Kinetic, Isotherm and Thermodynamic Analysis on Adsorption of Cr(VI) Ions from Aqueous Solutions by Synthesis and Characterization of Magnetic-Poly(divinylbenzene-vinylimidazole) Microbeads

The magnetic-poly(divinylbenzene-1-vinylimidazole) [m-poly(DVB-VIM)] microbeads (average diameter 53–212 μm) were synthesized and characterized; their use as adsorbent in removal of Cr(VI) ions from aqueous solutions was investigated. The m-poly(DVB-VIM) microbeads were prepared by copolymerizing of divinylbenzene (DVB) with 1-vinylimidazole (VIM). The m-poly(DVB-VIM) microbeads were characterized by N2 adsorption/desorption isotherms, ESR, elemental analysis, scanning electron microscope (SEM) and swelling studies. At fixed solid/solution ratio the various factors affecting adsorption of Cr(VI) ions from aqueous solutions such as pH, initial concentration, contact time and temperature were analyzed. Langmuir, Freundlich and Dubinin–Radushkvich isotherms were used as the model adsorption equilibrium data. Langmuir isotherm model was the most adequate. The pseudo-first-order, pseudo-second-order, Ritch-second-order and intraparticle diffusion models were used to describe the adsorption kinetics. The apparent activation energy was found to be 5.024 kJ mol−1, which is characteristic of a chemically controlled reaction. The experimental data fitted to pseudo-second-order kinetic. The study of temperature effect was quantified by calculating various thermodynamic parameters such as Gibbs free energy, enthalpy and entropy changes. The thermodynamic parameters obtained indicated the endothermic nature of adsorption of Cr(VI) ions. Morever, after the use in adsorption, the m-poly(DVB-VIM) microbeads with paramagnetic property were separeted via the applied magnetic force. The magnetic beads could be desorbed up to about 97% by treating with 1.0 M NaOH. These features make the m-poly(DVB-VIM) microbeads a potential candidate for support of Cr(VI) ions removal under magnetic field

USING SATELLITE OBSERVATION FOR EARLY WARNING OF CONVECTIVE STORM IN TEHRAN

Severe convective storms are responsible for large amount of damage each year around the world. They form an important part of the climate system by redistributing heat, moisture, and trace gases, as well as producing large quantities of precipitation. As these extreme and rare events are in mesoscale there is many uncertainty in predicting them and we can’t rely on just models. On the other hand, remote sensing has a large application in Meteorology and near real time weather forecasting, especially in rare and extreme events like convective storms that might be difficult to predict with atmospheric models. On second of June 2014, near 12UTC a sudden and strong convective storm occurred in Tehran province that was not predicted, and caused economic and human losses. In This research we used satellite observations along with synoptic station measurements to predict and monitor this storm. Results from MODIS data show an increase in the amount of cloudiness and also aerosol optical depth and sudden decrease in cloud top temperature few hours before the storm occurs. EUMETSAT images show the governing of convection before the storm occurs. With combining the observation data that shows Lake of humidity and high temperature in low levels with satellite data that reveals instability in high levels that together caused this convective, we could track the storm and decrease the large amount of damage

Removal of hexavalent chromium-contaminated water and wastewater: A review

Cr(VI) is a well-known highly toxic metal, considered a priority pollutant. Industrial sources of Cr(VI) include leather tanning, cooling tower blowdown, plating, electroplating, anodizing baths, rinse waters, etc. This article includes a survey of removal techniques for Cr(VI)-contaminated aqueous solutions. A particular focus is given to adsorption, membrane filtration, ion exchange, and electrochemical treatment methods. The primary objective of this article is to provide recent information about the most widely used techniques for Cr(VI) removal

Hexavalent chromium adsorption on impregnated palm shell activated carbon with polyethyleneimine

Removal of Cr(VI) ions from aqueous solution was investigated using modified palm shell activated carbon. Low Molecular Weight Polyethyleneimine (LMW PEI) was used for impregnation purpose. The maximum amount of LMW PEI adsorbed on activated carbon was determined to be approximately 228.2 mg/g carbon. The adsorption experiments were carried out in a batch system using potassium dichromate K2Cr2O7 as the source of Cr(VI) in the synthetic waste water and modified palm shell activated carbon as the adsorbent. The effects of pH, concentration of Cr(VI) and PEI loaded on activated carbon were studied. The adsorption data were found to fit well with the Freundlich isotherm model. This modified Palm shell activated carbon showed high adsorption capacity for chromium ions

The electrochemical reduction of Cr(VI) ions in acid solution at titanium and graphite electrodes

Cyclic voltammetry (CV) and rotating disc electrode (RDE) linear sweep voltammetry were used to study the reduction of Cr(VI) ions on a titanium electrode at 298 K. Diffusion controlled reduction of Cr(VI) ions occurred between –0.22 V and –0.45 V vs. Ag/AgCl and appears to take place in a single, 3-electron step. The diffusion coefficient was 1.2 × 10-5 cm2 s-1, which agrees with data reported in the literature. Following a study in a three-electrode cell, the electrolysis of 2 × 10-3 mol dm-3 Cr(VI) in 0.1 mol dm-3 H2SO4 solution at –1.0 V vs. Ag/AgCl, on titanium and –0.65 V vs. Ag/AgCl on carbon electrodes were carried out. The area of the electrodes was 64 cm2 and the mean linear flow velocity of electrolyte past the cathode varied between 10 and 80 cm s-1 (630 – 5680 cm3 min-1). The parasitic reactions of oxygen reduction and hydrogen evolution, which decreased the current efficiency, were observed during the reduction of Cr(VI) ions at titanium electrode