1,390 research outputs found
Dynamic van der Waals Theory of two-phase fluids in heat flow
We present a dynamic van der Waals theory. It is useful to study phase
separation when the temperature varies in space. We show that if heat flow is
applied to liquid suspending a gas droplet at zero gravity, a convective flow
occurs such that the temperature gradient within the droplet nearly vanishes.
As the heat flux is increased, the droplet becomes attached to the heated wall
that is wetted by liquid in equilibrium. In one case corresponding to partial
wetting by gas, an apparent contact angle can be defined. In the ther case with
larger heat flux, the droplet completely wets the heated wall expelling liquid.Comment: 6pages, 8figure
Ion-induced nucleation in polar one-component fluids
We present a Ginzburg-Landau theory of ion-induced nucleation in a gas phase
of polar one-component fluids, where a liquid droplet grows with an ion at its
center. By calculating the density profile around an ion, we show that the
solvation free energy is larger in gas than in liquid at the same temperature
on the coexistence curve. This difference much reduces the nucleation barrier
in a metastable gas.Comment: 9 pagers, 9 figures, to be published in J. Chem. Phy
Dynamics of Binary Mixtures with Ions: Dynamic Structure Factor and Mesophase Formation
Dynamic equations are presented for polar binary mixtures containing ions in
the presence of the preferential solvation. In one-phase states, we calculate
the dynamic structure factor of the composition accounting for the ion motions.
Microphase separation can take place for sufficiently large solvation asymmetry
of the cations and the anions. We show two-dimensional simulation results of
the mesophase formation with an antagonistic salt, where the cations are
hydrophilic and the anions are hydrophobic. The structure factor S(q) in the
resultant mesophase has a sharp peak at an intermediate wave number on the
order of the Debye-Huckel wave number. As the quench depth is increased, the
surface tension nearly vanishes in mesophases due to an electric double layer.Comment: 24 pages, 10 figures, to appear in Journal of Physics: Condensed
Matte
Surface tension of electrolytes: Hydrophilic and hydrophobic ions near an interface
We calculate the ion distributions around an interface in fluid mixtures of
highly polar and less polar fluids (water and oil) for two and three ion
species. We take into account the solvation and image interactions between ions
and solvent. We show that hydrophilic and hydrophobic ions tend to undergo a
microphase separation at an interface, giving rise to an enlarged electric
double layer. We also derive a general expression for the surface tension of
electrolyte systems, which contains a negative electrostatic contribution
proportional to the square root of the bulk salt density. The amplitude of this
square-root term is small for hydrophilic ion pairs, but is much increased for
hydrophilic and hydrophobic ion pairs. For three ion species including
hydrophilic and hydrophobic ions, we calculate the ion distributions to explain
those obtained by x-ray reflectivity measurements.Comment: 8 figure
Defect structures in nematic liquid crystals around charged particles
We numerically study the orientation deformations in nematic liquid crystals
around charged particles. We set up a Ginzburg-Landau theory with inhomogeneous
electric field. If the dielectric anisotropy varepsilon_1 is positive, Saturn
ring defects are formed around the particles. For varepsilon_1<0, novel "ansa"
defects appear, which are disclination lines with their ends on the particle
surface. We find unique defect structures around two charged particles. To
lower the free energy, oppositely charged particle pairs tend to be aligned in
the parallel direction for varepsilon_1>0 and in the perpendicular plane for
varepsilon_1<0 with respect to the background director . For identically
charged pairs the preferred directions for varepsilon_1>0 and varepsilon_1<0
are exchanged. We also examie competition between the charge-induced anchoring
and the short-range anchoring. If the short-range anchoring is sufficiently
strong, it can be effective in the vicinity of the surface, while the director
orientation is governed by the long-range electrostatic interaction far from
the surface.Comment: 10 papes, 12 figures, to appear in European Physical Journal
Pressure-induced Superconductivity in a Ferromagnet UGe -- Resistivity Measurements in Magnetic Field --
The electrical resistivity measurements in the magnetic field are carried out
on the pressure-induced superconductor UGe. The superconductivity is
observed from 1.06 to 1.44 GPa. The upper critical field of is
anisotropic where exhibits positive curvature for and
-axis. The characteristic enhancement of is reconfirmed for
-axis. In the temperature and field dependence of resistivity at where the ferromagnetic ordering disappears, it is observed that the
application of the external field along the {\it a}-axis increases the
coefficient of Fermi liquid behavior correspondingly to the
metamagnetic transition.Comment: To be published in the proceeding of the International Conference on
High Pressure Science and Technology(AIRAPT-18),Beijing,China,23-27 July 200
Pattern formation in crystal growth under parabolic shear flow
Morphological instability of the solid-liquid interface occuring in a crystal
growing from an undercooled thin liquid being bounded on one side by a free
surface and flowing down inclined plane is investigated by a linear stability
analysis under shear flow. It is found that restoring forces due to gravity and
surface tension is important factor for stabilization of the solid-liquid
interface on long length scales. This is a new stabilizing effect different
from the Gibbs-Thomson effect. A particular long wavelength mode of about 1 cm
of wavy pattern observed on the surface of icicles covered with thin layer of
flowing water is obtained from the dispersion relation including the effect of
flow and restoring forces.Comment: 30 pages, 4 figure
Charged inclusion in nematic liquid crystals
We present a general theory of liquid crystals under inhomogeneous electric
field in a Ginzburg-Landau scheme. The molecular orientation can be deformed by
electric field when the dielectric tensor is orientation-dependent. We then
investigate the influence of a charged particle on the orientation order in a
nematic state. The director is aligned either along or perpendicular to the
local electric field around the charge, depending on the sign of the dielectric
anisotropy. The deformation becomes stronger with increasing the ratio ,
where is the charge and is the radius of the particle. Numerical
analysis shows the presence of defects around the particle for large .
They are nanometer-scale defects for microscopic ions. If the dielectric
anisotropy is positive, a Saturn ring defect appears. If it is negative, a pair
of point defects appear apart from the particle surface, each being connected
to the surface by a disclination line segment.Comment: 12 figure
Shear flow effects on phase separation of entangled polymer blends
We introduce an entanglement model mixing rule for stress relaxation in a polymer blend to a modified Cahn-Hilliard equation of motion for concentration fluctuations in the presence of shear flow. Such an approach predicts both shear-induced mixing and demixing, depending on the relative relaxation times and plateau moduli of the two components
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