The crystal and molecular structure of Hydridotetrakis(diethyl phenylphosphonite)cobalt(I)

An X-ray structure determination of the title compound shows that the co-ordination about the cobalt atom is approximately trigonal bipyramidal; n.m.r. data indicate that the complex is non-rigid in solution

V4743 Sgr, a magnetic nova?

Two XMM Newton observations of Nova V4743 Sgr (Nova Sgr 2002) were performed shortly after it returned to quiescence, 2 and 3.5 years after the explosion. The X-ray light curves revealed a modulation with a frequency of ~0.75 mHz, indicating that V4743 Sgr is most probably an intermediate polar (IP). The X-ray spectra have characteristics in common with known IPs, with a hard thermal plasma component that can be fitted only assuming a partially covering absorber. In 2004 the X-ray spectrum had also a supersoft blackbody-like component, whose temperature was close to that of the white dwarf (WD) in the supersoft X-ray phase following the outburst, but with flux by at least two orders of magnitude lower. In quiescent IPs, a soft X-ray flux component originates at times in the polar regions irradiated by an accretion column, but the supersoft component of V4743 Sgr disappeared in 2006, indicating a possible origin different from accretion. We suggest that it may have been due to an atmospheric temperature gradient on the WD surface, or to continuing localized thermonuclear burning at the bottom of the envelope, before complete turn-off. An optical spectrum obtained with SALT 11.5 years after the outburst showed a prominent He II 4686A line and the Bowen blend, which reveal a very hot region, but with peak temperature shifted to the ultraviolet (UV) range. V4743 Sgr is the third post-outburst nova and IP candidate showing a low-luminosity supersoft component in the X-ray flux a few years after the outburst.Comment: 9 pages, 5 figures, accepted to MNRA

The X-ray emission from Nova V382 Velorum: I. The hard component observed with BeppoSAX

We present BeppoSAX observations of Nova Velorum 1999 (V382 Vel), done in a broad X-ray band covering 0.1-300 keV only 15 days after the discovery and again after 6 months. The nova was detected at day 15 with the BeppoSAX instruments in the energy range 1.8-10 keV and we attribute the emission to shocks in the ejecta. The plasma temperature was kT~6 keV and the unabsorbed flux was F(x)~4.3 x 10(-11) erg/cm**2/s. The nebular material was affected by high intrinsic absorption of the ejecta. 6 months after after the outburst, the intrinsic absorption did not play a role, the nova had turned into a bright supersoft source, and the hot nebular component previously detected had cooled to a plasma temperature kT<=1 keV. No emission was detected in either observation above 20 keV.Comment: 1 tex file, 2 figures as .ps, and 1 .sty file of MNRA

Diagnóstico para identificação de demandas de pesquisa no setor produtivo de suínos e aves no Estado do Pará.

bitstream/item/63289/1/Oriental-Doc103.pd

Effects of Metformin With or Without Supplementation With Folate on Homocysteine Levels and Vascular Endothelium of Women With Polycystic Ovary Syndrome

OBJECTIVE: To evaluate whether the administration of metformin exerts any effects on serum homocysteine (Hcy) levels in patients with polycystic ovary syndrome (PCOS) and whether supplementation with folate enhances the positive effects of metformin on the structure and function of the vascular endothelium. RESEARCH DESIGN AND METHODS: A total of 50 patients affected by PCOS, without additional metabolic or cardiovascular diseases, were enrolled in a prospective nonrandomized placebo-controlled double-blind clinical study. They were grouped into two treatment arms that were matched for age and BMI. Patients were treated with a 6-month course of metformin (1,700 mg daily) plus folic acid (400 microg daily; experimental group, n = 25) or placebo (control group, n = 25). Complete hormonal and metabolic patterns, serum Hcy, folate, vitamin B12, endothelin-1 levels, brachial artery diameter at the baseline (BAD-B) and after reactive hyperemia (BAD-RH), flow-mediated dilation, and intima-media thickness in both common carotid arteries were evaluated. RESULTS: After treatment, a significant increase in serum Hcy levels was observed in the control group compared with the baseline values and the experimental group. A beneficial effect was observed in the concentrations of BAD-B, BAD-RH, flow-mediated dilation, intima-media thickness, and serum endothelin-1 in both groups. However, the results were improved more significantly in the experimental group than in the control subjects. CONCLUSIONS: Metformin exerts a slight but significant deleterious effect on serum Hcy levels in patients with PCOS, and supplementation with folate is useful to increase the beneficial effect of metformin on the vascular endothelium

The X-ray emission from Nova V382 Velorum: II. The super-soft component observed with BeppoSAX

Nova Velorum 1999 (V382 Vel) was observed by BeppoSAX 6 months after optical maximum and was detected as a bright X-ray supersoft source, with a count rate 3.454+-0.002 cts/s in the LECS. It was the softest and most luminous supersoft source observed with this instrument. The flux in the 0.1-0.7 keV range was not constant during the observation. It dropped by a factor of 2 in less than 1.5 hour and then was faint for at least 15 minutes, without significant spectral changes. The observed spectrum is not well fit with atmospheric models of a hot, hydrogen burning white dwarf. This is due mainly to a supersoft excess in the range 0.1-0.2 keV, but the fit can be significantly improved at higher energy if at least one emission feature is superimposed. We suggest that a ``pseudocontinuum'' was detected, consisting of emission lines in the supersoft X-ray range superimposed on the thermal continuum of a white dwarf atmosphere. As a result, an accurate determination of the effective temperature and gravity of the white dwarf at this post-outburst stage is not possible.Comment: To appear in MNRA

Optical observations of "hot" novae returning to quiescence

We have monitored the return to quiescence of novae previously observed in outburst as supersoft X-ray sources, with optical photometry of the intermediate polar (IP) V4743 Sgr and candidate IP V2491 Cyg, and optical spectroscopy of these two and seven other systems. Our sample includes classical and recurrent novae, short period (few hours), intermediate period (1-2 days) and long period (symbiotic) binaries. The light curves of V4743 Sgr and V2491 Cyg present clear periodic modulations. For V4743 Sgr, the modulation occurs with the beat of the rotational and orbital periods. If the period measured for V2491 Cyg is also the beat of these two periods, the orbital one should be almost 17 hours. The recurrent nova T Pyx already shows fragmentation of the nebular shell less than 3 years after the outburst. While this nova still had strong [OIII] at this post-outburst epoch, these lines had already faded after 3 to 7 years in all the others. We did not find any difference in the ratio of equivalent widths of high ionization/excitation lines to that of the Hbeta line in novae with short and long orbital period, indicating that irradiation does not trigger high mass transfer rate from secondaries with small orbital separation. An important difference between the spectra of RS Oph and V3890 Sgr and those of many symbiotic persistent supersoft sources is the absence of forbidden coronal lines. With the X-rays turn-off, we interpret this as an indication that mass transfer in symbiotics recurrent novae is intermittent.Comment: In press in Monthly Notices of the Royal Astronomical Societ