34 research outputs found
Highly mobile carriers in orthorhombic phases of iron-based superconductors FeSeS
The field and temperature dependencies of the longitudinal and Hall
resistivity have been measured for FeSeS (x=0.04, 0.09 and
0.19) single crystals. The sample FeSeS does not show a
transition to an orthorhombic phase and exhibits at low temperatures the
transport properties quite different from those of orthorhombic samples. The
behavior of FeSeS is well described by the simple two
band model with comparable values of hole and electron mobility. In particular,
at low temperatures the transverse resistance shows a linear field dependence,
the magnetoresistance follow a quadratic field dependence and obeys to Kohler's
rule. In contrast, Kohler's rule is strongly violated for samples having an
orthorhombic low temperature structure. However, the transport properties of
the orthorhombic samples can be satisfactory described by the three band model
with the pair of almost equivalent to the tetragonal sample hole and electron
bands, supplemented with the highly mobile electron band which has two order
smaller carrier number. Therefore, the peculiarity of the low temperature
transport properties of the orthorhombic Fe(SeS) samples, as probably of many
other orthorhombic iron superconductors, is due to the presence of a small
number of highly mobile carriers which originate from the local regions of the
Fermi surface, presumably, nearby the Van Hove singularity points
Magnetotransport properties of FeSe in fields up to 50T
Magnetotransport properties of the high-quality FeSe crystal, measured in a
wide temperature range and in magnetic fields up to 50 T, show the symmetry of
the main holelike and electronlike bands in this compound. In addition to the
main two bands, there is also a tiny, highly mobile, electronlike band which is
responsible for the non-linear behavior of (B) at low temperatures
and some other peculiarities of FeSe. We observe the inversion of the
temperature coeficient at a magnetic field higher than about 20 T
which is an implicit conformation of the electron-hole symmetry in the main
bands.Comment: MISM 201
Majority carrier type inversion in FeSe family and "doped semimetal" scheme in iron-based superconductors
The field and temperature dependencies of the longitudinal and Hall
resistivity have been studied for high-quality FeSeS (x up to
0.14) single crystals. Quasiclassical analysis of the obtained data indicates a
strong variation of the electron and hole concentrations under the studied
isovalent substitution and proximity of FeSe to the point of the majority
carrier-type inversion. On this basis, we propose a `doped semimetal' scheme
for the superconducting phase diagram of the FeSe family, which can be applied
to other iron-based superconductors. In this scheme, the two local maxima of
the superconducting temperature can be associated with the Van Hove
singularities of a simplified semi-metallic electronic structure. The
multicarrier analysis of the experimental data also reveals the presence of a
tiny and highly mobile electron band for all the samples studied. Sulfur
substitution in the studied range leads to a decrease in the number of mobile
electrons by more than ten times, from about 3\% to about 0.2\%. This behavior
may indicate a successive change of the Fermi level position relative to
singular points of the electronic structure which is consistent with the `doped
semimetal' scheme. The scattering time for mobile carriers does not depend on
impurities, which allows us to consider this group as a possible source of
unusual acoustic properties of FeSe
Multiband effect in elastoresistance of Fe(Se,Te)
We have investigated the elastoresistance of two FeSeTe (x
about 0.4 - 0.5) compounds that have a close chemical composition but differ
significantly in electronic properties. The first compound has a negative
temperature coefficient of resistance and does not show any phase transitions
other than superconducting. The elastoresistance of this compound approximately
follows low as it usually occurs in Fe(Se,S) with metallic conductivity.
The second compound has a metallic type of conductivity and in addition to the
superconducting transition, there is also a phase transition at a temperature
of about 30 K. The elastoresistance of the second compound is sign-reversing
and can be approximated with the sum of two Curie-Weiss type terms with
opposite signs and different critical temperatures which suggest a competition
of contributions to the elastoresistance from different band valleys
1/3 magnetization plateau and frustrated ferrimagnetism in a sodium iron phosphite
AT was supported by the Federal Ministry for Education and Research through the Sofja Kovalevskaya Award of Alexander von Humboldt Foundation. This work was supported in part by Russian Foundation for Basic Research grants 14-02-00111, 14-02-00245, 16-02-00021, from the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST «MISiS» (№ К2-2015-075 and № K4-2015-020) and by Act 211 of the Government of Russian Federation, agreement № 02.A03.21.0006. EAZ, JW and RK acknowledge support by the Excellence Initiative of the German Federal Government and States. PL thanks EPSRC (EP/K503162/1) for partial support of a studentship to IM and the Leverhulme Trust for the award of a post-doctoral fellowship (RPG-2013-343) to LC. SK is grateful for the funding by SSP1458 of the DFG.The sodium-iron phosphite NaFe3(HPO3)2(H2PO3)6 is studied by ac-magnetic susceptibility, pulsed-field magnetization, specific heat, and high-frequency electron spin resonance (HF-ESR) measurements combined with Mössbauer spectroscopy and density-functional calculations. We show that this compound develops ferrimagnetic order below TC = 9.5 K and reveals a magnetization plateau at 1/3-saturation. The plateau extends to Bc ~ 8 T, whereas above Bc the magnetization increases linearly until reaching saturation at Bs ~ 27 T. The Mössbauer spectroscopy reveals two magnetically non-equivalent iron sites with the 2:1 ratio. The HF-ESR spectra are consistent with a two-sublattice ferrimagnet and additionally pinpoint weak magnetic anisotropy as well as short-range spin order that persists well above TC. The ferrimagnetic order in the title compound is stabilized by a network of purely antiferromagnetic exchange interactions. The spin lattice comprises layers coinciding with the crystallographic (10-1) planes, with stronger couplings Ji ~ 1.5 K within the layers and weaker couplings Ji = 0.3−0.4 K between the layers. Both intralayer and interlayer couplings are frustrated. The ensuing ferrimagnetic order arises from a subtle interplay of the frustrated but nonequivalent exchange couplings.PostprintPostprintPeer reviewe
Multiband Effect in Elastoresistance of Fe(Se,Te)
We have investigated the elastoresistance of two compounds that have a close chemical composition but differ significantly in electronic properties. The first compound has a negative temperature coefficient of resistance and does not show any phase transitions other than a superconducting one. The elastoresistance of this compound approximately follows the law which is a special case of the Curie-Weiss law, which is usually observed for Fe(Se,S) with metallic conductivity. The second compound has a metallic type of conductivity and, in addition to the superconducting transition, there is also a phase transition at a temperature of about 30 K. The elastoresistance of the second compound is sign-reversing and can be approximated with the sum of two Curie-Weiss-type terms with opposite signs and different critical temperatures. We attribute this behavior to the competition of contributions to the elastoresistance from different band valleys. These competing contributions may appear since the composition of our compound is close to the critical point at which the low-temperature ground state in the 11 series of iron-based superconductors changes from electronic nematic order to magnetic order. © Copyright2020 EPLA.This work was supported in part from the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST “MISiS” (K2-2020-008) and by Act 211 of the Government of Russian Federation, agreements 02.A03.21.0004 and 02.A03.21.0006 and by the Program of Competitive Growth of Kazan Federal University. We acknowledge support from Russian Foundation for Basic Research (Grants 20-02-00561 and ofi-m 17-29-10007) and Russian Science Foundation (Grant 19-42-02010)
Phase Separation Near the Charge Neutrality Point in FeSe1-xTexcrystals with x < 0.15
Our study of FeSe1-xTe x crystals with x < 0.15 shows that the phase separation in these compositions occurs into phases with a different stoichiometry of iron. This phase separation may indicate structural instability of the iron plane in the studied range of compositions. We tentatively propose an explanation of the structural instability of the iron plane in the studied layered compounds in terms of the possible change in the bond polarity and the peculiarity of the direct d-d exchange in the iron plane in the framework of the basic phenomenological description such as the Bethe-Slater curve. With this approach, when the distance between iron atoms is close to the value at which the sign of the magnetic exchange for some d orbitals changes, structural and electronic instability can occur. Anomalies in the crystal field near the point of charge neutrality can also be a significant component of this instability. © 2021 IOP Publishing Ltd