Spectroscopic techniques and the conservation of artists’ acrylic emulsion paints

Artists’ acrylic emulsion paints are used in many contexts such as paintings, murals, sculptures, works on paper and mixed media; and are forming increasing proportions of modern and contemporary art collections. Although acrylic emulsion paints have been the focus of museum-led research over the past decade, the impact of artists’ technique and conservation treatment on the upper-most surface of these paints remains essentially unexplored ; This paper summarises previous studies using vibrational (FTIR) spectroscopy and presents initial assessments of paint surfaces using X-ray spectroscopies (XPS and NEXAFS) aimed at characterising artists’ acrylic paint film surfaces after natural ageing and wet surface cleaning treatment. Both techniques were found to be well suited for surface-sensitive investigations of the organic materials associated with artists’ acrylic paints, including explorations into: (A) cleaning system residues, (B) surfactant extraction from paint surfaces, (C) the identification of migrated surfactant, and (D) monitoring pigment changes at the paint/air interface of paint films ; It has been shown is that these X-ray spectroscopic techniques can be used for the analysis of almost purely organic materials in a way that complements mass spectroscopic techniques, FTIR and XRF. This investigation forms part of broader, currently ongoing, multi-technique investigation into the properties of artists’ acrylic paints and development of conservation treatments for works-of-art made with these materials

Diffusion of water from a range of conservation treatment gels into paint films studied by unilateral NMR: Part I: Acrylic emulsion paint

Unilateral NMR was used to monitor the penetration of water into acrylic emulsion paint-outs on canvas during cleaning simulations with five thickened conservation treatment systems – agarose gels, methylcellulose paste, Pemulen-TR2, poly(vinyl alcohol)-borax gels, and Velvesil Plus – and water-moistened swabs. Studies were also carried out to measure the rate of water penetration from the different treatment methods into acrylic paints during continuous exposure. Unilateral NMR is shown to be an effective technique for comparing depth penetration of water during cleaning treatments; the volume of paint occupied by water can be extracted from these measurements. The results show that young paint films (1 month) are more prone to swelling than aged paint films (2–50 years), with light aged paints having the highest resistance to water penetration during treatments. Aged organic pigmented acrylic paint (Hansa yellow light) shows a higher propensity for swelling during cleaning than aged titanium dioxide white paint. Cleaning simulations using water-moistened swabs and agar gels deposit approximately equivalent amounts of water into the paint films, whilst all other gel systems tested, with the exception of Velvesil Plus, tend to allow approximately 50% more water into the paint films. None of the aqueous thickened cleaning systems tested reduced the quantity of water which entered the paint films relative to swab cleaning

Variation of turbulent burning rate of methane, methanol, and iso-octane air mixtures with equivalence ratio at elevated pressure

Turbulent burning velocities for premixed methane, methanol, and iso-octane/air mixtures have been experimentally determined for an rms turbulent velocity of 2 m/s and pressure of 0.5 MPa for a wide range of equivalence ratios. Turbulent burning velocity data were derived using high-speed schlieren photography and transient pressure recording; measurements were processed to yield a turbulent mass rate burning velocity, utr. The consistency between the values derived using the two techniques, for all fuels for both fuel-lean and fuel-rich mixtures, was good. Laminar burning measurements were made at the same pressure, temperature, and equivalence ratios as the turbulent cases and laminar burning velocities and Markstein numbers were determined. The equivalence ratio (φ) for peak turbulent burning velocity proved not always coincident with that for laminar burning velocity for the same fuel; for isooctane, the turbulent burning velocity unexpectedly remained high over the range φ = 1 to 2. The ratio of turbulent to laminar burning velocity proved remarkably high for very rich iso-octane/air and lean methane/air mixtures

MODIS Information, Data, and Control System (MIDACS) system specifications and conceptual design

The MODIS Information, Data, and Control System (MIDACS) Specifications and Conceptual Design Document discusses system level requirements, the overall operating environment in which requirements must be met, and a breakdown of MIDACS into component subsystems, which include the Instrument Support Terminal, the Instrument Control Center, the Team Member Computing Facility, the Central Data Handling Facility, and the Data Archive and Distribution System. The specifications include sizing estimates for the processing and storage capacities of each data system element, as well as traffic analyses of data flows between the elements internally, and also externally across the data system interfaces. The specifications for the data system, as well as for the individual planning and scheduling, control and monitoring, data acquisition and processing, calibration and validation, and data archive and distribution components, do not yet fully specify the data system in the complete manner needed to achieve the scientific objectives of the MODIS instruments and science teams. The teams have not yet been formed; however, it was possible to develop the specifications and conceptual design based on the present concept of EosDIS, the Level-1 and Level-2 Functional Requirements Documents, the Operations Concept, and through interviews and meetings with key members of the scientific community

MODIS information, data and control system (MIDACS) operations concepts

The MODIS Information, Data, and Control System (MIDACS) Operations Concepts Document provides a basis for the mutual understanding between the users and the designers of the MIDACS, including the requirements, operating environment, external interfaces, and development plan. In defining the concepts and scope of the system, how the MIDACS will operate as an element of the Earth Observing System (EOS) within the EosDIS environment is described. This version follows an earlier release of a preliminary draft version. The individual operations concepts for planning and scheduling, control and monitoring, data acquisition and processing, calibration and validation, data archive and distribution, and user access do not yet fully represent the requirements of the data system needed to achieve the scientific objectives of the MODIS instruments and science teams. The teams are not yet formed; however, it is possible to develop the operations concepts based on the present concept of EosDIS, the level 1 and level 2 Functional Requirements Documents, and through interviews and meetings with key members of the scientific community. The operations concepts were exercised through the application of representative scenarios

MODIS information, data and control system (MIDACS) level 2 functional requirements

The MODIS Information, Data and Control System (MIDACS) Level 2 Functional Requirements Document establishes the functional requirements for MIDACS and provides a basis for the mutual understanding between the users and the designers of the EosDIS, including the requirements, operating environment, external interfaces, and development plan. In defining the requirements and scope of the system, this document describes how MIDACS will operate as an element of the EOS within the EosDIS environment. This version of the Level 2 Requirements Document follows an earlier release of a preliminary draft version. The sections on functional and performance requirements do not yet fully represent the requirements of the data system needed to achieve the scientific objectives of the MODIS instruments and science teams. Indeed, the team members have not yet been selected and the team has not yet been formed; however, it has been possible to identify many relevant requirements based on the present concept of EosDIS and through interviews and meetings with key members of the scientific community. These requirements have been grouped by functional component of the data system, and by function within each component. These requirements have been merged with the complete set of Level 1 and Level 2 context diagrams, data flow diagrams, and data dictionary

MODIS-HIRIS ground data systems commonality report

The High Resolution Imaging Spectrometer (HIRIS) and Moderate Resolution Imaging Spectrometer (MODIS) Data Systems Working Group was formed in September 1988 with representatives of the MODIS Data System Study Group and the HIRIS Project Data System Design Group to collaborate in the development of requirements on the EosDIS necessary to meet the science objectives of the two facility instruments. A major objective was to identify and promote commonality between the HIRIS and MODIS data systems, especially from the science users' point of view. A goal was to provide a base set of joint requirements and specifications which could easily be expanded to a Phase-B representation of the needs of the science users of all EOS instruments. This document describes the points of commonality and difference between the Level-II Requirements, Operations Concepts, and Systems Specifications for the ground data systems for the MODIS and HIRIS instruments at their present state of development