221 research outputs found

    Induced magnetic anisotropy features in FeCrSiBNbCu nanocrystalline alloy: Role of stress distribution proven by direct X-ray measurements

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    Fe73.5-xCrxSi13.5B9Nb 3Cu1 (x = 1, 2, and 3) amorphous ribbons were prepared by single roller rapid quenching technique. Both conventional and stress annealing at 520 C for 2 h at the value of the specific load of 150 MPa resulted in the formation of a nanocrystalline structure with average grain size about 13 nm. No significant differences in crystallite size were observed for all samples under consideration. The crystallite orientations were practically isotropic indicating no texture in the samples of all types. For all conventionally annealed ribbons a longitudinal effective magnetic anisotropy with an easy magnetization axis parallel to the ribbon axis was observed. For all stress annealed ribbons a transverse induced magnetic anisotropy with the anisotropy constant value of about 1800 ± 50 J/m3 was evident. Induced magnetic anisotropy features in FeCrSiBNbCu nanocrystalline alloy, namely an importance of the stress distribution was proven by direct X-ray measurements. A very good correlation between the induced magnetic anisotropy constant values and anisotropic stress distribution was observed. © 2013 Elsevier B.V. All rights reserved

    Optimising piezoelectric and magnetoelectric responses on CoFe2O4/P(VDF-TrFE) nanocomposites

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    Magnetoelectric nanocomposite films composed of magnetostrictive CoFe2O4 nanoparticles with sizes between 35 and 55 nm embedded in P(VDF-TrFE) have been successfully prepared by a solvent casting method. The ferroelectric, piezoelectric, magnetic and magnetoelectric properties of the nanocomposite and their variation with the wt% of the ferrite filler, thickness of the composite and direction of the applied magnetic field have been investigated. Ferroelectric and piezoelectric properties are improved when small amount of ferrite nanoparticles were added to the polymeric matrix. Magnetic properties vary linearity with ferrite content. The highest magnetoelectric response of 41.3 mV/cmOe was found in the composite with 72wt% when a 2.5 kOe DC field was transversely applied to the sample surface. This value is among the highest reported in two phase particulate polymer nanocomposites. Thickness of the composite has no influence in the magnetoelectric response, allowing tailoring sensor thickness for specific applications. The good value of the magnetoelectric coefficient and the flexibility of the films make these composites suitable for applications in magnetoelectric smart devices.Fundação para a Ciência e a Tecnologia (FCT) (PTDC/CTM/69316/2006), (SFRH/BD/45265/2008).FEDER “Programa Operacional Factores de Competitividade – COMPETE” (NANO/NMed-SD/0156/2007)Basque Government Industry Department - Project Actimat (ETORTEK-IE10-272)COST Action MP1003, 2010 - The „European Scientific Network for Artificial Muscles‟ (ESNAM)

    Assemblies of magnetite nanoparticles extracted from magnetotactic bacteria: A magnetic study

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    Self-assembly has emerged as a suitable technique for tuning the properties of nanoparticles. In this work, we report the self-assembly of magnetosomes assisted by an external magnetic field. The magnetosomes are magnetite nanoparticles biomineralized by magnetotactic bacteria Magnetospirillum gryphiswaldense. These nanoparticles present truncated cubo-octahedral morphology with a mean diameter of ˜36 nm and are surrounded by a lipid bilayer membrane with a thickness ˜2-4 nm. The use of the appropriate preparation conditions, such as initial colloidal concentration and magnetic fields applied during deposition allowed us to obtain very reproducible self-assembled 2D patterns. Homogeneous ensembles of magnetosomes onto silicon and carbon surfaces are composed of elongated structures in the form of wide chains that cover a large area of the substrates. Transmission electron microscopy image and off-axis electron holography showed the map of the stray magnetic fields produced by these assemblies. The induced magnetic anisotropy was analyzed by measuring the hysteresis loops of the assemblies at different angles in a magneto-optical Kerr effect magnetometer. The evolution of the coercive field and remanence verified the presence of well-defined patterns. The experimental results were analyzed on the based of a biaxial model

    Surface modified Ni nanoparticles produced by the electrical explosion of wire

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    Spherical nickel nanoparticles were prepared by the electrical explosion of wire. The as prepared nanoparticles were modified immediately after fabrication at room temperature in order to provide tunable surface properties with focus on the development of composites filled with nanoparticles. Following liquid modificators were used: hexane, toluene and the solution of polystyrene in toluene. In one case the surface modification by carbon was made in gas phase as a result of hydrocarbon injection. The average size of the nanoparticles was about 50 nm and unit cell parameters were close to 0.351 nm. Detailed characterization was done by X-ray diffraction, transmission electron microscopy, and magnetization measurements. Sphericity was also checked using microwave resonant absorption. © (2015) Trans Tech Publications, Switzerland.Electromagnetics of Russian Academy of Sciences;et al;Institute for Theoretical and Applied;Japan Society for the Promotion of Science;Lomonosov Moscow State University;Russian Foundation for Basic Researc

    FIELD TRIP TO THE YPRESIAN/LUTETIAN BOUNDARY AT THE GORRONDATXE BEACH SECTION (BASQUE COUNTRY, W PYRENEES)

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    One of the Paleogene Stage boundaries still needing official definition is the Ypresian/Lutetain (Early- Middle Eocene) boundary. With the aim of contributing to attain this definition, a high-resolution multidisciplinary study, including physical stratigraphy (lithostratigraphy, sequence stratigraphy and magnetostratigraphy) and biostratigraphy (calcareous nannofossil, planktic foraminifer and larger foraminifer), has been carried out over the 700 m thick uppermost Ypresian – lower Lutetian Gorrondatxe section. The results show that the different events traditionally used to place the Ypresian/Lutetian boundary, hitherto thought to be simultaneous (i.e., the planktic foraminifer P9 (=E7) / P10 (=E8) Zone boundary; the calcareous nannofossil CP12a / CP12b Subzone boundary; the larger foraminifer SBZ12 / SBZ13 Zone boundary; and the boundary between magnetic polarity chrons C22n and C21r), actually occur at very different levels. Therefore, before considering any section to place the Ypresian/Lutetian boundary stratotype, the criterion to precisely define this boundary should be selected. To this end, the succession of events pinpointed in the Ypresian/Lutetian boundary interval of the Gorrondatxe beach section might prove a useful database. The Gorrondatxe section fulfils most of the requirements demanded of a prospective stratotype section. In addition, the great sedimentary thickness, which implies a very high deep-marine sedimentation rate, provides the Gorrondatxe section an additional value, as it offers the opportunity to chronologically order successive biomagnetostratigraphic events more precisely than elsewhere. Therefore, we consider that, once the criterion to define the Ypresian/Lutetian boundary is selected, the Gorrondatxe beach section should be deemed a firm candidate to place the Global Stratotype Section and Point of the base of the Lutetian Stage
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