8 research outputs found
In situ FTIR Spectroelectrochemical Studies of Surface Films Formed on Li and Nonactive Electrodes at Low Potentials in Li Salt Solutions Containing CO 2
No full textThe Study of Surface Films Formed on Lithium and Noble Metal Electrodes in Polar Aprotic Systems By the Use of In Situ Fourier Transform Infrared Spectroscopy
No full textThe Application of In Situ FTIR Spectroscopy to the Study of Surface Films Formed on Lithium and Noble Metals at Low Potentials in Li Battery Electrolytes
No full textThe Correlation Between the Surface Chemistry and the Performance of Li‐Carbon Intercalation Anodes for Rechargeable ‘Rocking‐Chair’ Type Batteries
No full textAdvances in Magnesium Electrochemistry — A Challenge for Nanomaterials
No full text875-890In this review, very recent studies related
to magnesium electrochemistry (in connection with R&D of Mg batteries) have
been reported. These include the study of new electrolyte solutions, based on complexes
with the formal stoichiometry, Mg(ALCL4-nRn)2 in
ethers, their unique structures and analysis by electrochemical and spectroscopic
methods, the study of Mg deposition processes by microelectrodes and microscopy,
and the study of Mg insertion into hosts based on the so-called Chevrel phase structure
(Mg0-2Mo6X8, X=S, Se). The ionic mobility of Mg2+
ions and their ease of diffusion within these structures are discussed. It is demonstrated
that the use of a nanostructured active mass may be highly important for reducing
the diffusion length considerably, and hence, for increasing the kinetics of transport
of the bivalent cations. We deal herein with some key factors that may affect
the possibility of smooth and reversible Mg insertion into inorganic host materials,
and the possible advantages in the use of nanoparticles for these systems
Alkyl Group Transmetalation Reactions in Electrolytic Solutions Studied by Multinuclear NMR
No full textAdvances in magnesium electrochemistry — A challenge for nanomaterials
No full text875-890In this review, very recent studies related
to magnesium electrochemistry (in connection with R&D of Mg batteries) have
been reported. These include the study of new electrolyte solutions, based on complexes
with the formal stoichiometry, Mg(ALCL4-nRn)2 in
ethers, their unique structures and analysis by electrochemical and spectroscopic
methods, the study of Mg deposition processes by microelectrodes and microscopy,
and the study of Mg insertion into hosts based on the so-called Chevrel phase structure
(Mg0-2Mo6X8, X=S, Se). The ionic mobility of Mg2+
ions and their ease of diffusion within these structures are discussed. It is demonstrated
that the use of a nanostructured active mass may be highly important for reducing
the diffusion length considerably, and hence, for increasing the kinetics of transport
of the bivalent cations. We deal herein with some key factors that may affect
the possibility of smooth and reversible Mg insertion into inorganic host materials,
and the possible advantages in the use of nanoparticles for these systems
