55 research outputs found

    Bifurcations of cubic homoclinic tangencies in two-dimensional symplectic maps

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    We study bifurcations of cubic homoclinic tangencies in two-dimensional symplectic maps. We distinguish two types of cubic homoclinic tangencies, and each type gives different first return maps derived to diverse conservative cubic H\'enon maps with quite different bifurcation diagrams. In this way, we establish the structure of bifurcations of periodic orbits in two parameter general unfoldings generalizing to the conservative case the results previously obtained for the dissipative case. We also consider the problem of 1:4 resonance for the conservative cubic H\'enon maps.Comment: 20 pages, 12 figure

    Thermoelectric properties and phase transitions of II-VI semiconductors at high pressure

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    The high-pressure phase transitions in II -VI semiconductors (HgTe, HgSe, HgS, HgO, CdTe, CdSe, CdS, ZnTe, ZnSe, ZnS, ZnO) are analyzed in light of recent findings. A contribution is emphasized of the thermoelectric power (Seebeck effect) technique to registration of new electronic phases and to prediction of their related structural modifications. A novel thermopower study of ZnX (X -Te, Se, S) revealed a difference between the high-pressure NaCl phases of ZnSe and ZnS and the orthorhombic Cmcm phase of ZnTe. Mechanisms of the pressure-induced transitions in ZnX and other II -VI compounds are discussed

    Giant Room-Temperature Power Factor in p-Type Thermoelectric SnSe under High Pressure

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    Materials that can efficiently convert heat into electricity are widely utilized in energy conversion technologies. The existing thermoelectrics demonstrate rather limited performance characteristics at room temperature, and hence, alternative materials and approaches are very much in demand. Here, it is experimentally shown that manipulating an applied stress can greatly improve a thermoelectric power factor of layered p‐type SnSe single crystals up to ≈180 µW K(−2) cm(−1) at room temperature. This giant enhancement is explained by a synergetic effect of three factors, such as: band‐gap narrowing, Lifshitz transition, and strong sample deformation. Under applied pressure above 1 GPa, the SnSe crystals become more ductile, which can be related to changes in the prevailing chemical bonding type inside the layers, from covalent toward metavalent. Thus, the SnSe single crystals transform into a highly unconventional crystalline state in which their layered crystal stacking is largely preserved, while the layers themselves are strongly deformed. This results in a dramatic narrowing in a band gap, from E (g) = 0.83 to 0.50 eV (at ambient conditions). Thus, the work demonstrates a novel strategy of improving the performance parameters of chalcogenide thermoelectrics via tuning their chemical bonding type, stimulating a sample deformation and a band‐structure reconstruction

    Thermo-and galvanomagnetic technique for semiconductors testing at high pressure up to 30 GPa

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    Abstract The thermoelectric power (S), magnetoresistance (MR) and thermomagnetic (TM) e ects were measured at high pressure (P) in the vicinity of semiconductor-metal phase transitions for Te, Se and S micro-samples. From longitudinal and transverse Nernst-Ettingshausen (N-E) e ects for Te and Se, the scattering parameter (r) of holes was estimated and under the closing of semiconductor gap (Eg) the decreasing of their e ective mass (m) was found. S of Sulphur also decreased with pressure up to 40 GPa and the negative MR e ect observed indicates low mobility ( ) of holes. The technique developed seems to be suitable for use in micro-device technology.

    On the hierarchy of partially invariant submodels of differential equations

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    It is noticed, that partially invariant solution (PIS) of differential equations in many cases can be represented as an invariant reduction of some PIS of the higher rank. This introduce a hierarchic structure in the set of all PISs of a given system of differential equations. By using this structure one can significantly decrease an amount of calculations required in enumeration of all PISs for a given system of partially differential equations. An equivalence of the two-step and the direct ways of construction of PISs is proved. In this framework the complete classification of regular partially invariant solutions of ideal MHD equations is given

    Electronic properties of multi-phase systems with varying configuration of inclusions

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    ABSTRACT Multi-component systems (heterophases, layered, porous, misfit, composite) present the interest for different spheres of science and engineering. The paper covers both theoretical and experimental investigations of such systems with varying concentration and configuration of inclusions. En equations describing the dependence of electronic properties (thermomagnetic and galvanomagnetic as well as electrical and thermoelectric ones) of such systems on concentration and configuration of inclusions are presented. The equations derived may be used for analysis of electronic properties of advanced heterostructures. The above model describing the dependence of electronic properties of multi-component heterophase systems on concentration and configurations of inclusions allows to point out the ways for improving of electronic properties (thermoelectric effectiveness, thermoelectric and thermomagnetic figure of merit, etc.) and for extending of functional possibilities of such systems. So, the approach offered may be used for optimization of properties and for design of microdevices with improved characteristics

    Analytical description of stationary ideal MHD flows with constant total pressure

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    Incompressible stationary flows of ideal plasma are observed. By introduction of curvilinear system of coordinates in which streamlines and magnetic force lines form a family of coordinate surfaces, MHD equations are partially integrated and brought to a certain convenient form. It is demonstrated that the admissible group of Bogoyavlenskij's symmetry transformations performs as a scaling transformation for the curvilinear coordinates. Analytic description of stationary flows with constant total pressure is given. It is shown, that contact magnetic surfaces of such flows are translational surfaces, i.e. are swept out by translating one curve rigidly along another curve. Explicit examples of solutions with constant total pressure possessing a significant functional arbitrariness are given

    Some Aspects of Mast Cells Carboxypeptidase A3 Participation in the Pathogenesis of COVID-19

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    Background: This study aimed to determine the involvement of carboxypeptidase A3 (CPA3) in developing lung damage in patients with COVID-19. Methods and Results: The study included samples of autopsy material from the lungs of patients who died as a result of severe COVID-19 (the main group [MG] and persons who died from external causes (the control group [CG]). Immunohistochemical staining for CPA3 was carried out. A quantitative study of CPA3-positive mast cells (MCs) and the degree of their degranulation was carried out using a ×40 objective lens with an analysis of ≥50 fields of view with further conversion to 1 mm². Significant representation of CPA3-positive MCs per 1 mm2 of CPA3-positive MCs, CPA3-positive MCs with signs of degranulation (SD), and co-adjacent MCs was found in the MG compared to the CG (P=0.01 in all cases). In the main group, positive correlations were identified between the total number of CPA3-positive MCs, CPA3-positive MCs with SD and the blood hemoglobin level shortly before death (r=0.491 [P=0.008] and r=0.521 [P=0.004], respectively). Co-adjacent CPA3-positive MCs were negatively correlated with blood eosinophils at the beginning of hospitalization (r=-0.420 [P=0.023]). Also, the number of separately lying, CPA3-positive MCs negatively correlated with the blood monocyte shortly before death (r=-0.384 [P=0.044]). A positive correlation was established between the total number of CPA3-positive MCs, CPA3-positive MCs with SD, and adjacent CPA3-positive MCs with total blood protein in patients at the beginning of hospitalization (r=0.431 [P=0.020], r=0.449 [P=0.015] and r=0.456 [P=0.013], respectively). In addition, the study demonstrated a positive correlation between CPA3-positive MCs with SD and the total number of CPA3-positive MCs with blood aPTT levels (r=0.304 [P=0.045] and r=0.375 [P=0.045], respectively). A negative correlation was also found between the total number of CPA3-positive MCs and the blood INR level (r=-0.812 [P=0.050]). Finally, in patients at the beginning of hospitalization, a negative correlation was found between CPA3-positive MCs with SD, CPA3-positive MCs without SD, separately located CPA3-positive MCs, adjacent CPA3-positive MCs, and the total number of CPA3-positive MCs with blood amylase (r=-0.550 [P=0.002], r=-0.452 [P=0.045], r=-0.485 [P=0.030], r=-0.622 [P=0.008], and r=-0.590 [P=0.006], respectively). Conclusion: Our study identifies the potential involvement of CPA3 in the pathogenesis of severe COVID-19. However, many aspects of its participation remain unclear and require further study
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