206 research outputs found
Non-radiative resonance energy transfer in bi-polymer nanoparticles of fluorescent conjugated polymers
Cataloged from PDF version of article.his work demonstrates the comparative studies of non-radiative resonance energy transfer in bi-polymer nanoparticles based on fluorescent conjugated polymers. For this purpose, poly[(9,9-dihexylfluorene) (PF) as a donor (D) and poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) as an acceptor (A) have been utilized, from which four different bi-polymer nanoparticle systems are designed and synthesized. Both, steady-state fluorescence spectra and time-resolved fluorescence measurements indicate varying energy transfer efficiencies from the host polymer PF to the acceptor polymer MEH-PPV depending on the D-A distances and structural properties of the nanoparticles. The first approach involves the preparation of PF and MEH-PPV nanoparticles separately and mixing them at a certain ratio. In the second approach, first PF and MEH-PPV solutions are mixed prior to nanoparticle formation and then nanoparticles are prepared from the mixture. Third and fourth approaches involve the sequential nanoparticle preparation. In the former, nanoparticles are prepared to have PF as a core and MEH-PPV as a shell. The latter is the reverse of the third in which the core is MEH-PPV and the shell is PF. The highest energy transfer efficiency recorded to be 35% is obtained from the last system, in which a PF layer is sequentially formed on MEH-PPV NPs. © 2010 Optical Society of America
Quantum efficiency enhancement in film by making nanoparticles of polyfluorene
Cataloged from PDF version of article.We report on conjugated polymer nanoparticles of polyfluorene that were formed to exhibit higher fluorescence quantum efficiency in film (68%) and reduce undesired emission peak wavelength shifts in film (by 20 nm), compared to the solid-state polymer thin film made directly out of the same polymer solution without forming nanoparticles. Using the facile reprecipitation method, solutions of poly[9,9-dihexyl-9H-fluorene] in THF were added at different volume ratios to obtain different size distributions of nanoparticle dispersions in water. This allowed us to control the sizedependent optical emission of our polyfluorene nanoparticles. Such organic nanoparticles hold great promise for use as efficient emitters in optoelectronic device applications. (C) 2008 Optical Society of America
Observation of Selective Plasmon-Exciton Coupling in Nonradiative Energy Transfer: Donor-Selective versus Acceptor-Selective
Cataloged from PDF version of article.We report selectively plasmon-mediated nonradiative energy transfer between quantum dot (QD) emitters interacting with each other via Forster-type resonance energy transfer (FRET) under controlled plasmon coupling either to only the donor QDs (i.e., donor-selective) or to only the acceptor QDs (i.e., acceptor-selective). Using layer-by-layer assembled colloidal QD nanocrystal solids with metal nanoparticles integrated at carefully designed spacing, we demonstrate the ability to enable/disable the coupled plasmon-exciton (plexciton) formation distinctly at the donor (exciton departing) site or at the acceptor (exciton feeding) site of our choice, while not hindering the donor exciton-acceptor exciton interaction but refraining from simultaneous coupling to both sites of the donor and the acceptor in the FRET process.. In the case of donor-selective plexciton, we observed a substantial shortening in the donor QD lifetime from 1.33 to 0.29 ns as a result of plasmon-coupling to the donors and the FRET-assisted exciton transfer from the donors to the acceptors, both of which shorten the donor lifetime. This consequently enhanced the acceptor emission by a factor of 1.93. On the other hand, in the complimentary case of acceptor-selective plexciton, we observed a 2.70-fold emission enhancement in the acceptor QDs, larger than the acceptor emission enhancement of the donor-selective plexciton, as a result of the combined effects of the acceptor plasmon coupling and the FRET-assisted exciton feeding. Here we present the comparative results of theoretical modeling of the donor- and acceptor-selective plexcitons of nonradiative energy transfer developed here for the first time, which are in excellent agreement with the systematic experimental characterization. Such an ability to modify and control energy transfer through mastering plexcitons is of fundamental importance, opening up new applications for quantum dot embedded plexciton devices along with the development of new techniques in FRET-based fluorescence microscopy
Anisotropic Emission from Multilayered Plasmon Resonator Nanocomposites of Isotropic Semiconductor Quantum Dots
Cataloged from PDF version of article.We propose and demonstrate a nanocomposite localized surface plasmon resonator
embedded into an artificial three-dimensional construction. Colloidal semiconductor quantum dots
are assembled between layers of metal nanoparticles to create a highly strong plasmon-exciton
interaction in the plasmonic cavity. In such a multilayered plasmonic resonator architecture of
isotropic CdTe quantum dots, we observed polarized light emission of 80% in the vertical
polarization with an enhancement factor of 4.4, resulting in a steady-state anisotropy value of
0.26 and reaching the highest quantum efficiency level of 30% ever reported for such CdTe quantum
dot solids. Our electromagnetic simulation results are in good agreement with the experimental
characterization data showing a significant emission enhancement in the vertical polarization, for
which their fluorescence decay lifetimes are substantially shortened by consecutive replication of our
unit cell architecture design. Such strongly plasmon-exciton coupling nanocomposites hold great
promise for future exploitation and development of quantum dot plasmonic biophotonics and
quantum dot plasmonic optoelectronics
White emitting polyfluorene functionalized with azide hybridized on near-UV light emitting diode for high color rendering index
Cataloged from PDF version of article.We develop and demonstrate high-quality white light generation that relies on the use of a single-type simple conjugated polymer of polyfluorene functionalized with azide groups (PFA) integrated on a near-UV LED platform. The high-quality white emission from the polyfluorene is achieved by using the azide functionalization to facilitate cross-linking intentionally when cast into solid-state form. Hybridized on n-UV InGaN/GaN LED at 378 nm, the PFA emitters collectively generate a very broad down-converting photoluminescence at longer wavelengths across the entirety of the visible spectrum, yielding high color rendering indices up to 91. (c) 2008 Optical Society of America
First observation of a narrow charm-strange meson DsJ(2632) -> Ds eta and D0 K+
We report the first observation of a charm-strange meson DsJ(2632) at a mass
of 2632.6+/-1.6 MeV/c^2 in data from SELEX, the charm hadro-production
experiment E781 at Fermilab. This state is seen in two decay modes, Ds eta and
D0 K+. In the Ds eta decay mode we observe an excess of 49.3 events with a
significance of 7.2sigma at a mass of 2635.9+/-2.9 MeV/c^2. There is a
corresponding peak of 14 events with a significance of 5.3sigma at 2631.5+/-1.9
MeV/c^2 in the decay mode D0 K+. The decay width of this state is <17 MeV/c^2
at 90% confidence level. The relative branching ratio Gamma(D0K+)/Gamma(Dseta)
is 0.16+/-0.06. The mechanism which keeps this state narrow is unclear. Its
decay pattern is also unusual, being dominated by the Ds eta decay mode.Comment: 5 pages, 3 included eps figures. v2 as accepted for publication by
PR
First Measurement of pi e -> pi e gamma Pion Virtual Compton Scattering
Pion Virtual Compton Scattering (VCS) via the reaction pi e --> pi e gamma
was observed in the Fermilab E781 SELEX experiment. SELEX used a 600 GeV/c pi-
beam incident on target atomic electrons, detecting the incident pi- and the
final state pi-, electron and gamma. Theoretical predictions based on chiral
perturbation theory are incorporated into a Monte Carlo simulation of the
experiment and are compared to the data. The number of reconstructed events (9)
and their distribution with respect to the kinematic variables (for the
kinematic region studied) are in reasonable accord with the predictions. The
corresponding pi- VCS experimental cross section is sigma=38.8+-13 nb, in
agreement with the theoretical expectation sigma=34.7 nb.Comment: 10 pages, 12 figures, 4 tables, 25 references, SELEX home page is
http://fn781a.fnal.gov/, revised July 21, 2002 in response to journal referee
Comment
Observation of the Cabibbo-suppressed decay Xi_c+ -> p K- pi+
We report the first observation of the Cabibbo-suppressed charm baryon decay
Xi_c+ -> p K- pi+. We observe 150 +- 22 events for the signal. The data were
accumulated using the SELEX spectrometer during the 1996-1997 fixed target run
at Fermilab, chiefly from a 600 GeV/c Sigma- beam. The branching fractions of
the decay relative to the Cabibbo-favored Xi_c+ -> Sigma+ K- pi+ and Xi_c+ ->
X- pi+ pi+ are measured to be B(Xi_c+ -> p K- pi+)/B(Xi_c+ -> Sigma+ K- pi+) =
0.22 +- 0.06 +- 0.03 and B(Xi_c+ -> p K- pi+)/B(Xi_c+ -> X- pi+ pi+) = 0.20 +-
0.04 +- 0.02, respectively.Comment: 5 pages, RevTeX, 3 figures (postscript), Submitted to Phys. Rev. Let
First Observation of the Doubly Charmed Baryon Xi_cc^+
We observe a signal for the doubly charmed baryon Xi_cc^+ in the charged
decay mode Xi_cc^+ --> Lambda_c^+ K- pi+ in data from SELEX, the charm
hadro-production experiment at Fermilab. We observe an excess of 15.9 events
over an expected background of 6.1 +/- 0.5 events, a statistical significance
of 6.3sigma. The observed mass of this state is (3519 +/- 1) MeV/c^2. The
Gaussian mass width of this state is 3MeV/c^2, consistent with resolution; its
lifetime is less than 33fsec at 90% confidence.Comment: 5 pages, 3 figures, accepted for publication in Physical Review
Letter
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