at 470 nm, 38–39 at 546 nm, 40–41.3 at 589 nm, and 42.5–44.2 at 650 nm. Electron-microprobe analyses yielded a mean composition (wt.%) of: S 41.78, V 54.11, Ni 1.71, Fe 1.1, Co 0.67, and Mo 0.66, totali 100.03. On the basis of Σatoms = 15 apfu and taking into account the structural data, the empirical formula of eliopoulosite is (V6.55Ni0.19Fe0.12Co0.07Mo0.04)Σ = 6.97S8.03. The simplified formula is (V, Ni, Fe)7S8 and the ideal formula is V7S8, which corresponds to V 58.16%, S 41.84%, total 100 wt.%. The density, based on the empirical formula and unit-cell volume refined form single-crystal structure XRD data, is 4.545 g·cm−3. The mineral is trigonal, space group P3221, with a = 6.689(3) Å, c = 17.403(6) Å, V = 674.4(5) Å3, Z = 3, and exhibits a twelve-fold superstructure (2a × 2a × 3c) of the NiAs-type subcell with V-atoms octahedrally coordinated by S atoms. The distribution of vacancies is discussed in relation to other pyrrhotite-like compounds. The mineral name is for Dr. Demetrios Eliopoulos (1947–2019), a geoscientist at the Institute of Geology and Mineral Exploration (IGME) of Greece and his widow, Prof. Maria Eliopoulos (nee Economou, 1947), University of Athens, Greece, for their contributions to the knowledge of ore deposits of Greece and to the mineralogical, petrographic, and geochemical studies of ophiolites, including the Othrys complex. The mineral and its name have been approved by the Commission of New Minerals, Nomenclature, and Classification of the International Mineralogical Association (No. 2019-96).© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access
article distributed under the terms and conditions of the Creative Commons Attribution
(CC BY) license (http://creativecommons.org/licenses/by/4.0/)
Effects of quarantine on Physical Activity prevalence in Italian Adults: a pilot study
Background: COVID-19 is a respiratory disease that caused a global pandemic status in March 2020. Due to its fast diffusion, many governments adopted forced solutions including social restrictions, which could negatively affect citizens’ habits as physical activity. Our study aimed to investigate how and why the physical activity prevalence varied from the period before the quarantine up to the period after it, and understand what citizens thought of physical inactivity COVID-19 related to and whether they were satisfied with physical activity promotion during the lockdown. Methods: A new questionnaire was created and administered online. A sample of 749 interviews (female = 552 (73.7%), male = 197 (26.3%)) was collected and analysed. Results: The prevalence of people who were older than 50 years reduced both during and after the lockdown (P < 0.05) and the most common reason for which they have quitted physical activity practice was related to psychological problems (lockdown = 64.57%; post-lockdown = 62.17%). In addition, youngers seemed to be more sensitive than elders to unhealthy consequences generated by forced isolation (P < 0.05), and they believed that children/adolescents and older adults practised an insufficient amount of physical activity and/or sport, which could negatively impact public health. Conclusions: Although many strategies were implemented during the lockdown to promote regular physical activity practice, several results suggested that quarantine negatively affected citizens’ habits. The future government should focus on adequate measures to improve health behaviours
Intermediate phase, network demixing, boson and floppy modes, and compositional trends in glass transition temperatures of binary AsxS1-x system
The structure of binary As_xS_{1-x} glasses is elucidated using
modulated-DSC, Raman scattering, IR reflectance and molar volume experiments
over a wide range (8%<x<41%) of compositions. We observe a reversibility window
in the calorimetric experiments, which permits fixing the three elastic phases;
flexible at x<22.5%, intermediate phase (IP) in the 22.5%<x<29.5% range, and
stressed-rigid at x>29.5%. Raman scattering supported by first principles
cluster calculations reveal existence of both pyramidal (PYR, As(S1/2)3) and
quasi-tetrahedral(QT, S=As(S1/2)3) local structures. The QT unit concentrations
show a global maximum in the IP, while the concentration of PYR units becomes
comparable to those of QT units in the phase, suggesting that both these local
structures contribute to the width of the IP. The IP centroid in the sulfides
is significantly shifted to lower As content x than in corresponding selenides,
a feature identified with excess chalcogen partially segregating from the
backbone in the sulfides, but forming part of the backbone in selenides. These
ideas are corroborated by the proportionately larger free volumes of sulfides
than selenides, and the absence of chemical bond strength scaling of Tgs
between As-sulfides and As-selenides. Low-frequency Raman modes increase in
scattering strength linearly as As content x of glasses decreases from x = 20%
to 8%, with a slope that is close to the floppy mode fraction in flexible
glasses predicted by rigidity theory. These results show that floppy modes
contribute to the excess vibrations observed at low frequency. In the
intermediate and stressed rigid elastic phases low-frequency Raman modes
persist and are identified as boson modes. Some consequences of the present
findings on the optoelectronic properties of these glasses is commented upon.Comment: Accepted for PR
Five-dimensional structure refinement of natural melilite, (Ca1.89Sr0.01Na0.08K0.02)(Mg0.92Al0.08)-(Si1.98Al0.02)O-7
The structure of a crystal of natural melilite from San Venanzo, Umbria (Italy) of the general formula X(2)T1(T2)(2)O-7, where X = Ca0.945Sr0.005Na0.04K0.01, T1 = Mg0.92Al0.08 and T2 = Si0.99Al0.01, has been solved and refined as an incommensurate structure in five-dimensional superspace. The structure is tetragonal, superspace group P (4) over bar2(1)m:p4mg, cell parameters a = 7.860 (1), c =5.024 (1) Angstrom, modulation vectors q(1) = 0.2815 (3)(a* +b*), q(2) = 0.2815 (3)(-a* +b*). The data collection was performed on a KumaCCD diffractometer. The structure was refined from 7606 reflections to final R = 0.0481. A special modification of the refinement program Jana2000 was necessary to take into account overlapping of satellite reflections m x n = +/- 1, which could not be properly separated in the integration procedure. The final model includes modulations of the atomic positions as well as modulations of the thermal parameters. The latter are induced by strong differences in the neighbourhood of the actual modulated positions. The occupational modulation was neither significant for X nor for T1 sites and the sites were supposed to be occupied only by Ca and Mg, respectively. As a consequence of the Ca and O positional modulations six-, seven- and eightfold Ca coordination occur throughout the structure and the thermal ellipsoid changes its shape correspondingly. The positional modulation of the atoms causes variations in the interatomic distances which, however, do not affect bond-valence sums considerably, but induce flattening and rotation in T1 and T2 tetrahedra, respectively. [References: 23] 2
Analysis of serious games implementation for project management courses
Previous researches in pedagogy and project management have already underlined the positive contribution of serious games on project management courses. However, the empirical outcome of their studies has not been translated yet into functional and technical specifications for "serious games" designers. Our study aims at obtaining a set of technical and functional design guidelines for serious game scenario editors to be used in large classes of project management students. We have conceived a framework to assess the influence of different serious games components over student's perceived acquired competency. Such frameworks will allow us to develop a software module for reflective learning, which is meant to extend theory of serious games design
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