602 research outputs found
Legislative Constitutional Interpretation
The standard method of estimating the value of travel time variability for use in policy appraisal is to estimate the parameters of a reduced-form utility function, where some measure of travel time variability (such as the standard deviation) is included. A problem with this approach is that the obtained valuation will in general depend on the standardized travel time distribution, and hence cannot be transferred from one context to another. A recently suggested remedy for this problem has been to estimate a scheduling model, which in theory is transferrable, and use the implied reduced-form to derive valuations for use in appraisal. In this paper we estimate both a scheduling model and the implied reduced-form model, using stated choice data. The valuation of travel time variability implied by the scheduling model turns out to be substantially smaller than what is obtained from a reduced-form model estimated on the same sample. The results suggest that the scheduling model does not capture all of the disutility arising from travel time variability. Hence, although it can be shown that scheduling and reduced-form models are theoretically equivalent, that hypothesized equivalence is not reflected in the empirical evidence. We speculate that the derivation of reduced-form models from an underlying scheduling model omits two essential features: first, the notion of an exogenously fixed “preferred arrival time” neglects the fact that most activities can be rescheduled given full information about the travel times in advance, and second, disutility may be derived from uncertainty as such, in the form of anxiety, decisions costs or costs for having contingency plans. We also report our estimates of the valuation of travel time variability for public transit trips, for use in applied appraisal
Effects of hydrogen bonding on supercooled liquid dynamics and the implications for supercooled water
The supercooled state of bulk water is largely hidden by unavoidable
crystallization, which creates an experimentally inaccessible temperature
regime - a 'no man's land'. We address this and circumvent the crystallization
problem by systematically studying the supercooled dynamics of hydrogen bonded
oligomeric liquids (glycols), where water corresponds to the chain-ends alone.
This novel approach permits a 'dilution of water' by altering the hydrogen bond
concentration via variations in chain length. We observe a dynamic crossover in
the temperature dependence of the structural relaxation time for all glycols,
consistent with the common behavior of most supercooled liquids. We find that
the crossover becomes more pronounced for increasing hydrogen bond
concentrations, which leads to the prediction of a marked dynamic transition
for water within 'no man's land' at T~220 K. Interestingly, the predicted
transition thus takes place at a temperature where a so called 'strong-fragile'
transition has previously been suggested. Our results, however, imply that the
dynamic transition of supercooled water is analogous to that commonly observed
in supercooled liquids. Moreover, we find support also for the existence of a
secondary relaxation of water with behavior analogous to that of the secondary
relaxation observed for the glycols.Comment: 20 pages, 5 figures; corrected typos, title changed, small clarifying
text changes, two labels removed from Fig. 2
Soft-Surface DNA Nanotechnology: DNA Constructs Anchored and Aligned to Lipid Membrane**
No strings attached: At least three attachment points are needed to align a two-dimensional DNA nanoconstruct to a soft lipid membrane surface with a porphyrin nucleoside as membrane anchor (see picture). The resulting freely diffusing DNA constructs can be reversibly assembled on the surface thus enabling the possibility of a self-repairing system. \ua9 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Use of near infrared reflectance spectroscopy to predict nitrogen uptake by winter wheat within fields with high variability in organic matter
In this study, the ability to predict N-uptake in winter wheat crops using NIR-spectroscopy on soil samples was evaluated. Soil samples were taken in unfertilized plots in one winter wheat field during three years (1997-1999) and in another winter wheat field nearby in one year (2000). Soil samples were analyzed for organic C content and their NIR-spectra. N-uptake was measured as total N-content in aboveground plant materials at harvest. Models calibrated to predict N-uptake were internally cross validated and validated across years and across fields. Cross-validated calibrations predicted N-uptake with an average error of 12.1 to 15.4 kg N ha-1. The standard deviation divided by this error (RPD) ranged between 1.9 and 2.5. In comparison, the corresponding calibrations based on organic C alone had an error from 11.7 to 28.2 kg N ha-1 and RPDs from 1.3 to 2.5. In three of four annual calibrations within a field, the NIR-based calibrations worked better than the organic C based calibrations. The prediction of N-uptake across years, but within a field, worked slightly better with an organic C based calibration than with a NIR based one, RPD = 1.9 and 1.7 respectively. Across fields, the corresponding difference was large in favour of the NIR-calibration, RPD = 2.5 for the NIR-calibration and 1.5 for the organic C calibration. It was concluded that NIR-spectroscopy integrates information about organic C with other relevant soil components and therefore has a good potential to predict complex functions of soils such as N-mineralization. A relatively good agreement of spectral relationships to parameters related to the N-mineralization of datasets across the world suggests that more general models can be calibrated
Propylene Carbonate Reexamined: Mode-Coupling Scaling without Factorisation ?
The dynamic susceptibility of propylene carbonate in the moderately viscous
regime above is reinvestigated by incoherent neutron and
depolarised light scattering, and compared to dielectric loss and solvation
response. Depending on the strength of relaxation, a more or less
extended scaling regime is found. Mode-coupling fits yield consistently
and K, although different positions of the
susceptibility minimum indicate that not all observables have reached the
universal asymptotics
Theoretical study of the thermal behavior of free and alumina-supported Fe-C nanoparticles
The thermal behavior of free and alumina-supported iron-carbon nanoparticles
is investigated via molecular dynamics simulations, in which the effect of the
substrate is treated with a simple Morse potential fitted to ab initio data. We
observe that the presence of the substrate raises the melting temperature of
medium and large nanoparticles ( = 0-0.16, = 80-1000, non-
magic numbers) by 40-60 K; it also plays an important role in defining the
ground state of smaller Fe nanoparticles ( = 50-80). The main focus of our
study is the investigation of Fe-C phase diagrams as a function of the
nanoparticle size. We find that as the cluster size decreases in the
1.1-1.6-nm-diameter range the eutectic point shifts significantly not only
toward lower temperatures, as expected from the Gibbs-Thomson law, but also
toward lower concentrations of C. The strong dependence of the maximum C
solubility on the Fe-C cluster size may have important implications for the
catalytic growth of carbon nanotubes by chemical vapor deposition.Comment: 13 pages, 11 figures, higher quality figures can be seen in article 9
at http://alpha.mems.duke.edu/wahyu
Struggling for recognition and inclusion—parents' and pupils' experiences of special support measures in school
During the last decade an increasing use of differentiated support measures for pupils with special educational needs, indicative of a discrepancy between educational policies and practices, has been witnessed in Sweden. Another trend has been the increased use of medical diagnoses in school. The aim of this study was to explore the main concern of support given to pupils with special educational needs and how pupils and parents experience and handle this. Interviews were conducted with eight pupils in Grades 7–9—and their parents—at two compulsory schools in a city in northern Sweden. A grounded theory approach was used for analyzing the interview data. A conceptual model was generated illuminating the main concern of special support measures for pupils and parents. The core category of the model, struggling for recognition and inclusion, was related to two categories, which further described how this process was experienced and handled by the participants. These categories were labeled negotiating expertise knowledge within a fragmented support structure and coping with stigma, ambivalence, and special support measures. The developed conceptual model provides a deeper understanding of an ongoing process of struggle for recognition and inclusion in school as described by the pupils and parents
Universal and non-universal features of glassy relaxation in propylene carbonate
It is demonstrated that the susceptibility spectra of supercooled propylene
carbonate as measured by depolarized-light-scattering, dielectric-loss, and
incoherent quasi-elastic neutron-scattering spectroscopy within the GHz window
are simultaneously described by the solutions of a two-component schematic
model of the mode-coupling theory (MCT) for the evolution of glassy dynamics.
It is shown that the universal beta-relaxation-scaling laws, dealing with the
asymptotic behavior of the MCT solutions, describe the qualitative features of
the calculated spectra. But the non-universal corrections to the scaling laws
render it impossible to achieve a complete quantitative description using only
the leading-order-asymptotic results.Comment: 37 pages, 16 figures, to be published in Phys. Rev.
Physical Origin of the Boson Peak Deduced from a Two-Order-Parameter Model of Liquid
We propose that the boson peak originates from the (quasi-) localized
vibrational modes associated with long-lived locally favored structures, which
are intrinsic to a liquid state and are randomly distributed in a sea of
normal-liquid structures. This tells us that the number density of locally
favored structures is an important physical factor determining the intensity of
the boson peak. In our two-order-parameter model of the liquid-glass
transition, the locally favored structures act as impurities disturbing
crystallization and thus lead to vitrification. This naturally explains the
dependence of the intensity of the boson peak on temperature, pressure, and
fragility, and also the close correlation between the boson peak and the first
sharp diffraction peak (or prepeak).Comment: 5 pages, 1 figure, An error in the reference (Ref. 7) was correcte
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